Home Other Building Blocks TRIFLUOROACETALDEHYDE

TRIFLUOROACETALDEHYDE

CAS No.:
75-90-1
Catalog Number:
AG00G42Q
Molecular Formula:
Molecular Weight:
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Purity
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Product Description
Catalog Number:
AG00G42Q
Chemical Name:
TRIFLUOROACETALDEHYDE
CAS Number:
75-90-1
IUPAC Name:
2,2,2-trifluoroacetaldehyde
InChI:
InChI=1S/C2HF3O/c3-2(4,5)1-6/h1H
InChI Key:
JVTSHOJDBRTPHD-UHFFFAOYSA-N
EC Number:
200-914-1
NSC Number:
9446
Properties
Complexity:
54.3  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
97.998g/mol
Formal Charge:
0
Heavy Atom Count:
6  
Hydrogen Bond Acceptor Count:
4  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
98.024g/mol
Monoisotopic Mass:
97.998g/mol
Rotatable Bond Count:
0
Topological Polar Surface Area:
17.1A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
0.8  
Literature
Title Journal
Substituent exchange reactions of linear oligomeric aryloxyphosphazenes with sodium 2,2,2-trifluoroethoxide. Inorganic chemistry 20121105
Intake of ruminant trans fatty acids and changes in body weight and waist circumference. European journal of clinical nutrition 20121001
Enantioselective synthesis of 2,5-dihydrobenzo[b]azepine derivatives via iridium-catalyzed asymmetric allylic amination with 2-allylanilines and ring-closing-metathesis reaction. Organic & biomolecular chemistry 20120814
A remarkable anion effect on palladium nanoparticle formation and stabilization in hydroxyl-functionalized ionic liquids. Physical chemistry chemical physics : PCCP 20120507
Capture of the volatile carbonyl metabolite of flecainide on 2,4-dinitrophenylhydrazine cartridge for quantitation by stable-isotope dilution mass spectrometry coupled with chromatography. Journal of chromatography. A 20120406
Decreased lung hyaluronan in a model of ARDS in the rat: effect of an inhibitor of leukocyte elastase. Upsala journal of medical sciences 20120301
Substituent exchange reactions of trimeric and tetrameric aryloxycyclophosphazenes with sodium 2,2,2-trifluoroethoxide. Dalton transactions (Cambridge, England : 2003) 20120221
Reactive photonic film for label-free and selective sensing of cyanide. Small (Weinheim an der Bergstrasse, Germany) 20120220
Peculiarity of methoxy group-substituted phenylhydrazones in Fischer indole synthesis. Proceedings of the Japan Academy. Series B, Physical and biological sciences 20120111
Enhanced activity of an insecticidal protein, trypsin modulating oostatic factor (TMOF), through conjugation with aliphatic polyethylene glycol. Pest management science 20120101
Novel approach to bile duct damage in primary biliary cirrhosis: participation of cellular senescence and autophagy. International journal of hepatology 20120101
GC-MS and GC-IRD studies on dimethoxyphenethylamines (DMPEA): regioisomers related to 2,5-DMPEA. Journal of chromatographic science 20120101
GC-MS and GC-IRD studies on brominated dimethoxyamphetamines: regioisomers related to 4-Br-2,5-DMA (DOB). Drug testing and analysis 20120101
NiCl2(PMe3)(2)-catalyzed borylation of aryl chlorides. Organic letters 20111104
Liquid chromatography/isotope ratio mass spectrometry measurement of δ13C of amino acids in plant proteins. Rapid communications in mass spectrometry : RCM 20111030
Occurrence of the human tumor-specific antigen structure Galβ1-3GalNAcα- (Thomsen-Friedenreich) and related structures on gut bacteria: prevalence, immunochemical analysis and structural confirmation. Glycobiology 20111001
A cross-sectional study on trans-fatty acids and risk markers of CHD among middle-aged men representing a broad range of BMI. The British journal of nutrition 20111001
Drug design structural alert: formation of trifluoroacetaldehyde through N-dealkylation is linked to testicular lesions in rat. International journal of toxicology 20111001
Synthesis of a new trifluoromethylketone analogue of l-arginine and contrasting inhibitory activity against human arginase I and histone deacetylase 8. Bioorganic & medicinal chemistry letters 20111001
