Home Other Building Blocks ETHYLENE SULFIDE

ETHYLENE SULFIDE

CAS No.:
420-12-2
Catalog Number:
AG003QIM
Molecular Formula:
C2H4S
Molecular Weight:
60.1182
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Product Description
Catalog Number:
AG003QIM
Chemical Name:
ETHYLENE SULFIDE
CAS Number:
420-12-2
Molecular Formula:
C2H4S
Molecular Weight:
60.1182
MDL Number:
MFCD00005159
IUPAC Name:
thiirane
InChI:
InChI=1S/C2H4S/c1-2-3-1/h1-2H2
InChI Key:
VOVUARRWDCVURC-UHFFFAOYSA-N
SMILES:
S1CC1
EC Number:
206-993-9
UNII:
A2W5165740
NSC Number:
89690
RTECS Number:
KX3500000
Properties
Complexity:
10.3  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
60.003g/mol
Formal Charge:
0
Heavy Atom Count:
3  
Hydrogen Bond Acceptor Count:
1  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
60.114g/mol
Monoisotopic Mass:
60.003g/mol
Rotatable Bond Count:
0
Topological Polar Surface Area:
25.3A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
0.6  
Literature
Title Journal
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(1) H NMR Spectra. Part 28: Proton chemical shifts and couplings in three-membered rings. A ring current model for cyclopropane and a novel dihedral angle dependence for (3) J(HH) couplings involving the epoxy proton. Magnetic resonance in chemistry : MRC 20120401
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Functional and structural analyses of N-acylsulfonamide-linked dinucleoside inhibitors of RNase A. The FEBS journal 20110201
An engineered viral protease exhibiting substrate specificity for a polyglutamine stretch prevents polyglutamine-induced neuronal cell death. PloS one 20110101
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Energetics and mechanism for the deamination of lithiated cysteine. The journal of physical chemistry. B 20100325
The X-ray structure of carboxypeptidase A inhibited by a thiirane mechanism-based inhibitor. Chemical biology & drug design 20100101
Active site ring-opening of a thiirane moiety and picomolar inhibition of gelatinases. Chemical biology & drug design 20091201
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Matrix metalloproteinase 2 inhibition: combined quantum mechanics and molecular mechanics studies of the inhibition mechanism of (4-phenoxyphenylsulfonyl)methylthiirane and its oxirane analogue. Biochemistry 20091020
Ethylenesulfide as a useful agent for incorporation into the biopolymer chitosan in a solvent-free reaction for use in cation removal. Carbohydrate research 20090908
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DFT studies of the ring-opening mechanism of SB-3CT, a potent inhibitor of matrix metalloproteinase 2. Organic letters 20090618
Thermal and spectroscopic properties of polystyrene/gold nanocomposite containing well-dispersed gold nanoparticles. Journal of nanoscience and nanotechnology 20090501
Elementary reactions and their role in gas-phase prebiotic chemistry. International journal of molecular sciences 20090501
Matrix photochemistry, photoelectron spectroscopy, solid-phase structure, and ring strain energy of beta-propiothiolactone. The journal of physical chemistry. A 20090416
Isolation of the key intermediates in the catalyst-free conversion of oxiranes to thiiranes in water at ambient temperature. Organic & biomolecular chemistry 20090407
Structural study of Ga(III), In(III), and Fe(III) complexes of triaza-macrocycle based ligands with N3S3 donor set. Inorganic chemistry 20090406
Observation of direct sulfenium and selenenium group transfer from thiiranium and seleniranium ions to alkenes. Journal of the American Chemical Society 20090318
Influence of disulfide density and molecular weight on disulfide cross-linked polyethylenimine as gene vectors. Bioconjugate chemistry 20090201
A potent gelatinase inhibitor with anti-tumor-invasive activity and its metabolic disposition. Chemical biology & drug design 20090201
Mechanism and regioselectivity of the cycloaddition of thiones derived from Meldrum's acid, malonates, or other dicarbonyls. The Journal of organic chemistry 20081003
Imaging atomic orbital polarization in photodissociation. Chemical reviews 20080901
The effects of sulfur substitution for the nucleophile and bridging oxygen atoms in reactions of hydroxyalkyl phosphate esters. The Journal of organic chemistry 20080704
Conformational analyses of thiirane-based gelatinase inhibitors. Bioorganic & medicinal chemistry letters 20080515
Reactivity of fullerene epoxide: preparation of fullerene-fused thiirane, tetrahydrothiazolidin-2-one, and 1,3-dioxolane. The Journal of organic chemistry 20080404
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Chemical toxicology of reactive intermediates formed by the glutathione-dependent bioactivation of halogen-containing compounds. Chemical research in toxicology 20080101
A mechanistic view of enzyme inhibition and peptide hydrolysis in the active site of the SARS-CoV 3C-like peptidase. Journal of molecular biology 20070824
Vibrational overtone spectroscopy of three-membered rings. The journal of physical chemistry. A 20070628
Theoretical study of the reaction from 6-methylidene penem to seven-membered ring intermediates. The journal of physical chemistry. A 20070531
