Home Aldehydes 2-(Diphenylphosphino)benzaldehyde

2-(Diphenylphosphino)benzaldehyde

CAS No.:
50777-76-9
Catalog Number:
AG00I93W
Molecular Formula:
C19H15OP
Molecular Weight:
290.2956
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
1g
97%
In Stock USA
United States
$18
- +
5g
97%
In Stock USA
United States
$50
- +
10g
97%
In Stock USA
United States
$88
- +
25g
97%
In Stock USA
United States
$175
- +
100g
97%
In Stock USA
United States
$525
- +
Product Description
Catalog Number:
AG00I93W
Chemical Name:
2-(Diphenylphosphino)benzaldehyde
CAS Number:
50777-76-9
Molecular Formula:
C19H15OP
Molecular Weight:
290.2956
MDL Number:
MFCD00013367
IUPAC Name:
2-diphenylphosphanylbenzaldehyde
InChI:
InChI=1S/C19H15OP/c20-15-16-9-7-8-14-19(16)21(17-10-3-1-4-11-17)18-12-5-2-6-13-18/h1-15H
InChI Key:
DRCPJRZHAJMWOU-UHFFFAOYSA-N
SMILES:
O=Cc1ccccc1P(c1ccccc1)c1ccccc1
Properties
Complexity:
300  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
290.086g/mol
Formal Charge:
0
Heavy Atom Count:
21  
Hydrogen Bond Acceptor Count:
1  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
290.302g/mol
Monoisotopic Mass:
290.086g/mol
Rotatable Bond Count:
4  
Topological Polar Surface Area:
17.1A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
4.1  
Literature
Title Journal
Synthesis of the phosphino-fullerene PPh2(o-C6H4)(CH2NMeCH)C60 and its function as an η1-P or η3-P,C2 ligand. Dalton transactions (Cambridge, England : 2003) 20120314
Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands. Journal of the American Chemical Society 20120314
Aldimines generated from aza-Wittig reaction between bis(iminophosphoranes) derived from 1,1'-diazidoferrocene and aromatic or heteroaromatic aldehydes: electrochemical and optical behaviour towards metal cations. Dalton transactions (Cambridge, England : 2003) 20111214
Chlorido{N-[2-(diphenyl-phosphan-yl)benz-yl]-1-(pyridin-2-yl)methanamine-κP}gold(I). Acta crystallographica. Section E, Structure reports online 20111101
Stereoselective synthesis of trisubstituted olefins by a directed allylic substitution strategy. Chemistry (Weinheim an der Bergstrasse, Germany) 20111010
Stereoselective and diversity-oriented synthesis of trisubstituted allylic alcohols and amines. Chemistry (Weinheim an der Bergstrasse, Germany) 20111010
Chlorido{N-[2-(diphenylphosphanyl)benz-ylidene]-2-(2-thienyl)ethanamine-κN,P}methylpalladium(II) dichloromethane hemisolvate. Acta crystallographica. Section E, Structure reports online 20100601
Diphen-yl[2-(2-pyridylamino-meth-yl)phen-yl]phosphine oxide. Acta crystallographica. Section E, Structure reports online 20100501
Total synthesis of (+)-bourgeanic acid utilizing o-DPPB-directed allylic substitution. Organic letters 20090806
New hydridoirida-beta-diketones derived from 8-quinoline-carbaldehyde and o-(diphenylphosphino)benzaldehyde. Dalton transactions (Cambridge, England : 2003) 20090607
Synthesis and characterization of iron(II) complexes with tetradentate diiminodiphosphine or diaminodiphosphine ligands as precatalysts for the hydrogenation of acetophenone. Inorganic chemistry 20090119
Synthesis and characterization of a novel Pd(II) complex with the condensation product of 2-(diphenylphosphino)benzaldehyde and ethyl hydrazinoacetate. Cytotoxic activity of the synthesized complex and related Pd(II) and Pt(II) complexes. Journal of inorganic biochemistry 20061101
o-DPPB-directed copper-mediated and -catalyzed allylic substitution with Grignard reagents. Chemistry (Weinheim an der Bergstrasse, Germany) 20060825
Palladium-catalyzed allylic alkylation using chiral hydrazones as ligands. The Journal of organic chemistry 20010309
Properties