Home Other Building Blocks tert-Butyl formate

tert-Butyl formate

CAS No.:
762-75-4
Catalog Number:
AG003UKO
Molecular Formula:
Molecular Weight:
Pack Size
Purity
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Product Description
Catalog Number:
AG003UKO
Chemical Name:
tert-Butyl formate
CAS Number:
762-75-4
MDL Number:
MFCD00003290
IUPAC Name:
tert-butyl formate
InChI:
InChI=1S/C5H10O2/c1-5(2,3)7-4-6/h4H,1-3H3
InChI Key:
RUPAXCPQAAOIPB-UHFFFAOYSA-N
EC Number:
212-105-0
Properties
Complexity:
61  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
102.068g/mol
Formal Charge:
0
Heavy Atom Count:
7  
Hydrogen Bond Acceptor Count:
2  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
102.133g/mol
Monoisotopic Mass:
102.068g/mol
Rotatable Bond Count:
2  
Topological Polar Surface Area:
26.3A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
1.1  
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tert-Butyl 6-benzoyl-5-hydr-oxy-2-oxo-2H-chromene-4-carboxyl-ate. Acta crystallographica. Section E, Structure reports online 20080701
Effect of oxidant-to-substrate ratios on the degradation of MTBE with Fenton reagent. Water research 20080601
High specific activity tritium-labeled N-(2-methoxybenzyl)-2,5-dimethoxy-4-iodophenethylamine (INBMeO): a high-affinity 5-HT2A receptor-selective agonist radioligand. Bioorganic & medicinal chemistry 20080601
Efficient total synthesis of (+)-negamycin, a potential chemotherapeutic agent for genetic diseases. Chemical communications (Cambridge, England) 20080528
Oxygen-atom transfer from carbon dioxide to a Fischer carbene at (PNP)Ir. Journal of the American Chemical Society 20080507
[Degradation of methyl tert-butyl ether (MTBE) by O3/H2O2]. Huan jing ke xue= Huanjing kexue 20080501
Synthesis and biological evaluation of a novel pentagastrin-toxin conjugate designed for a targeted prodrug mono-therapy of cancer. International journal of molecular sciences 20080501
VEGF 165 b, an antiangiogenic VEGF-A isoform, binds and inhibits bevacizumab treatment in experimental colorectal carcinoma: balance of pro- and antiangiogenic VEGF-A isoforms has implications for therapy. British journal of cancer 20080422
Conformational change from antiparallel beta-sheet to alpha-helix in a series of depsipeptide, -(Leu-Leu-Lac)(n)-: syntheses, spectroscopic studies, and crystal structures of Boc-Leu-Lac-OEt and Boc-(Leu-Leu-Lac)(n)-OEt (n = 1, 2). Biopolymers 20080401
Immunohistochemical characterization of guided bone regeneration at a dehiscence-type defect using different barrier membranes: an experimental study in dogs. Clinical oral implants research 20080401
[Botryoid odontogenic cyst]. Revue de stomatologie et de chirurgie maxillo-faciale 20080401
H-d-Phe-d-Pro-Gly methyl ester hydro-chloride monohydrate. Acta crystallographica. Section E, Structure reports online 20080401
Development of a liposaccharide-based delivery system and its application to the design of group A streptococcal vaccines. Journal of medicinal chemistry 20080313
Emerging rules for subunit-based, multiantigenic, multistage chemically synthesized vaccines. Accounts of chemical research 20080301
Synthesis of a versatile constrained analogue of dipeptide DG (Asp-Gly). Amino acids 20080201
Chiral-catalyst-based convergent synthesis of HIV protease inhibitor GRL-06579A. Chemistry, an Asian journal 20080201
Chemical synthesis of a glycoprotein having an intact human complex-type sialyloligosaccharide under the Boc and Fmoc synthetic strategies. Journal of the American Chemical Society 20080116
Inequality of use of cancer genetics services by members of breast, ovarian and colorectal cancer families in South East Scotland. Familial cancer 20080101
Synthesis and characterisation of helical beta-peptide architectures that contain (S)-beta3-HDOPA(Crown Ether) derivatives. Chemistry (Weinheim an der Bergstrasse, Germany) 20080101
Characterization of global transcription profile of normal and HPV-immortalized keratinocytes and their response to TNF treatment. BMC medical genomics 20080101
Differential screening identifies transcripts with depot-dependent expression in white adipose tissues. BMC genomics 20080101
Anti-plasmodium activity of angiotensin II and related synthetic peptides. PloS one 20080101
Differential gene expression associated with postnatal equine articular cartilage maturation. BMC musculoskeletal disorders 20080101
Stereotactic body radiation therapy with or without transarterial chemoembolization for patients with primary hepatocellular carcinoma: preliminary analysis. BMC cancer 20080101
Induction of cytotoxicity, apoptosis and cell cycle arrest by 1-t-butyl carbamoyl, 7-methyl-indole-3-ethyl isothiocyanate (NB7M) in nervous system cancer cells. Drug design, development and therapy 20080101
Long-term effect of yogic practices on diurnal metabolic rates of healthy subjects. International journal of yoga 20080101