Enantioselective Friedel-Crafts reaction of indoles with trifluoroacetaldehyde catalyzed by Cinchona alkaloids. Chirality 20110901
Gas-phase study of new organozinc reagents by IRMPD-spectroscopy, computational modelling and tandem-MS. Physical chemistry chemical physics : PCCP 20110807
Effect of trans-fatty acid intake on insulin sensitivity and intramuscular lipids--a randomized trial in overweight postmenopausal women. Metabolism: clinical and experimental 20110701
Effect of substituent of β-diketones on the synergistic extraction of lanthanoids with linear polyether. Talanta 20110530
Antifouling activity of commercial biocides vs. natural and natural-derived products assessed by marine bacteria adhesion bioassay. Marine pollution bulletin 20110501
The effect of light, salinity, and nitrogen availability on lipid production by Nannochloropsis sp. Applied microbiology and biotechnology 20110501
Recent advances in pediatric anesthesia. Korean journal of anesthesiology 20110501
Comparison of stationary phases for packed column supercritical fluid chromatography based upon ionic liquid motifs: a study of cation and anion effects. Analytical and bioanalytical chemistry 20110401
Star-shaped tripodal chemosensors for the detection of aliphatic amines. Chemistry (Weinheim an der Bergstrasse, Germany) 20110117
Reversal of diastereoselectivity in reactions of the trifluoroacetaldehyde ethyl hemiacetal with enamines and imines: metal-free, complementary anti- and syn-selective synthesis of 4,4,4-trifluoro-1-aryl-3-hydroxy-2-methyl-1-butanones. The Journal of organic chemistry 20110107
A-D-A-D-A-type oligothiophenes for vacuum-deposited organic solar cells. Organic letters 20110107
Incorporation of 3-aminobenzanthrone into 2'-deoxyoligonucleotides and its impact on duplex stability. Journal of nucleic acids 20110101
A technique combining trifluoroacetyl derivatization and gas chromatography-mass spectrometry to distinguish methamphetamine and its 4-substituted analogs. Journal of mass spectrometry : JMS 20101201
The DAC system and associations with acute leukemias and myelodysplastic syndromes. Investigational new drugs 20101201
GC-MS studies on side chain regioisomers related to substituted methylenedioxyphenethylamines: MDEA, MDMMA, and MBDB. Journal of chromatographic science 20101001
Nitric oxide synthesis is reduced in subjects with type 2 diabetes and nephropathy. Diabetes 20100901
An oxo-bacteriochlorin derivative for long-wavelength fluorescence ratiometric alcohol sensing. The Analyst 20100901
A medicinal chemist's guide to molecular interactions. Journal of medicinal chemistry 20100722
GC-MS and GC-IRD analysis of ring and side chain regioisomers of ethoxyphenethylamines related to the controlled substances MDEA, MDMMA and MBDB. Forensic science international 20100715
Optical basicity of ionic liquids. Physical chemistry chemical physics : PCCP 20100714
Differential impact of milk fatty acid profiles on cardiovascular risk biomarkers in healthy men and women. European journal of clinical nutrition 20100701
Trifluoromethyl nitrones: from fluoral to optically active hydroxylamines. Organic & biomolecular chemistry 20100628
Separation of open-cage fullerenes using nonaqueous capillary electrophoresis. Journal of chromatography. A 20100625
Synthesis of 2-trifluoromethyl-1,3-oxazolidines as hydrolytically stable pseudoprolines. The Journal of organic chemistry 20100618
Generation of T cell responses targeting the reactive metabolite of halothane in mice. Toxicology letters 20100504
Trifluoroacetyl neonicotinoid insecticides with enhanced hydrophobicity and effectiveness. Journal of agricultural and food chemistry 20100428
Trifluoroacetylation-induced Houben-Hoesch-type cyclization of cyanoacetanilides: increased nucleophilicity of CN groups. The Journal of organic chemistry 20100416
Leukotriene D4 activates {beta}2-integrin adhesion in human polymorphonuclear leukocytes. The European respiratory journal 20100201
Contribution of the trifluoroacetyl group in the thermodynamics of antigen-antibody binding. Journal of molecular recognition : JMR 20100101
Quantitation of opioids in blood and urine using gas chromatography-mass spectrometry (GC-MS). Methods in molecular biology (Clifton, N.J.) 20100101
