Home Other Building Blocks (R)-2,2',3,3'-Tetrahydro-1,1'-spirobi[indene]-7,7'-diol

(R)-2,2',3,3'-Tetrahydro-1,1'-spirobi[indene]-7,7'-diol

CAS No.:
223259-62-9
Catalog Number:
AG00BBYO
Molecular Formula:
Molecular Weight:
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
1g
>98.0%(GC)
1 week
United States
$3557
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Product Description
Catalog Number:
AG00BBYO
Chemical Name:
(R)-2,2',3,3'-Tetrahydro-1,1'-spirobi[indene]-7,7'-diol
CAS Number:
223259-62-9
MDL Number:
MFCD31714175
IUPAC Name:
3,3'-spirobi[1,2-dihydroindene]-4,4'-diol
InChI:
InChI=1S/C17H16O2/c18-13-5-1-3-11-7-9-17(15(11)13)10-8-12-4-2-6-14(19)16(12)17/h1-6,18-19H,7-10H2
InChI Key:
YBRDFCQKQVTQKX-UHFFFAOYSA-N
Properties
Complexity:
319  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
252.115g/mol
Formal Charge:
0
Heavy Atom Count:
19  
Hydrogen Bond Acceptor Count:
2  
Hydrogen Bond Donor Count:
2  
Isotope Atom Count:
0
Molecular Weight:
252.313g/mol
Monoisotopic Mass:
252.115g/mol
Rotatable Bond Count:
0
Topological Polar Surface Area:
40.5A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
4.1  
Literature
Title Journal
Optically active 1,1'-spirobiindane-7,7'-diol (SPINOL)-based phosphoric acids as highly enantioselective catalysts for asymmetric organocatalysis. The Journal of organic chemistry 20110520
Sequential aldol condensation-transition metal-catalyzed addition reactions of aldehydes, methyl ketones, and arylboronic acids. Organic letters 20110415
SPINOL-derived phosphoric acids: synthesis and application in enantioselective Friedel-Crafts reaction of indoles with imines. The Journal of organic chemistry 20101217
Chiral diphosphine and monodentate phosphorus ligands on a spiro scaffold for transition-metal-catalyzed asymmetric reactions. Accounts of chemical research 20080501
Asymmetric hydrogenation of quinolines with high substrate/catalyst ratio. Chemical communications (Cambridge, England) 20070214
Synthesis and application of chiral spiro phospholane ligand in Pd-catalyzed asymmetric allylation of aldehydes with allylic alcohols. Organic letters 20050609
Synthesis of monodentate chiral spiro phosphonites and the electronic effect of ligand in asymmetric hydrogenation. The Journal of organic chemistry 20041112
Rhodium-catalyzed asymmetric hydrogenation of functionalized olefins using monodentate spiro phosphoramidite ligands. The Journal of organic chemistry 20040709
Highly enantioselective copper-catalyzed conjugate addition of diethylzinc to enones using chiral spiro phosphoramidites as ligands. The Journal of organic chemistry 20030221
Properties