Triazine dendrimers with orthogonally protected amines on the periphery. Masking amines with Dde and BOC groups provides an alternative to carrying protected alcohols and disulfides through an iterative synthesis. The Journal of organic chemistry 20071221
Structure-activity relationships of adenosines with heterocyclic N6-substituents. Bioorganic & medicinal chemistry letters 20071215
Guided bone regeneration at dehiscence-type defects using biphasic hydroxyapatite + beta tricalcium phosphate (Bone Ceramic) or a collagen-coated natural bone mineral (BioOss Collagen): an immunohistochemical study in dogs. International journal of oral and maxillofacial surgery 20071201
Botryoid odontogenic cyst: clinical and pathological analysis in relation to recurrence. Medicina oral, patologia oral y cirugia bucal 20071201
Rheumatic heart disease: 15 years of clinical and immunological follow-up. Vascular health and risk management 20071201
Keck Foundation Biotechnology Resource Laboratory, Yale University. The Yale journal of biology and medicine 20071201
Enhancement of oral drug absorption-effect of lipid conjugation on the enzymatic stability and intestinal permeability of l-Glu-l-Trp-NH(2). Bioorganic & medicinal chemistry 20071115
Synthesis procedure for routine production of 2-[18F]fluoro-3-(2(S)-azetidinylmethoxy)pyridine (2-[18F]F-A-85380). Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine 20071101
Fluorous-tagged carbamates for the pd-catalyzed amination of aryl halides. The Journal of organic chemistry 20071012
Effect of chlorides and sulfates on the performance of a Fe3+/H2O2 Fenton-like system in the degradation of methyl tert-butyl ether and its byproducts. Water environment research : a research publication of the Water Environment Federation 20071001
Influence of young age at diagnosis and family history of breast or ovarian cancer on breast cancer outcomes in a population-based cohort study. Breast cancer research and treatment 20070901
A population-based job exposure matrix for power-frequency magnetic fields. Journal of occupational and environmental hygiene 20070901
Influence of inorganic ions on MTBE degradation by Fenton's reagent. Journal of hazardous materials 20070817
An alpha-fetoprotein-derived peptide reduces the uterine hyperplasia and increases the antitumour effect of tamoxifen. British journal of cancer 20070806
Synthesis and solid-phase application of suitably protected gamma-hydroxyvaline building blocks. The Journal of organic chemistry 20070720
Resin-bound sulfonyl azides: efficient loading and activation strategy for the preparation of the N-acyl sulfonamide linker. The Journal of organic chemistry 20070608
Direct access to N-H-aziridines from asymmetric catalytic aziridination with borate catalysts derived from vaulted binaphthol and vaulted biphenanthrol ligands. Journal of the American Chemical Society 20070606
Catalytic asymmetric phase-transfer Michael reaction and Mannich-type reaction of glycine Schiff bases with tartrate-derived diammonium salts. Chemistry, an Asian journal 20070604
Quantification of growth factors in allogenic bone grafts extracted with three different methods. Cell and tissue banking 20070601
Degradation of methyl tertiary-butyl ether (MTBE) by anodic Fenton treatment. Journal of hazardous materials 20070601
Comparison of procedures for directly obtaining protected peptide acids from peptide-resins. Journal of peptide science : an official publication of the European Peptide Society 20070601
RGD targeted poly(L-glutamic acid)-cystamine-(Gd-DO3A) conjugate for detecting angiogenesis biomarker alpha(v) beta3 integrin with MRT, mapping. International journal of nanomedicine 20070601
Sub-micrometer patterning of proteins by electric lithography. Langmuir : the ACS journal of surfaces and colloids 20070410
EPR study of copper(II) complexes of hydroxysalen derivatives in order to be used in the DNA cleavage. Journal of photochemistry and photobiology. B, Biology 20070301
Mixed-sequence pyrrolidine-amide oligonucleotide mimics: Boc(Z) synthesis and DNA/RNA binding properties. Organic & biomolecular chemistry 20070121
Preparation of N-tBoc L-glutathione dimethyl and di-tert-butyl esters: versatile synthetic building blocks. Bioorganic & medicinal chemistry 20070115
Enantioselective fluorination of tert-butoxycarbonyl lactones and lactams catalyzed by chiral Pd(II)-bisphosphine complexes. The Journal of organic chemistry 20070105
Proline-catalyzed mannich reaction of aldehydes with N-boc-imines. Angewandte Chemie (International ed. in English) 20070101
Theoretical evidence for pyramidalized bicyclic serine enolates in highly diastereoselective alkylations. Chemistry (Weinheim an der Bergstrasse, Germany) 20070101
Synthesis of the functionalizable methionine surrogate azidohomoalanine using Boc-homoserine as precursor. Nature protocols 20070101