Synthesis of the marine pyrroloiminoquinone alkaloids, discorhabdins. Marine drugs 20100101
Biliary epithelial apoptosis, autophagy, and senescence in primary biliary cirrhosis. Hepatitis research and treatment 20100101
Primary biliary cirrhosis. Seminars in immunopathology 20090901
Synthesis and electrochemical evaluation of conjugates between 2'-deoxyadenosine and modified anthraquinone: probes for hole-transfer studies in DNA. The Journal of organic chemistry 20090703
Comparison of GC-MS and GC-IRD methods for the differentiation of methamphetamine and regioisomeric substances. Forensic science international 20090310
Novel defluorinative alkylation of trifluoroacetaldehyde N,O-acetal derivatives and its application to multi-component reaction. Chemical communications (Cambridge, England) 20090307
IP-10 protects while MIP-2 promotes experimental anesthetic hapten - induced hepatitis. Journal of autoimmunity 20090201
An overview of conventional and emerging analytical methods for the determination of mycotoxins. International journal of molecular sciences 20090101
New clinical developments in histone deacetylase inhibitors for epigenetic therapy of cancer. Journal of hematology & oncology 20090101
Molecular control of HIV-1 postintegration latency: implications for the development of new therapeutic strategies. Retrovirology 20090101
A cavitand with a fluorous rim acts as an amine receptor. Chemical communications (Cambridge, England) 20081221
Solvent effects on the infrared spectra of beta-alkoxyvinyl methyl ketones I. Carbonyl and vinyl stretching vibrations. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20081201
Kinetic studies on the stability and reactivity of beta-amino alkylzinc iodides derived from amino acids. The Journal of organic chemistry 20081121
Alpha-trifluoromethylated carbanion synthons. Accounts of chemical research 20080701
A technetium intermediate specifically promotes deprotection of trifluoroacetyl HYNIC during radiolabelling under mild conditions. Dalton transactions (Cambridge, England : 2003) 20080614
GC-MS studies on acylated derivatives of 3-methoxy-4-methyl- and 4-methoxy-3-methyl-phenethylamines: regioisomers related to 3,4-MDMA. Forensic science international 20080610
Simultaneous determination of a spectrum of trichothecene toxins out of residuals of biogas production. Journal of chromatography. A 20080606
Isomerization of delta-9-THC to delta-8-THC when tested as trifluoroacetyl-, pentafluoropropionyl-, or heptafluorobutyryl- derivatives. Journal of mass spectrometry : JMS 20080501
Comparative analysis of hydrogen bonding with participation of the nitrogen, oxygen and sulfur atoms in the 2(2'-heteroaryl)pyrroles and their trifluoroacetyl derivatives based on the 1H, 13C, 15N spectroscopy and DFT calculations. Magnetic resonance in chemistry : MRC 20080501
Discrimination and identification of the six aromatic positional isomers of trimethoxyamphetamine (TMA) by gas chromatography-mass spectrometry (GC-MS). Journal of mass spectrometry : JMS 20080401
Synthesis of trifluoromethyl-substituted pyrazoles and 1,2,4-triazines by ring transformation of mesoionic 4-trifluoroacetyl-1,3-oxazolium-5-olates with phenylhydrazine. Chemical & pharmaceutical bulletin 20080401
Evaluation of various derivatization approaches for gas chromatography-mass spectrometry analysis of buprenorphine and norbuprenorphine. Journal of chromatography. A 20080222
Intake of ruminant trans fatty acids and risk of coronary heart disease. International journal of epidemiology 20080201
Synthesis and anchoring of antineoplastic ferrocene and phthalocyanine derivatives on water-soluble polymeric drug carriers derived from lysine and aspartic Acid. Metal-based drugs 20080101
Correlation between symmetry breaker position and the preferences of conformationally constrained homopeptides: a molecular dynamics investigation. Biopolymers 20080101
Improved photocontrol of alpha-chymotrypsin activity: peptidomimetic trifluoromethylketone photoswitch enzyme inhibitors. Chemistry (Weinheim an der Bergstrasse, Germany) 20080101
