Home Other Building Blocks ALLYLTRICHLOROSILANE

ALLYLTRICHLOROSILANE

CAS No.:
107-37-9
Catalog Number:
AG003NQN
Molecular Formula:
Molecular Weight:
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Product Description
Catalog Number:
AG003NQN
Chemical Name:
ALLYLTRICHLOROSILANE
CAS Number:
107-37-9
MDL Number:
MFCD00000486
IUPAC Name:
trichloro(prop-2-enyl)silane
InChI:
InChI=1S/C3H5Cl3Si/c1-2-3-7(4,5)6/h2H,1,3H2
InChI Key:
HKFSBKQQYCMCKO-UHFFFAOYSA-N
EC Number:
203-485-9
UNII:
UB3N98803N
NSC Number:
20940
UN Number:
1724
Properties
Complexity:
65.1  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
173.923g/mol
Formal Charge:
0
Heavy Atom Count:
7  
Hydrogen Bond Acceptor Count:
0
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
175.508g/mol
Monoisotopic Mass:
173.923g/mol
Rotatable Bond Count:
1  
Topological Polar Surface Area:
0A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
Literature
Title Journal
Enantioselective allylation of α,β-unsaturated aldehydes with allyltrichlorosilane catalyzed by METHOX. The Journal of organic chemistry 20110603
A multiwell platform for studying stiffness-dependent cell biology. PloS one 20110101
Aryl tert-butyl sulfoxide-promoted highly enantioselective addition of allyltrichlorosilane to aldehydes. Organic & biomolecular chemistry 20090921
Vibrational spectra of metals treated with allyltrimethoxysilane sol-gel and self-assembled monolayer of allytrichlorosilane. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20070701
C2-symmetric bissulfoxides as organocatalysts in the allylation of benzoyl hydrazones: spacer and concentration effects. Organic letters 20070524
First enantioselective organocatalytic allylation of simple aldimines with allyltrichlorosilane. Chemical communications (Cambridge, England) 20061207
Ultraviolet photochemistry of trichlorovinylsilane and allyltrichlorosilane: vinyl radical (HCCH2) and allyl radical (H2CCHCH2) production in 193 nm photolysis. Physical chemistry chemical physics : PCCP 20060521
Structurally simple pyridine N-oxides as efficient organocatalysts for the enantioselective allylation of aromatic aldehydes. The Journal of organic chemistry 20060217
Chiral phosphoramide-catalyzed enantioselective addition of allylic trichlorosilanes to aldehydes. Preparative and mechanistic studies with monodentate phosphorus-based amides. The Journal of organic chemistry 20060217
Chiral phosphoramide-catalyzed enantioselective addition of allylic trichlorosilanes to aldehydes. Preparative studies with bidentate phosphorus-based amides. The Journal of organic chemistry 20060217
Readily available pyridine- and quinoline-N-oxides as new organocatalysts for the enantioselective allylation of aromatic aldehydes with allyl(trichloro)silane. Chirality 20050801
Proline-based N-oxides as readily available and modular chiral catalysts. Enantioselective reactions of allyltrichlorosilane with aldehydes. Organic letters 20050721
METHOX: a new pyridine N-oxide organocatalyst for the asymmetric allylation of aldehydes with allyltrichlorosilanes. Organic letters 20050721
Polystyrenes with chiral phosphoramide substituents as Lewis base catalysts for asymmetric addition of allyltrichlorosilane: enhancement of catalytic performance by polymer effect. Chemical communications (Cambridge, England) 20050414
The first series of chiral 2,2':6',2''-terpyridine tri-N-oxide ligands for Lewis base-catalyzed asymmetric allylation of aldehydes. Organic & biomolecular chemistry 20040721
The first catalytic asymmetric allylation of imines with the tetraallylsilane-TBAF-MeOH system, using the chiral bis-pi-allylpalladium complex. The Journal of organic chemistry 20040206
New Lewis-basic N-oxides as chiral organocatalysts in asymmetric allylation of aldehydes. The Journal of organic chemistry 20031212
Chiral sulfoxides in the enantioselective allylation of aldehydes with allyltrichlorosilane. Chemical communications (Cambridge, England) 20031107
A new synthetic route to enantiomerically pure axially chiral 2,2'-bipyridine N,N'-dioxides. Highly efficient catalysts for asymmetric allylation of aldehydes with allyl(trichloro)silanes. The Journal of organic chemistry 20030808
Polymer-supported formamides as reusable organocatalysts for allylation of aldehydes with allyltrichlorosilane. Chemical communications (Cambridge, England) 20030121
A novel axially chiral 2,2'-bipyridine N,N'-dioxide. Its preparation and use for asymmetric allylation of aldehydes with allyl(trichloro)silane as a highly efficient catalyst. Organic letters 20020808
Chiral 2,2'-bipyridine-type N-monoxides as organocatalysts in the enantioselective allylation of aldehydes with allyltrichlorosilane. Organic letters 20020321
Highly stereoselective synthesis of homoallylic amines based on addition of allyltrichlorosilanes to benzoylhydrazones. Journal of the American Chemical Society 20011003
Properties