Practical Proline-catalyzed asymmetric Mannich reaction of aldehydes with N-Boc-imines. Nature protocols 20070101
Organocatalytic asymmetric Mannich reactions with N-Boc and N-Cbz protected alpha-amido sulfones (Boc: tert-butoxycarbonyl, Cbz: benzyloxycarbonyl). Chemistry (Weinheim an der Bergstrasse, Germany) 20070101
Temperature effect on tert-butyl alcohol (TBA) biodegradation kinetics in hyporheic zone soils. Biomedical engineering online 20070101
Diastereoselective addition of enantiopure lithium tert-butylsulfinylferrocene to imines. The Journal of organic chemistry 20061222
A flow reactor process for the synthesis of peptides utilizing immobilized reagents, scavengers and catch and release protocols. Chemical communications (Cambridge, England) 20061214
Simultaneous determination of methyl tert-butyl ether, its degradation products and other gasoline additives in soil samples by closed-system purge-and-trap gas chromatography-mass spectrometry. Journal of chromatography. A 20061103
Chiral interaction in Gly-capped N-terminal motif of 3(10)-helix and domino-type induction in helix sense. Biopolymers 20061101
Colorimetric anion sensing and color imaging based on catalyzed deprotection in a new azonaphthol chromophore. Journal of nanoscience and nanotechnology 20061101
Advances in analytical techniques for polychlorinated dibenzo-p-dioxins, polychlorinated dibenzofurans and dioxin-like PCBs. Analytical and bioanalytical chemistry 20061001
Intraoperative monitoring study of ipsilateral motor evoked potentials in scoliosis surgery. European spine journal : official publication of the European Spine Society, the European Spinal Deformity Society, and the European Section of the Cervical Spine Research Society 20061001
Missense mutations of BRCA1 gene affect the binding with p53 both in vitro and in vivo. Oncology reports 20061001
Determination of naturally occurring MTBE biodegradation by analysing metabolites and biodegradation by-products. Journal of contaminant hydrology 20060910
Immunogenicity of synthetic peptides derived from Plasmodium falciparum proteins. Experimental parasitology 20060801
The chemistry of nitrogen coordinated tertiary carboxamides: a spectroscopic study on bis(picolyl)amidecopper(II) complexes. Dalton transactions (Cambridge, England : 2003) 20060714
[Synthesis of 5-fluorouracil derivatives containing alkanoic acid]. Sichuan da xue xue bao. Yi xue ban = Journal of Sichuan University. Medical science edition 20060701
Correlating electronic properties of bimetallic surfaces with reaction pathways of C2 hydrocarbons. The journal of physical chemistry. B 20060622
t-Butyloxycarbonyl: an ordinary but promising group for protecting peptides from deiodination. Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine 20060601
Synthesis of a glycosylated peptide thioester by the Boc strategy and its application to segment condensation. Bioscience, biotechnology, and biochemistry 20060601
Alpha-selenoconotoxins, a new class of potent alpha7 neuronal nicotinic receptor antagonists. The Journal of biological chemistry 20060519
Synthesis, stability and optimized photolytic cleavage of 4-methoxy-2-nitrobenzyl backbone-protected peptides. Chemical communications (Cambridge, England) 20060414
Isolation and characterization of a new Mycobacterium austroafricanum strain, IFP 2015, growing on MTBE. Applied microbiology and biotechnology 20060401
Simultaneous decontamination of hexavalent chromium and methyl tert-butyl ether by UV/TiO2 process. Chemosphere 20060401
Energy transfer in calixarene-based cofacial-positioned perylene bisimide arrays. Journal of the American Chemical Society 20060329
Mitsunobu dehydration of N-Boc neomycin B. Organic & biomolecular chemistry 20060107
Stabilization of unusual structures in peptides using alpha,beta-dehydrophenylalanine: crystal and solution structures of Boc-Pro-DeltaPhe-Val-DeltaPhe-Ala-OMe and Boc-Pro-DeltaPhe-Gly-DeltaPhe-Ala-OMe. Biopolymers 20060101
Tandem electrospray mass spectrometric studies of proton and sodium ion adducts of neutral peptides with modified N- and C-termini: synthetic model peptides and microheterogeneous peptaibol antibiotics. Rapid communications in mass spectrometry : RCM 20060101
2-(N-Fmoc)-3-(N-Boc-N-methoxy)-diaminopropanoic acid, an amino acid for the synthesis of mimics of O-linked glycopeptides. Biopolymers 20060101
Year in review 2005: Critical Care--respirology: mechanical ventilation, infection, monitoring, and education. Critical care (London, England) 20060101
The effect of long term combined yoga practice on the basal metabolic rate of healthy adults. BMC complementary and alternative medicine 20060101
Electrochemically generated acid and its containment to 100 micron reaction areas for the production of DNA microarrays. PloS one 20060101