Mechanism-based inhibition of Sir2 deacetylases by thioacetyl-lysine peptide. Biochemistry 20071218
Semi-synthesis of polymyxin B (2-10) and colistin (2-10) analogs employing the Trichloroethoxycarbonyl (Troc) group for side chain protection of alpha,gamma-diaminobutyric acid residues. Chemical & pharmaceutical bulletin 20071201
Case report: fatal hepatic failure after aortic valve replacement and sevoflurane exposure. Canadian journal of anaesthesia = Journal canadien d'anesthesie 20071101
Gas chromatography-mass spectrometry analysis of ketamine and its metabolites--a comparative study on the utilization of different derivatization groups. Journal of chromatography. A 20070720
Complex structure of a bacterial class 2 histone deacetylase homologue with a trifluoromethylketone inhibitor. Acta crystallographica. Section F, Structural biology and crystallization communications 20070401
Bifurcated hydrogen-bonding effect on the shielding and coupling constants in trifluoroacetyl pyrroles as studied by 1H, 13C and 15N NMR spectroscopy and DFT calculations. Magnetic resonance in chemistry : MRC 20070301
Novel trifluoroacetophenone derivatives as malonyl-CoA decarboxylase inhibitors. Bioorganic & medicinal chemistry letters 20070215
Asymmetric syntheses of 1-aryl-2,2,2-trifluoroethylamines via diastereoselective 1,2-addition of arylmetals to 2-methyl-N-(2,2,2-trifluoroethylidene)propane-2-sulfinamide. Organic letters 20070215
Silent cerebral infarct after cardiac catheterization as detected by diffusion weighted Magnetic Resonance Imaging: a randomized comparison of radial and femoral arterial approaches. Trials 20070101
Evaluating coupling procedures for synthesis of lna-Peptide conjugates. Nucleosides, nucleotides & nucleic acids 20070101
Mass spectrometric data characteristics of commonly abused amphetamines with sequential derivatization at two active sites. Forensic science international 20060912
Amination of CF3-enones with nosyloxycarbamates. The Journal of organic chemistry 20060804
Gas-chromatographic separation of stereoisomers of dipeptides. Chirality 20060801
Determination of carbofuran, carbaryl and their main metabolites in plasma samples of agricultural populations using gas chromatography-tandem mass spectrometry. Analytical and bioanalytical chemistry 20060801
Transcellular secretion of group V phospholipase A2 from epithelium induces beta 2-integrin-mediated adhesion and synthesis of leukotriene C4 in eosinophils. Journal of immunology (Baltimore, Md. : 1950) 20060701
Intake of ruminant trans fatty acids and risk of coronary heart disease-an overview. Atherosclerosis. Supplements 20060501
Functional liquid crystal films selectively recognize amine vapours and simultaneously change their colour. Chemical communications (Cambridge, England) 20060414
Selective removal of the 2'- and 3'-O-acyl groups from 2',3',5'-tri-O-acylribonucleoside derivatives with lithium trifluoroethoxide. The Journal of organic chemistry 20060414
Convenient asymmetric synthesis of beta-trifluoromethyl-beta-amino acid, beta-amino ketones, and gamma-amino alcohols via Reformatsky and Mannich-type reactions from 2-trifluoromethyl-1,3-oxazolidines. The Journal of organic chemistry 20060303
Comparison of trifluoroacetyl monostyryl and distyryl dyes: effects of chromophore elongation on the spectral properties and chemical reactivity. Journal of fluorescence 20060301
CFSUM1 and CFSUM2 in urine from patients with chronic fatigue syndrome are methodological artefacts. Clinica chimica acta; international journal of clinical chemistry 20060201
Variability in the structures of [4-(aminomethyl)pyridine]silver(I) complexes through effects of ligand ratio, anion, hydrogen bonding, and pi-stacking. Inorganic chemistry 20060123
Crystallographic studies on two bioisosteric analogues, N-acetyl-beta-D-glucopyranosylamine and N-trifluoroacetyl-beta-D-glucopyranosylamine, potent inhibitors of muscle glycogen phosphorylase. Bioorganic & medicinal chemistry 20060101
Uncharged isocoumarin-based inhibitors of urokinase-type plasminogen activator. BMC chemical biology 20060101
