Home Sulfos Lithium trifluoromethanesulfonate

Lithium trifluoromethanesulfonate

CAS No.:
33454-82-9
Catalog Number:
AG003RC9
Molecular Formula:
CF3LiO3S
Molecular Weight:
156.0101
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
1g
97%
In Stock USA
United States
$13
- +
5g
97%
In Stock USA
United States
$19
- +
25g
97%
In Stock USA
United States
$44
- +
100g
97%
In Stock USA
United States
$113
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Product Description
Catalog Number:
AG003RC9
Chemical Name:
Lithium trifluoromethanesulfonate
CAS Number:
33454-82-9
Molecular Formula:
CF3LiO3S
Molecular Weight:
156.0101
MDL Number:
MFCD00013227
IUPAC Name:
lithium;trifluoromethanesulfonate
InChI:
InChI=1S/CHF3O3S.Li/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1
InChI Key:
MCVFFRWZNYZUIJ-UHFFFAOYSA-M
SMILES:
FC(S(=O)(=O)[O-])(F)F.[Li+]
EC Number:
251-528-5
UNII:
1C966KV50I
Properties
Complexity:
163  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
2  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
155.968g/mol
Formal Charge:
0
Heavy Atom Count:
9  
Hydrogen Bond Acceptor Count:
6  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
156.003g/mol
Monoisotopic Mass:
155.968g/mol
Rotatable Bond Count:
0
Topological Polar Surface Area:
65.6A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
Literature
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Pyrrole synthesis catalyzed by AgOTf or cationic Au(I) complexes. The Journal of organic chemistry 20060609
In(OTf)3-catalyzed tandem nucleophilic addition and cyclization of ortho-alkynylarylaldimines to 1,2-dihydroisoquinolines. Angewandte Chemie (International ed. in English) 20060602
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Catalytic asymmetric mannich-type reactions activated by ZnF2 chiral diamine in aqueous media. Chemistry (Weinheim an der Bergstrasse, Germany) 20060123
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Regioselective conversion of the secondary hydroxyl groups of D-glucuronic acid without the requirement of O-protecting groups. Chemistry (Weinheim an der Bergstrasse, Germany) 20051021
A mild and environmentally friendly scandium(III) trifluoromethanesulfonate-catalyzed synthesis of bis(3'-indolyl)alkanes and bis(3'-indolyl)-1-deoxyalditols. Carbohydrate research 20051017
Arylation reactions: the photo-S(N)1 path via phenyl cation as an alternative to metal catalysis. Accounts of chemical research 20050901
A facile one-pot benzylation of sodium enolates using trifluoromethanesulfonic anhydride and diphenyl sulfoxide. Chemical & pharmaceutical bulletin 20050501
Efficient radiosynthesis of carbon-11 labelled uncharged Thioflavin T derivatives using [11C]methyl triflate for beta-amyloid imaging in Alzheimer's Disease with PET. Applied radiation and isotopes : including data, instrumentation and methods for use in agriculture, industry and medicine 20050401
A practical catalytic method for preparing highly substituted cyclobutanes and cyclobutenes. Journal of the American Chemical Society 20050323
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Synthesis of O-aminodihydroartemisinin via TMS triflate catalyzed C-O coupling reaction. The Journal of organic chemistry 20040430
Superacid-catalyzed reactions of cinnamic acids and the role of superelectrophiles. The Journal of organic chemistry 20040402
Preparation and palladium-catalyzed cross-coupling of aryl triethylammonium bis(catechol) silicates with aryl triflates. The Journal of organic chemistry 20040220
Direct synthesis of sulfonamides and activated sulfonate esters from sulfonic acids. Journal of the American Chemical Society 20040204
Experimental and theoretical vibrational study of 2,2,2-trifluoroethyl trifluoromethanesulfonate, CF3SO2OCH2CF3. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20040201
Palladium-catalyzed amination of aryl nonaflates. The Journal of organic chemistry 20031212
Deglycosylation of glycoproteins with trifluoromethanesulphonic acid: elucidation of molecular structure and function. The Biochemical journal 20031201
The 3,4-O-carbonate protecting group as a beta-directing group in rhamnopyranosylation in both homogeneous and heterogeneous glycosylations as compared to the chameleon-like 2,3-O-carbonates. The Journal of organic chemistry 20031031
Facile Cu(OTf)2-catalyzed preparation of per-O-acetylated hexopyranoses with stoichiometric acetic anhydride and sequential one-pot anomeric substitution to thioglycosides under solvent-free conditions. The Journal of organic chemistry 20031031
Efficient protocol for ring opening of spiroketals using trifluoroacetyl trifluoromethanesulfonate (TFAT). Organic letters 20031002
Billion-fold acceleration of the methanolysis of paraoxon promoted by La(OTf)3 in methanol. Journal of the American Chemical Society 20030625
