Home Other Building Blocks Trimethyl Phosphite

Trimethyl Phosphite

CAS No.:
121-45-9
Catalog Number:
AG003V3F
Molecular Formula:
C3H9O3P
Molecular Weight:
124.0755
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
5g
95%
In Stock USA
United States
$33
- +
25g
95%
In Stock USA
United States
$47
- +
100g
95%
In Stock USA
United States
$87
- +
Product Description
Catalog Number:
AG003V3F
Chemical Name:
Trimethyl Phosphite
CAS Number:
121-45-9
Molecular Formula:
C3H9O3P
Molecular Weight:
124.0755
MDL Number:
MFCD00008350
IUPAC Name:
trimethyl phosphite
InChI:
InChI=1S/C3H9O3P/c1-4-7(5-2)6-3/h1-3H3
InChI Key:
CYTQBVOFDCPGCX-UHFFFAOYSA-N
SMILES:
COP(OC)OC
EC Number:
204-471-5
UNII:
26Q0321ZDG
NSC Number:
6513
RTECS Number:
TH1400000
UN Number:
2329
Properties
Complexity:
31.7  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
124.029g/mol
Formal Charge:
0
Heavy Atom Count:
7  
Hydrogen Bond Acceptor Count:
3  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
124.076g/mol
Monoisotopic Mass:
124.029g/mol
Rotatable Bond Count:
3  
Topological Polar Surface Area:
27.7A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
0.1  
Literature
Title Journal
Reductive functionalization of carbon dioxide to methyl acrylate at zerovalent tungsten. Dalton transactions (Cambridge, England : 2003) 20120921
Oxidation of phosphorus centers by ferrate(VI): spectral observation of an intermediate. Inorganic chemistry 20120618
Dust as a collection media for contaminant source attribution. Forensic science international 20120410
Conformations of trimethyl phosphite: a matrix isolation infrared and ab initio study. The journal of physical chemistry. A 20110908
Correlation between the rate order and the number of molecules in the reaction of trimethyl phosphite with water in acetonitrile solvent. The journal of physical chemistry. A 20101104
CO insertion in lithiated diene-tricarbonyliron complexes. Chemical communications (Cambridge, England) 20100721
An overview of recent development in composite catalysts from porous materials for various reactions and processes. International journal of molecular sciences 20100101
Rapid modification of the insect elicitor N-linolenoyl-glutamate via a lipoxygenase-mediated mechanism on Nicotiana attenuata leaves. BMC plant biology 20100101
cis-Dichlorido-bis(trimethoxy-phos-phine)palladium(II) at 125 K. Acta crystallographica. Section E, Structure reports online 20091101
cis-Dichloridobis(triisopropoxy-phosphine)-platinum(II). Acta crystallographica. Section E, Structure reports online 20091101
Methyl [hydr-oxy(phen-yl)phosphono-meth-yl]phospho-nate methanol solvate. Acta crystallographica. Section E, Structure reports online 20081001
Alkylamine sensing using langmuir-blodgett films of n-alkyl-N-phenylamide-substituted zinc porphyrins. The journal of physical chemistry. B 20080911
Dinuclear Cp* cobalt complexes of the 1,2,4,5-benzenetetrathiolate bischelating ligand. Inorganic chemistry 20080218
Electron-rich heteroaroylphosphonates and their reaction with trimethyl phosphite. Organic & biomolecular chemistry 20080207
17O NMR investigation of phosphite hydrolysis mechanisms. Magnetic resonance in chemistry : MRC 20071201
Mechanism of the sulfurisation of phosphines and phosphites using 3-amino-1,2,4-dithiazole-5-thione (xanthane hydride). Organic & biomolecular chemistry 20070207
Tuning haptotropic rearrangements of arene-chromium complexes: steric and electronic effects of phosphorus coligands. Chemistry (Weinheim an der Bergstrasse, Germany) 20050905
Gas-phase reactivity of the O=P(OCH3)2 + phosphonium ion towards alpha,beta-unsaturated esters in a quadrupole ion trap. Journal of mass spectrometry : JMS 20050401
New modification of the Perkow reaction: halocarboxylate anions as leaving groups in 3-acyloxyquinoline-2,4(1H,3H)-dione compounds. Beilstein journal of organic chemistry 20050101
Synthesis of mono- and disaccharide analogs of moenomycin and lipid II for inhibition of transglycosylase activity of penicillin-binding protein 1b. Bioorganic & medicinal chemistry 20041215
[Studies on the reactions of unsaturated chloride polyether polyol with trimethyl phosphite by FTIR]. Guang pu xue yu guang pu fen xi = Guang pu 20041101
Stereoselective palladium-catalyzed O-glycosylation using glycals. Journal of the American Chemical Society 20040211
[Hygienic standards of the occupational air quality established by the Experts on Chemical Agents, 2002]. Medycyna pracy 20040101
Cobalt-catalyzed cycloisomerization of 1,6-enynes and allyl propargyl ethers. Organic letters 20030710
Synthesis and acid-base properties of (1H-benzimidazol-2-yl-methyl)phosphonate (Bimp2-). Evidence for intramolecular hydrogen-bond formation in aqueous solution between (N-1)H and the phosphonate group. Organic & biomolecular chemistry 20030521
Trimethyl phosphite as a trap for alkoxy radicals formed from the ring opening of oxiranylcarbinyl radicals. Conversion to alkenes. Mechanistic applications to the study of C-C versus C-O ring cleavage. Journal of the American Chemical Society 20030319
Reaction between naphthols and dimethyl acetylenedicarboxylate in the presence of phosphites. Synthesis of stable oxa-2 lambda 5-phosphaphenanthrenes, and benzochromene derivatives. Organic & biomolecular chemistry 20030207
Gas-phase reactivity of the O=P(OCH3)2+ phosphonium ion with aliphatic esters in a quadrupole ion trap. Spontaneous elimination of ketenes. Journal of mass spectrometry : JMS 20020901
Electronic and medium effects on the rate of arene C [bond] H activation by cationic Ir(III) complexes. Journal of the American Chemical Society 20020220
Gas-phase ion/molecule reactions between dimethoxyphosphonium ions and aromatic hydrocarbons. Rapid communications in mass spectrometry : RCM 20020101
Synthesis of glycosyl phosphoramidates: novel isosteric analogues of glycosyl phosphates. Bioorganic & medicinal chemistry letters 20010917
Copper-mediated cross-coupling of functionalized arylmagnesium reagents with functionalized alkyl and benzylic halides. Organic letters 20010906
Properties