Toxicity and metabolism of the chloral-derived mammalian alkaloid 1-trichloromethyl-1,2,3,4-tetrahydro-beta-carboline (TaClo) in PC12 cells. Zeitschrift fur Naturforschung. C, Journal of biosciences 20060101
Efficient non-viral ocular gene transfer with compacted DNA nanoparticles. PloS one 20060101
Characterization of the lipolytic pathways that mediate free fatty acid release during Fas/CD95-induced apoptosis. Apoptosis : an international journal on programmed cell death 20051201
Isolation of flavanol-anthocyanin adducts by countercurrent chromatography. Journal of chromatographic science 20051001
The chemistry of trifluoromethyl imines and related acetals derived from fluoral. Chemical Society reviews 20050701
Reactions of pyrazolylborate-zinc-hydroxide complexes related to beta-lactamase activity. Inorganic chemistry 20050613
Development of simultaneous gas chromatography-mass spectrometric and liquid chromatography-electrospray ionization mass spectrometric determination method for the new designer drugs, N-benzylpiperazine (BZP), 1-(3-trifluoromethylphenyl)piperazine (TFMPP) and their main metabolites in urine. Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20050525
A novel model of drug hapten-induced hepatitis with increased mast cells in the BALB/c mouse. Experimental and molecular pathology 20050401
ROM polymerization-capture-release strategy for the chromatography-free synthesis of novel unsymmetrical porphyrazines. The Journal of organic chemistry 20050401
Glycosidically bound volatiles and flavor precursors in Laurus nobilis L. Journal of agricultural and food chemistry 20050323
Incorporation of N2-deoxyguanosine metabolic adducts of 2-aminonaphthalene and 2-aminofluorene into oligomeric DNA. Chemical research in toxicology 20050301
O-acylation of hydroxyproline residues: effect on peptide-bond isomerization and collagen stability. Biopolymers 20050101
High throughput purification of amino-modified oligonucleotides and its application to novel detection system of gene expression. Nucleic acids symposium series (2004) 20050101
Gas chromatography-mass spectrometry analysis of trifluoroacetyl derivatives of precursors of nitrogen and sulfur mustards for verification of chemical weapons convention. Journal of chromatography. A 20041203
Capillary gas chromatographic separation of bile acid acyl glycosides without thermal decomposition and isomerization. Journal of chromatography. A 20041119
NMR structures of salt-refolded forms of the 434-repressor DNA-binding domain in 6 M urea. Biochemistry 20041109
Electronic substituent effects on the cleavage specificity of a non-heme Fe(2+)-dependent beta-diketone dioxygenase and their mechanistic implications. Journal of the American Chemical Society 20041006
Synthesis of 2-quinolones via palladium-catalyzed carbonylative annulation of internal alkynes by N-substituted o-iodoanilines. The Journal of organic chemistry 20041001
Practical asymmetric synthesis of beta-hydroxy-beta-trifluoromethylated ketones via the first example of the in situ generation of trifluoro-acetaldehyde and its successive asymmetric carbon-carbon bond formation reaction with chiral imines. Chemical communications (Cambridge, England) 20040921
Stable helical polyguanidines: poly[N-(1-anthryl)-N'-[(R)- and/or (S)-3,7-dimethyloctyl]guanidines]. Journal of the American Chemical Society 20040331
Trifluoroacetyl-activated nitrogen-nitrogen bond cleavage of hydrazines by samarium(II) iodide. Organic letters 20040219
Theoretical study of the spin trapping of hydroxyl radical by cyclic nitrones: a density functional theory approach. Journal of the American Chemical Society 20040218
Is there a weak H-bond --> LBHB transition on tetrahedral complex formation in serine proteases? Proteins 20040215
[Identification of narcotics in urine by capillary gas chromatography]. Sudebno-meditsinskaia ekspertiza 20040101
Derivatisation of 4-nonylphenol and bisphenol A with halogenated anhydrides. Water science and technology : a journal of the International Association on Water Pollution Research 20040101
Juvenile hormone (JH) esterase: why are you so JH specific? Insect biochemistry and molecular biology 20031201