Stereoblock copolymers and tacticity control in controlled/living radical polymerization. Journal of the American Chemical Society 20030611
Reaction of azulenes with 1-trifluoromethanesulfonylpyridinium trifluoromethanesulfonate (TPT) and synthesis of the parent azulene. Organic & biomolecular chemistry 20030607
Rhodium-catalyzed disulfide exchange reaction. Journal of the American Chemical Society 20030604
Super acid-induced Pummerer-type cyclization reaction: improvement in the synthesis of chiral 1,3-dimethyl-1,2,3,4-tetrahydroisoquinolines. Chemical & pharmaceutical bulletin 20030601
A study on the conversion of indanones into carbostyrils. Bioorganic & medicinal chemistry 20030515
Synthesis of 2,3,6-trideoxysugar-containing disaccharides by cyclization and glycosidation through the sequential activation of sulfoxide and methylsulfanyl groups in a one-pot procedure. Angewandte Chemie (International ed. in English) 20030425
Zinc triflate-benzoyl bromide: a versatile reagent for the conversion of ether into benzoate protecting groups and ether glycosides into glycosyl bromides. Carbohydrate research 20030214
Carbodiimide-mediated preparation of the tricyclic pyrido[3',2':4,5]pyrrolo[1,2-c]pyrimidine ring system and its application to the synthesis of the potent antitumoral marine alkaloid variolin B and analog. The Journal of organic chemistry 20030124
Microwave-promoted Pd-catalyzed cyanation of aryl triflates: a fast and versatile access to 3-cyano-3-desoxy-10-ketomorphinans. Organic letters 20030123
Scaleable and efficient synthesis of 2'-deoxy-2'-N-phthaloyl nucleoside phosphoramidites for oligonucleotide synthesis. Bioorganic & medicinal chemistry letters 20021118
Study of interhalogens/silver trifluoromethanesulfonate as promoter systems for high-yielding sialylations. The Journal of organic chemistry 20021018
A convenient method for the conversion of N-acyloxazolidinones to hydroxamic acids. Organic letters 20021003
Scandium(III) trifluoromethanesulfonate catalyzed aromatic nitration with inorganic nitrates and acetic anhydride. Chemical & pharmaceutical bulletin 20020801
Palladium-catalyzed cross-coupling reaction of bis(pinacolato)diboron with 1-alkenyl halides or triflates: convenient synthesis of unsymmetrical 1,3-dienes via the borylation-coupling sequence. Journal of the American Chemical Society 20020710
Polar, non-coordinating ionic liquids as solvents for the alternating copolymerization of styrene and CO catalyzed by cationic palladium catalysts. Chemical communications (Cambridge, England) 20020707
Brønsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidines. Organic letters 20020502
Coupling of isoprenoid triflates with organoboron nucleophiles: synthesis and biological evaluation of geranylgeranyl diphosphate analogues. Bioorganic & medicinal chemistry 20020501
p-Methoxybenzyl ether cleavage by polymer-supported sulfonamides. Organic letters 20020404
Preparation of alpha-sulfenyl enones by thermal fragmentation of beta-sulfenyl enol triflates. Organic letters 20020321
Metal trifluoromethanesulfonate-catalyzed regioselective borane-reductive ring opening of benzylidene acetals: a concise synthesis of 1,4-dideoxy-1,4-imino-L-xylitol. Organic letters 20020307
Rare earth metal trifluoromethanesulfonates catalyzed benzyl-etherification. Chemical & pharmaceutical bulletin 20020301
Chemical deglycosylation can induce methylation, succinimide formation, and isomerization. Journal of protein chemistry 20011001
1-Benzenesulfinyl piperidine/trifluoromethanesulfonic anhydride: a potent combination of shelf-stable reagents for the low-temperature conversion of thioglycosides to glycosyl triflates and for the formation of diverse glycosidic linkages. Journal of the American Chemical Society 20010919
Iodine monochloride/silver trifluoromethanesulfonate (ICI/AgOTf) as a convenient promoter system for O-glycoside synthesis. Organic letters 20010322
Cross-coupling reactions of potassium alkyltrifluoroborates with aryl and 1-alkenyl trifluoromethanesulfonates. Organic letters 20010208
Studies on the synthesis of 1,2-cis pentofuranosides from S-glycofuranosyl dithiocarbamates, dithiocarbonates and phosphorodithioates. Carbohydrate research 20010115
Structural studies of the O-specific polysaccharide of Vibrio cholerae O8 using solvolysis with triflic acid. Carbohydrate research 20010115
Brominations of steroidal hormone having alpha,beta-unsaturated ketone, 17-O-acetyltestosterone, in the presence of silver triflate. Chemical & pharmaceutical bulletin 20010101
Synthesis and anti-HIV-1 activity of novel 2,3-dihydro-7H-thiazolo[3,2-a]pyrimidin-7-ones. Journal of medicinal chemistry 19980115
Chitin-bound protein of sarcophagid larvae: metabolism of covalently linked aromatic constituents. Biochemistry 19821207
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