Programming the internal structure and stability of helical pores self-assembled from dendritic dipeptides via the protective groups of the peptide. Journal of the American Chemical Society 20051221
N-triazinylammonium tetrafluoroborates. A new generation of efficient coupling reagents useful for peptide synthesis. Journal of the American Chemical Society 20051207
A highly directional fourfold hydrogen-bonding motif for supramolecular structures through self-assembly of fullerodendrimers. Chemistry (Weinheim an der Bergstrasse, Germany) 20051104
Fate of gasoline oxygenates in conventional and multilevel wells of a contaminated groundwater table in Düsseldorf, Germany. Environmental toxicology and chemistry 20051101
Copper-catalyzed synthesis of medium- and large-sized nitrogen heterocycles via N-arylation of phosphoramidates and carbamates. Organic letters 20051013
Solid-phase extraction as a tool to remove impurities and small fragments from synthetic peptides. Analytical biochemistry 20050901
Botryoid odontogenic cyst: report of a case with extensive epithelial proliferation. International journal of oral and maxillofacial surgery 20050901
Hydrogen-mediated reductive coupling of conjugated alkynes with ethyl (N-Sulfinyl)iminoacetates: synthesis of unnatural alpha-amino acids via rhodium-catalyzed C-C bond forming hydrogenation. Journal of the American Chemical Society 20050817
Synthesis, solution equilibria and antiproliferative activity of copper(II) aminomethyltriazole and aminomethylthioxotriazoline complexes. Journal of inorganic biochemistry 20050801
An excimer emission approach for patterned fluorescent imaging. Chemical communications (Cambridge, England) 20050721
Synthesis and activity of 2-oxoamides containing long chain beta-amino acids. Journal of peptide science : an official publication of the European Peptide Society 20050701
Amino acid deletion products resulting from incomplete deprotection of the Boc group from Npi-benzyloxymethylhistidine residues during solid-phase peptide synthesis. Journal of peptide science : an official publication of the European Peptide Society 20050701
Accurate, two-state ab initio study of the ground and first-excited states of He2+, including exact treatment of all Born-Oppenheimer correction terms. The Journal of chemical physics 20050508
Biotinylated GHK peptide incorporated collagenous matrix: A novel biomaterial for dermal wound healing in rats. Journal of biomedical materials research. Part B, Applied biomaterials 20050501
Synthesis, enantiomeric resolution, F-18 labeling and biodistribution of reboxetine analogs: promising radioligands for imaging the norepinephrine transporter with positron emission tomography. Nuclear medicine and biology 20050501
Predicting methyl tert-butyl ether, tert-butyl formate, and tert-butyl alcohol levels in the environment using the fugacity approach. Environmental science & technology 20050501
Enzymatic removal of carboxyl protecting groups. 1. Cleavage of the tert-butyl moiety. The Journal of organic chemistry 20050429
No auxiliary, no byproduct strategy for water-soluble prodrugs of taxoids: scope and limitation of O-N intramolecular acyl and acyloxy migration reactions. Journal of medicinal chemistry 20050407
Toward semisynthetic lipoproteins by convergent strategies based on click and ligation chemistry. Chembiochem : a European journal of chemical biology 20050401
Elucidation of the presence and location of t-Boc protecting groups in amines and dipeptides using on-column H/D exchange HPLC/ESI/MS. Journal of the American Society for Mass Spectrometry 20050401
Amphiphilic polymethacrylate derivatives as antimicrobial agents. Journal of the American Chemical Society 20050330
Cadmium(II) and mercury(II) complexes of an NO2S2-donor macrocycle and its ditopic xylyl-bridged analogue. Dalton transactions (Cambridge, England : 2003) 20050221
Beta-turn mimic in tripeptide with Phe(1)-Aib(2) as corner residues and beta-strand structure in an isomeric tripeptide: an X-ray diffraction study. Organic & biomolecular chemistry 20050221
The architecture of protein-ligand binding sites revealed through template-assisted intramolecular peptide-peptide interactions. Angewandte Chemie (International ed. in English) 20050218
Spin adduct formation from lipophilic EMPO-derived spin traps with various oxygen- and carbon-centered radicals. Biochemical pharmacology 20050115
Oxidation kinetics and effect of pH on the degradation of MTBE with Fenton reagent. Water research 20050101
Toward the next-generation drug delivery vehicle: synthesis of a dendrimer with four orthogonally reactive groups. Molecular pharmaceutics 20050101
Multicystic lateral periodontal cyst and botryoid odontogenic cyst. Multifactorial analysis of previously unreported series and review of literature. The New York state dental journal 20050101
The removal of the t-BOC group by electrochemically generated acid and use of an addressable electrode array for peptide synthesis. Journal of combinatorial chemistry 20050101
