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Home Other Building Blocks Tris(trimethylsilyl)silane

Tris(trimethylsilyl)silane

CAS No.:
1873-77-4
Catalog Number:
AG003V8L
Molecular Formula:
C9H28Si4
Molecular Weight:
248.6606
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
1g
95%
In Stock USA
United States
$63
- +
5g
95%
In Stock USA
United States
$188
- +
25g
95%
In Stock USA
United States
$513
- +
Product Description
Catalog Number:
AG003V8L
Chemical Name:
Tris(trimethylsilyl)silane
CAS Number:
1873-77-4
Molecular Formula:
C9H28Si4
Molecular Weight:
248.6606
MDL Number:
MFCD00077893
InChI:
InChI=1S/C9H27Si4/c1-11(2,3)10(12(4,5)6)13(7,8)9/h1-9H3
InChI Key:
SCHZCUMIENIQMY-UHFFFAOYSA-N
SMILES:
C[Si]([SiH]([Si](C)(C)C)[Si](C)(C)C)(C)C
Properties
Complexity:
134  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
247.119g/mol
Formal Charge:
0
Heavy Atom Count:
13  
Hydrogen Bond Acceptor Count:
0
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
247.655g/mol
Monoisotopic Mass:
247.119g/mol
Rotatable Bond Count:
3  
Topological Polar Surface Area:
0A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
Literature
Title Journal
Recent applications of the (TMS)3SiH radical-based reagent. Molecules (Basel, Switzerland) 20120106
Safe, facile radical-based reduction and hydrosilylation reactions in a microreactor using tris(trimethylsilyl)silane. Chemical communications (Cambridge, England) 20080714
'Super silyl' group for diastereoselective sequential reactions: access to complex chiral architecture in one pot. Journal of the American Chemical Society 20070314
Synthesis of 2,4-disubstituted piperidines via radical cyclization: unexpected enhancement in diastereoselectivity with tris(trimethylsilyl)silane. The Journal of organic chemistry 20060707
Tris(trimethylsilyl)silane: an unprecedented enhancement in the diastereoselectivity of radical cyclisations to give 2,4-disubstituted piperidines. Organic & biomolecular chemistry 20040821
Properties