Trifluoroacetyl as an orthogonal protecting group for guanidines. The Journal of organic chemistry 20031128
Use of classical and 3-D QSAR to examine the hydration state of juvenile hormone esterase inhibitors. Bioorganic & medicinal chemistry 20031117
Signal transduction pathways involved in proteolysis-inducing factor induced proteasome expression in murine myotubes. British journal of cancer 20031103
Absolute configuration of 2-sec-butyl-4,5-dihydrothiazole in male mouse urine. Chemical senses 20031101
Investigation of liquid and gas chromatography techniques for separation of diastereomers of beta-(alpha-methylbenzyl) amino isobutyric acid. Journal of chromatographic science 20030901
The rate of elimination of a beta-amino zinc reagent is reduced by using a better leaving group. Chemical communications (Cambridge, England) 20030607
Pentafluoropropionyl and trifluoroacetyl groups for temporary hydroxyl group protection in oligomannoside synthesis. Carbohydrate research 20030501
Efficient [3,3]-sigmatropic rearrangement accelerated by a trifluoroacetyl group: synthesis of benzofurans under mild conditions. Organic & biomolecular chemistry 20030121
Application of tandem mass spectrometry combined with gas chromatography and headspace solid-phase dynamic extraction for the determination of drugs of abuse in hair samples. Rapid communications in mass spectrometry : RCM 20030101
Solid-phase parallel synthesis of 17alpha-substituted estradiol sulfamate and phenol libraries using the multidetachable sulfamate linker. Journal of combinatorial chemistry 20030101
Synthesis, structure, and reactivity of some sterically hindered (Silylamino)phosphines. Inorganic chemistry 20021230
Characterization of the macrocyclic carbon suboxide factors as potent Na,K-ATPase and SR Ca-ATPase inhibitors. Biochimica et biophysica acta 20021223
Quantitative GC analysis of secondary alcohol pheromones: determination of release rate of red palm weevil, Rhynchophorus ferrugineus, pheromone from lures. Journal of chemical ecology 20021101
Introduction of a hydroxy group at the para position and N-iodophenylation of N-arylamides using phenyliodine(III) bis(trifluoroacetate). The Journal of organic chemistry 20021018
N-to-C solid-phase peptide and peptide trifluoromethylketone synthesis using amino acid tert-butyl esters. Chemical & pharmaceutical bulletin 20020501
Reactivity of stable trifluoroacetaldehyde hemiaminals. 2. Generation and synthetic potentialities of fluorinated iminiums. The Journal of organic chemistry 20020208
A parallel processing solid phase extraction protocol for the determination of whole blood folate. Analytical biochemistry 20020201
Analysis of glycosidically bound aroma precursors in tea leaves. 3. Change in the glycoside content of tea leaves during the oolong tea manufacturing process. Journal of agricultural and food chemistry 20011101
Regulation of eosinophil function by phosphatidylinositol-specific PLC and cytosolic PLA(2). American journal of physiology. Lung cellular and molecular physiology 20011001
19F NMR of trifluoroacetyl-labeled cysteine mutants of myoglobin: structural probes of nitric oxide bound to the H93G cavity mutant. Biochemistry 20010724
A simple and versatile one-pot synthesis of meso-substituted trans-A2B-corroles. The Journal of organic chemistry 20010615
Critical study of and improvements in chromatographic methods for the analysis of type B trichothecenes. Journal of chromatography. A 20010518
Efficient asymmetric synthesis of alpha-trifluoromethyl-substituted primary amines via nucleophilic 1,2-addition to trifluoroacetaldehyde SAMP- or RAMP-hydrazone. Organic letters 20010517
Identification of a juvenile hormone esterase gene by matching its peptide mass fingerprint with a sequence from the Drosophila genome project. Insect biochemistry and molecular biology 20010427
Analysis of glycosidically bound aroma precursors in tea leaves. 2. Changes in glycoside contents and glycosidase activities in tea leaves during the black tea manufacturing process. Journal of agricultural and food chemistry 20010401
Properties