L-Phe end-capped poly(L-lactide) as macroinitiator for the synthesis of poly(L-lactide)-B-poly(L-lysine) block copolymer. Biomacromolecules 20050101
Rapid deprotection of N-Boc amines by TFA combined with freebase generation using basic ion-exchange resins. Molecular diversity 20050101
Alternative method of Boc-removal from sulfamide using silica-phenyl sulfonic acid in conjunction with microwave heating. Molecular diversity 20050101
N-h insertion reactions of Boc-amino acid amides: solution- and solid-phase synthesis of pyrazinones and pyrazines. Organic letters 20041125
A new strategy to produce beta-peptides: use of alicyclic beta-lactams. Organic letters 20041111
Novel urea-linked cinchona-calixarene hybrid-type receptors for efficient chromatographic enantiomer separation of carbamate-protected cyclic amino acids. Journal of chromatography. A 20041022
Addition of a peptide fragment on an alpha-helical depsipeptide induces alpha/3(10)-conjugated helix: synthesis, crystal structure, and CD spectra of Boc-Leu-Leu-Ala-(Leu-Leu-Lac)3-Leu-Leu-OEt. Biopolymers 20041015
Stereoselective synthesis of P-chiral phosphorus compounds from N-tert-butoxycarbonyl amino acids. The Journal of organic chemistry 20041015
Air-water transfer of MTBE, its degradation products, and alternative fuel oxygenates: the role of temperature. Environmental science & technology 20041015
Structural characterization of organic multilayers on silicon(111) formed by immobilization of molecular films on functionalized Si-C linked monolayers. Langmuir : the ACS journal of surfaces and colloids 20041012
Interaction of gramicidin derivatives with phospholipid monolayers. Langmuir : the ACS journal of surfaces and colloids 20041012
Degradation of MTBE in dilute aqueous solution by gamma radiolysis. Water research 20040901
Mass spectral study of Boc-carbo-beta3-peptides: differentiation of two pairs of positional and diastereomeric isomers. Journal of mass spectrometry : JMS 20040901
Solid phase synthesis of an amphiphilic peptide modified for immobilisation at the C-terminus. Journal of biotechnology 20040826
Forced peptide synthesis in nanoscale confinement under elastomeric stamps. Angewandte Chemie (International ed. in English) 20040813
Amyloid-beta as a 'difficult sequence' in solid phase peptide synthesis. Protein and peptide letters 20040801
Genetic testing for breast and ovarian cancer susceptibility: evaluating direct-to-consumer marketing--Atlanta, Denver, Raleigh-Durham, and Seattle, 2003. MMWR. Morbidity and mortality weekly report 20040716
Synthesis of fused heteroarylprolines and pyrrolopyrroles. The Journal of organic chemistry 20040709
Menstrual cycle phase and oral contraceptive effects on triglyceride mobilization during exercise. Journal of applied physiology (Bethesda, Md. : 1985) 20040701
Lithography application of a novel photoresist for patterning of cells. Biomaterials 20040501
Chemical oxidative degradation of methyl tert-butyl ether in aqueous solution by Fenton's reagent. Chemosphere 20040401
Chiral resolution of derivatized amino acids using uniformly sized molecularly imprinted polymers in hydro-organic mobile phases. Analytical and bioanalytical chemistry 20040401
Bacterial formyl peptides affect the innate cellular antimicrobial responses of larval Galleria mellonella (Insecta: Lepidoptera). Canadian journal of microbiology 20040401
A surface-modified dendrimer set for potential application as drug delivery vehicles: synthesis, in vitro toxicity, and intracellular localization. Chemistry (Weinheim an der Bergstrasse, Germany) 20040305
Synthesis of all nineteen appropriately protected chiral alpha-hydroxy acid equivalents of the alpha-amino acids for Boc solid-phase depsi-peptide synthesis. Organic letters 20040219
Conformational and structural analysis of the equilibrium between single- and double-strand beta-helix of a D,L-alternating oligonorleucine. Biopolymers 20040205
MTBE oxidation byproducts from the treatment of surface waters by ozonation and UV-ozonation. Chemosphere 20040201
Reactions on a solid surface. A simple, economical, and efficient acylation of alcohols and amines over Al2O3. The Journal of organic chemistry 20040123
Polyvinylpyrrolidone-drug conjugate: synthesis and release mechanism. Journal of controlled release : official journal of the Controlled Release Society 20040108
New isocysteine building blocks and chemoselective peptide ligation. Organic & biomolecular chemistry 20040107
A novel electrophilic synthesis and evaluation of medium specific radioactivity (1R,2S)-4-[18F]fluorometaraminol, a tracer for the assessment of cardiac sympathetic nerve integrity with PET. Nuclear medicine and biology 20040101
A novel method for evaluation and screening of caspase inhibitory peptides by the amino acid positional fitness score. BMC pharmacology 20040101