Highly selective copper-catalyzed ring expansion of vinyl thiiranes: application to synthesis of biotin and the heterocyclic core of plavix. Journal of the American Chemical Society 20070314
Water durability of resin bond to pure gold treated with various adhesion promoting thiirane monomers. Dental materials journal 20070101
Vibrational structures of dimethyl sulfide and ethylene sulfide cations studied by vacuum-ultraviolet mass-analyzed threshold ionization (MATI) spectroscopy. The journal of physical chemistry. A 20061214
An episulfide cation (thiiranium ring) trapped in the active site of HAV 3C proteinase inactivated by peptide-based ketone inhibitors. Journal of molecular biology 20060825
Kinetics, mechanism, and computational studies of rhenium-catalyzed desulfurization reactions of thiiranes (thioepoxides). Inorganic chemistry 20060710
Aquasonolysis of thioethers. Ultrasonics sonochemistry 20060501
The atmospheric pressure Meerwein reaction. Journal of mass spectrometry : JMS 20060401
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The reactions of sulfur mustard with the active components of organic decontaminants. Journal of hazardous materials 20050831
A comparison of the Cope rearrangements of cis-1,2-divinylcyclopropane, cis-2,3-divinylaziridine, cis-2,3-divinyloxirane, cis-2,3-divinylphosphirane, and cis-2,3-divinylthiirane: a DFT study. The Journal of organic chemistry 20050722
Rotational spectrum, inversion, and geometry of 2,5-dihydrofuran...ethyne and a generalization about Z...H-C hydrogen bonds. The Journal of chemical physics 20050401
Vibrational dynamics of medium strength hydrogen bonds: Fourier transform infrared spectra and band contour analysis of the DF stretching region of (CH2)2S-DF. The Journal of chemical physics 20041022
New potent and selective A1 adenosine receptor agonists. Bioorganic & medicinal chemistry 20040915
Oligomerization of ribonuclease A: two novel three-dimensional domain-swapped tetramers. The Journal of biological chemistry 20040827
Nickel-manganese sulfido carbonyl cluster complexes. synthesis, structure, and properties of the unusual paramagnetic complexes Cp2Ni2Mn(CO)3(mu 3-E)2, E = S, Se. Inorganic chemistry 20040419
Meerwein reaction of phosphonium ions with epoxides and thioepoxides in the gas phase. Journal of the American Society for Mass Spectrometry 20040301
Absolute rate constants for reactions of tributylstannyl radicals with bromoalkanes, episulfides, and alpha-halomethyl-episulfides, -cyclopropanes, and -oxiranes: new rate expressions for sulfur and bromine atom abstraction. The Journal of organic chemistry 20040220
Functionalization of cyclodextrins via reactions of 2,3-anhydrocyclodextrins. The Journal of organic chemistry 20031128
Comparative study of extraction techniques for determination of garlic flavor components by gas chromatography-mass spectrometry. Analytical and bioanalytical chemistry 20031001
Cysteine protease inhibitors containing small rings. Mini reviews in medicinal chemistry 20030901
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Synthesis of enantiomerically pure 2,2,3,4,5-pentasubstituted pyrrolidines by phenylsulfanyl migration. Organic letters 20021212
Disulfides of manganese carbonyl. Synthesis of Mn(2)(CO)(7)(mu-S2) and its reactions with tertiary phosphines and arsines. Inorganic chemistry 20021202
Theoretical study of silylene substituent effects on the abstraction reactions with oxirane and thiirane. Journal of the American Chemical Society 20021016
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Oligodeoxyribonucleotide analogues with bridging dimethylene sulfide, sulfoxide, and sulfone groups. Toward a second-generation model of nucleic acid structure. The Journal of organic chemistry 20020614
Surface treatment agent for dental metals using a thiirane monomer and a phosphoric acid monomer. Dental materials journal 20020601
Synthesis of trithiolanes and tetrathianes from thiiranes catalyzed by ruthenium salen nitrosyl complexes. Journal of the American Chemical Society 20020501
The thermal decomposition of thiirane: a mechanistic study by ab initio MO theory. Chemistry (Weinheim an der Bergstrasse, Germany) 20020104
A theoretical study of neighboring-group participation in thione-to-thiol rearrangement of xanthates. molecular orbital calculation using a conductor-like screening model (COSMO) approach. Chemical & pharmaceutical bulletin 20011101
A computational study of the reactions of thiiranes with ammonia and amines. The Journal of organic chemistry 20010907
The first 2,2-dialkoxythiirane. Organic letters 20010809
Palladium-catalyzed cyclization reactions of 2-vinylthiiranes with heterocumulenes. Regioselective and enantioselective formation of thiazolidine, oxathiolane, and dithiolane derivatives. The Journal of organic chemistry 20010518
A G2 study of SH+ exchange reactions involving lone-pair donors and unsaturated hydrocarbons. Chemistry (Weinheim an der Bergstrasse, Germany) 20010401
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Photodissociation of ethylene sulfide at 193 nm: a photofragment translational spectroscopy study with VUV synchrotron radiation and ab initio calculations. Journal of the American Chemical Society 20010110
Properties