Home Sulfos Fluorobis(phenylsulfonyl)methane

Fluorobis(phenylsulfonyl)methane

CAS No.:
910650-82-7
Catalog Number:
AG00GX4J
Molecular Formula:
Molecular Weight:
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
Product Description
Catalog Number:
AG00GX4J
Chemical Name:
Fluorobis(phenylsulfonyl)methane
CAS Number:
910650-82-7
MDL Number:
MFCD11036372
IUPAC Name:
[benzenesulfonyl(fluoro)methyl]sulfonylbenzene
InChI:
InChI=1S/C13H11FO4S2/c14-13(19(15,16)11-7-3-1-4-8-11)20(17,18)12-9-5-2-6-10-12/h1-10,13H
InChI Key:
TUZGMBZILYZZRU-UHFFFAOYSA-N
Properties
Complexity:
456  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
314.008g/mol
Formal Charge:
0
Heavy Atom Count:
20  
Hydrogen Bond Acceptor Count:
5  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
314.345g/mol
Monoisotopic Mass:
314.008g/mol
Rotatable Bond Count:
4  
Topological Polar Surface Area:
85A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
2.7  
Literature
Title Journal
Asymmetric allylic monofluoromethylation and methylation of Morita-Baylis-Hillman carbonates with FBSM and BSM by cooperative cinchona alkaloid/FeCl2 catalysis. Angewandte Chemie (International ed. in English) 20111004
Highly enantio- and diastereoselective synthesis of β-methyl-γ-monofluoromethyl-substituted alcohols. Chemistry (Weinheim an der Bergstrasse, Germany) 20110711
Nucleophilic fluoromethylation of aldehydes with fluorobis(phenylsulfonyl)methane: the importance of strong Li-O coordination and fluorine substitution for C-C bond formation. Angewandte Chemie (International ed. in English) 20110307
Synthesis of fluorinated allenes via palladium-catalyzed monofluoromethylation using FBSM. Chemical communications (Cambridge, England) 20091221
Iridium-catalyzed regio- and enantioselective allylic alkylation of fluorobis(phenylsulfonyl)methane. Chemical communications (Cambridge, England) 20091121
Enantioselective organocatalytic conjugate addition of fluorocarbon nucleophiles to alpha,beta-unsaturated aldehydes. Chemistry (Weinheim an der Bergstrasse, Germany) 20091005
Catalytic enantioselective conjugate addition of fluorobis(phenylsulfonyl)methane to enals: synthesis of chiral monofluoromethyl compounds. Chemical communications (Cambridge, England) 20090828
Efficient nucleophilic fluoromethylation and subsequent transformation of alkyl and benzyl halides using fluorobis(phenylsulfonyl)methane. Organic letters 20090305
Nucleophilic fluoroalkylation of alpha,beta-enones, arynes, and activated alkynes with fluorinated sulfones: probing the hard/soft nature of fluorinated carbanions. The Journal of organic chemistry 20080801
Catalytic enantioselective Michael addition of 1-fluorobis(phenylsulfonyl)methane to alpha,beta-unsaturated ketones catalyzed by cinchona alkaloids. Angewandte Chemie (International ed. in English) 20080101
Cinchona alkaloid-catalyzed enantioselective monofluoromethylation reaction based on fluorobis(phenylsulfonyl)methane chemistry combined with a Mannich-type reaction. Journal of the American Chemical Society 20070523
Fluorobis(phenylsulfonyl)methane: a fluoromethide equivalent and palladium-catalyzed enantioselective allylic monofluoromethylation. Angewandte Chemie (International ed. in English) 20060724
Properties