Trifluoroacetyl as an orthogonal protecting group for guanidines. The Journal of organic chemistry 20031128
A new approach to the chemical synthesis of keto-proteins. Journal of the American Chemical Society 20031126
A versatile set of aminooxy amino acids for the synthesis of neoglycopeptides. The Journal of organic chemistry 20031114
Degradation mechanism of t-butyl methyl ether (MTBE) in atmospheric droplets. Chemosphere 20031101
Light directed massively parallel on-chip synthesis of peptide arrays with t-Boc chemistry. Proteomics 20031101
Solid-supported synthesis of cryptand-like macrobicyclic peptides. The Journal of organic chemistry 20031031
Asymmetric cyclization via memory of chirality: a concise access to cyclic amino acids with a quaternary stereocenter. Journal of the American Chemical Society 20031029
Treatment of methyl tert-butyl ether contaminated water using a dense medium plasma reactor: a mechanistic and kinetic investigation. Environmental science & technology 20031015
Crystal structure of achiral nonapeptide Boc-(Aib-DeltaZPhe)4-Aib-OMe at atomic resolution: evidence for a 3(10)-helix. Biopolymers 20031001
Immunogenicity of Sm32 synthetic peptides derived from the Schistosoma mansoni adult worm. Immunology letters 20030908
Employing the structural diversity of nature: development of modular dipeptide-analogue ligands for ruthenium-catalyzed enantioselective transfer hydrogenation of ketones. Chemistry (Weinheim an der Bergstrasse, Germany) 20030905
Roles of tert-butyl formate, tert-butyl alcohol and acetone in the regulation of methyl tert-butyl ether degradation by Mycobacterium austroafricanum IFP 2012. Applied microbiology and biotechnology 20030801
Synthesis of protected 2-amino-2-deoxy-D-xylothionolactam derivatives and some aspects of their reactivity. Carbohydrate research 20030722
Mechanism for the noncovalent chiral domino effect: new paradigm for the chiral role of the N-terminal segment in a 3(10)-helix. Journal of the American Chemical Society 20030709
Platinum(II)-based coordination compounds as nucleic acid labeling reagents: synthesis, reactivity, and applications in hybridization assays. Chembiochem : a European journal of chemical biology 20030707
New strategic reactions for organic synthesis: catalytic asymmetric C-H activation alpha to nitrogen as a surrogate for the mannich reaction. Journal of the American Chemical Society 20030528
Rearrangement of the cyclohexadiene derivatives of C60 to bis(fulleroid) and bis(methano)fullerene: structure, stability, and mechanism. The Journal of organic chemistry 20030502
Simultaneous determination of methyl tert.-butyl ether and its degradation products, other gasoline oxygenates and benzene, toluene, ethylbenzene and xylenes in Catalonian groundwater by purge-and-trap-gas chromatography-mass spectrometry. Journal of chromatography. A 20030502
A convenient method for the determination of the absolute configuration of chiral amines. The Journal of organic chemistry 20030418
Syntheses of beta,beta-difluorotryptamines. The Journal of organic chemistry 20030404
Extensively stereodiversified scaffolds for use in diversity-oriented library synthesis. Organic letters 20030306
New stable backbone linker resins for solid-phase peptide synthesis. Organic letters 20030220
Synthesis of labelled PNA oligomers by a post-synthetic modification approach. Bioorganic & medicinal chemistry letters 20030210
A new selective cleavage of n,n-dicarbamoyl-protected amines using lithium bromide. The Journal of organic chemistry 20030207
Characterization of the initial reactions during the cometabolic oxidation of methyl tert-butyl ether by propane-grown Mycobacterium vaccae JOB5. Applied and environmental microbiology 20030201
High radiochemical yield synthesis of 3'-deoxy-3'-[18F]fluorothymidine using (5'-O-dimethoxytrityl-2'-deoxy-3'-O-nosyl-beta-D-threo pentofuranosyl)thymine and its 3-N-BOC-protected analogue as a labeling precursor. Nuclear medicine and biology 20030201
Chemical modification of lipases with various hydrophobic groups improves their enantioselectivity in hydrolytic reactions. Biotechnology letters 20030101
Deprotection and cleavage of peptides bound to Merrifield resin by stable dimethyl ether-poly(hydrogen fluoride) (DMEPHF) complex. a new and convenient reagent for peptide chemistry. Chemical communications (Cambridge, England) 20021207
Asymmetric catalytic Mannich reactions catalyzed by urea derivatives: enantioselective synthesis of beta-aryl-beta-amino acids. Journal of the American Chemical Society 20021106
Sonolytic degradation of methyl tert-butyl ether: the role of coupled Fenton process and persulphate ion. Water research 20021101
A novel cyclic octapeptide as an analogue of cyclic peptide in triostin A. Preparative biochemistry & biotechnology 20021101
Stereochemistry of protected ornithine side chains of gramicidin S derivatives: X-ray crystal structure of the bis-Boc-tetra-N-methyl derivative of gramicidin S. Journal of the American Chemical Society 20021030
Reductive activation of dioxygen for degradation of methyl tert-butyl ether by bifunctional aluminum. Environmental science & technology 20021015
Ring-closing metathesis of chiral allylamines. Enantioselective synthesis of (2S,3R,4S)-3,4-dihydroxyproline. The Journal of organic chemistry 20021004
Asymmetric carbon-carbon bond formations in conjugate additions of lithiated N-Boc allylic and benzylic amines to nitroalkenes: enantioselective synthesis of substituted piperidines, pyrrolidines, and pyrimidinones. Journal of the American Chemical Society 20021002
Kinetics of heat-assisted persulfate oxidation of methyl tert-butyl ether (MTBE). Chemosphere 20021001
Photocatalytic destruction of methyl tert-butyl ether in the gas phase using titanium dioxide. Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering 20021001
A new synthesis of phosphoramidates: inhibitors of the key bacterial enzyme aspartate semi-aldehyde dehydrogenase. Chemical communications (Cambridge, England) 20020921
A convenient method for the synthesis of C-protected esters of BOC-/Z-alpha,alpha- dialkylamino acids by the mixed carboxylic carbonic anhydride method. Protein and peptide letters 20020801
Role of N-t-Boc group in helix initiation in a novel tetrapeptide. The journal of peptide research : official journal of the American Peptide Society 20020601
O-Benzyl-N-tert-butoxycarbonyl-N-methyl-L-tyrosine. Acta crystallographica. Section C, Crystal structure communications 20020601
Peptoid inhibition of trypanothione reductase as a potential antitrypanosomal and antileishmanial drug lead. Amino acids 20020601
Chemistry of N-Boc-N-tert-butylthiomethyl-protected alpha-aminoorganostannanes: diastereoselective synthesis of primary beta-amino alcohols from alpha-aminoorganostannanes. The Journal of organic chemistry 20020531
First synthesis and anticancer activity of phosmidosine and its related compounds. The Journal of organic chemistry 20020517
Simultaneous determination of fuel oxygenates and BTEX using direct aqueous injection gas chromatography mass spectrometry (DAI-GC/MS). Environmental science & technology 20020501
Cycloserine fatty acid derivatives as prodrugs: synthesis, degradation and in vitro skin permeability. Chemical & pharmaceutical bulletin 20020401
Novel carboranes with a DNA binding unit for the treatment of cancer by boron neutron capture therapy. Chembiochem : a European journal of chemical biology 20020301
Inhibition of nuclear factor kappaB chemosensitizes non-small cell lung cancer through cytochrome c release and caspase activation. The Journal of thoracic and cardiovascular surgery 20020201
Synthesis and cleavage experiments of oligonucleotide conjugates with a diimidazole-derived catalytic center. Bioconjugate chemistry 20020101
Novel dendrimer based polyurethanes for PEO incorporation. Journal of biomaterials science. Polymer edition 20020101
Preparation of encoded combinatorial libraries for drug discovery. Methods in molecular biology (Clifton, N.J.) 20020101
Solid phase synthesis of hydrophobic difficult sequence peptides on BDDMA-PS support. Journal of peptide science : an official publication of the European Peptide Society 20011201
The development and application of a novel safety-catch linker for BOC-based assembly of libraries of cyclic peptides. The Journal of organic chemistry 20011116
Immunogenicity of synthetic peptides from the Sm31 antigen (cathepsin B) of the Schistosoma mansoni adult worms. Parasite immunology 20011101
MTBE oxidation by conventional ozonation and the combination ozone/hydrogen peroxide: efficiency of the processes and bromate formation. Environmental science & technology 20011101
Synthesis of novel potential antitumor agents: 2,6-dimethoxyhydroquinone-3-mercapto-acetyl peptide conjugates. Preparative biochemistry & biotechnology 20011101
Engineering the prion protein using chemical synthesis. The journal of peptide research : official journal of the American Peptide Society 20011101
A helical arrangement of beta-substituents of dehydropeptides: synthesis and conformational study of sequential nona- and dodecapeptides possessing (Z)-beta-(1-naphthyl)dehydroalanine residues. Biopolymers 20011015
Effects of hydrogen-bond deletion on peptide helices: structural characterization of depsipeptides containing lactic acid. Biopolymers 20011005
Fast, efficient and selective deprotection of the tert-butoxycarbonyl (Boc) group using HCl/dioxane (4 m). The journal of peptide research : official journal of the American Peptide Society 20011001
Quality of life in patients at risk of medullary thyroid carcinoma and followed by a comprehensive medical network: trends for future evaluations. Annals of oncology : official journal of the European Society for Medical Oncology 20011001
[Tracheopathia osteochondroplastica associated with a liver hydatic cyst broken in bronchi]. Annales de pathologie 20011001
Evaluation of the trifluoromethanosulfonic acid/trifluoroacetic acid/thioanisole cleavage procedure for application in solid-phase peptide synthesis. Chemical & pharmaceutical bulletin 20010901
Polypeptide synthesis using an expressed peptide as a building block for condensation with a peptide thioester: application to the synthesis of phosphorylated p21Max protein(1-101). Journal of peptide science : an official publication of the European Peptide Society 20010901
Chiral diamines 4: a computational study of the enantioselective deprotonation of Boc-pyrrolidine with an alkyllithium in the presence of a chiral diamine. Journal of the American Chemical Society 20010829
Evidence of a founder mutation of BRCA1 in a highly homogeneous population from southern Italy with breast/ovarian cancer. Human mutation 20010801
Combination of tert-butoxycarbonyl and triphenylphosphonium protecting groups in the synthesis of substituted hydrazines. Organic letters 20010726
Efficient introduction of protected guanidines in boc solid phase peptide synthesis. Organic letters 20010726
Synthesis of an analog of the thyroid hormone-binding protein transthyretin via regioselective chemical ligation. The Journal of biological chemistry 20010713
Solid phase synthesis of partially protected tocinoic acid: optimization with respect to resin and protecting groups. Journal of peptide science : an official publication of the European Peptide Society 20010701
Bocdene and mocdene derivatives of catechols and catecholamines. Organic letters 20010503
Bacterial formyl peptide mediated chemotaxis and extracellular acidification in shrimp haemocytes. Developmental and comparative immunology 20010501
Aerobic biodegradation of an oxygenates mixture: ETBE, MTBE and TAME in an upflow fixed-bed reactor. Water research 20010501
Solid-Phase synthesis of a dendritic peptide related to a retinoblastoma protein fragment utilizing a combined boc- and fmoc-chemistry approach. Journal of peptide science : an official publication of the European Peptide Society 20010501
Chichibabin indolizine synthesis revisited: synthesis of indolizinones by solvolysis of 4-alkoxycarbonyl-3-oxotetrahydroquinolizinium ylides. The Journal of organic chemistry 20010420
Solvent-induced beta-hairpin to helix conformational transition in a designed peptide. Biopolymers 20010415
Three-dimensional structure of RTD-1, a cyclic antimicrobial defensin from Rhesus macaque leukocytes. Biochemistry 20010410
Nitrile reduction in the presence of Boc-protected amino groups by catalytic hydrogenation over palladium-activated Raney-nickel. The Journal of organic chemistry 20010406
The molecular and crystal structure of tert-butyl Nalpha-tert-butoxycarbonyl-L-(S-trityl)cysteinate and the conformation-stabilizing function of weak intermolecular bonding. Chemical & pharmaceutical bulletin 20010401
Isolation and characterization of two aerobic bacterial strains that completely degrade ethyl tert-butyl ether (ETBE). Applied microbiology and biotechnology 20010401
Synthesis and properties of peptide nucleic acids containing a psoralen unit. Organic letters 20010322
Acid-labile protecting groups for the synthesis of lipidated peptides. Chemistry (Weinheim an der Bergstrasse, Germany) 20010316
Formal total synthesis of (+/-)-gamma-lycorane and (+/-)-1-deoxylycorine using the [4+2]-cycloaddition/rearrangement cascade of furanyl carbamates. The Journal of organic chemistry 20010309
Fragmentation of carbohydrate anomeric alkoxy radicals. synthesis of polyhydroxy piperidines and pyrrolidines related to carbohydrates. The Journal of organic chemistry 20010309
Pressure monitoring of continuous-flow solid-phase peptide synthesis. The journal of peptide research : official journal of the American Peptide Society 20010301
Samarium(0) and 1,1'-dioctyl-4,4'-bipyridinium dibromide: a novel electron-transfer system for the chemoselective reduction of aromatic nitro groups. The Journal of organic chemistry 20010209
Unprecedented migration of N-alkoxycarbonyl groups in protected pyroglutaminol. Organic letters 20010208
Regioselective palladium-catalyzed synthesis of beta-arylated primary allylamine equivalents by an efficient Pd-N coordination. The Journal of organic chemistry 20010126
A short stereoselective preparation of dienamides from cyclobutene compounds. Application in the synthesis of a new cyclohexene nucleoside. The Journal of organic chemistry 20010126
Structural and conformational properties of (Z)-beta-(1-naphthyl)- dehydroalanine residue. Biopolymers 20010101
Synthesis of of beta-amyloid precursor peptide and presenilin segments. Journal of peptide science : an official publication of the European Peptide Society 20010101
Properties