Home Other Building Blocks 2-(Trimethylsilyloxy)furan

2-(Trimethylsilyloxy)furan

CAS No.:
61550-02-5
Catalog Number:
AG003F68
Molecular Formula:
C7H12O2Si
Molecular Weight:
156.2545
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
5g
>96.0%(GC)
1 week
United States
$387
- +
25g
>96.0%(GC)
1 week
United States
$1131
- +
Product Description
Catalog Number:
AG003F68
Chemical Name:
2-(Trimethylsilyloxy)furan
CAS Number:
61550-02-5
Molecular Formula:
C7H12O2Si
Molecular Weight:
156.2545
MDL Number:
MFCD00011729
IUPAC Name:
furan-2-yloxy(trimethyl)silane
InChI:
InChI=1S/C7H12O2Si/c1-10(2,3)9-7-5-4-6-8-7/h4-6H,1-3H3
InChI Key:
ILBCDLOQMRDXLN-UHFFFAOYSA-N
SMILES:
C[Si](Oc1ccco1)(C)C
Properties
Complexity:
109  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
156.061g/mol
Formal Charge:
0
Heavy Atom Count:
10  
Hydrogen Bond Acceptor Count:
2  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
156.256g/mol
Monoisotopic Mass:
156.061g/mol
Rotatable Bond Count:
2  
Topological Polar Surface Area:
22.4A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
Literature
Title Journal
Iridium-catalyzed regioselective and enantioselective allylation of trimethylsiloxyfuran. Journal of the American Chemical Society 20120919
Enantioselective addition of cyclic enol silyl ethers to 2-alkenoyl-pyridine-N-oxides catalysed by Cu(II)-bis(oxazoline) complexes. Chemistry (Weinheim an der Bergstrasse, Germany) 20120910
Bismuth-catalyzed addition of silyl nucleophiles to carbonyl compounds and imines. Topics in current chemistry 20120101
Stereoselective vinylogous Mannich reaction of 2-trimethylsilyloxyfuran with N-gulosyl nitrones. Organic & biomolecular chemistry 20111107
Highly diastereoselective vinylogous Mukaiyama aldol reaction of α-keto phosphonates with 2-(trimethylsilyloxy)furan catalyzed by Cu(OTf)2. Organic & biomolecular chemistry 20111007
Highly efficient asymmetric vinylogous Mannich reaction induced by O-pivaloylated D-galactosylamine as the chiral auxiliary. Organic & biomolecular chemistry 20110321
P(PhCH2NCH2CH2)3N catalysis of Mukaiyama aldol reactions of aliphatic, aromatic, and heterocyclic aldehydes and trifluoromethyl phenyl ketone. The Journal of organic chemistry 20091106
Calixpyrrole derivatives: 'multi hydrogen bond' catalysts for gamma-butenolide synthesis. Molecules (Basel, Switzerland) 20090715
Surface-enhanced stereoselectivity in Mukaiyama aldol reactions catalyzed by clay-supported bis(oxazoline)-copper complexes. Chemical communications (Cambridge, England) 20081114
Chiral phosphine-catalyzed enantioselective construction of gamma-butenolides through substitution of Morita-Baylis-Hillman acetates with 2-trimethylsilyloxy furan. Journal of the American Chemical Society 20080611
Diastereoselective Mukaiyama aldol reaction of 2-(trimethylsilyloxy)furan catalyzed by bismuth triflate. The Journal of organic chemistry 20080104
2-(Trimethylsilyloxy)furan as a dianion equivalent: a two-step synthesis of functionalized spirocyclic butenolides. Organic letters 20060817
Stereoselective synthesis of bicyclic lactones by annelation with functionalized orthoesters. Chemical communications (Cambridge, England) 20060321
A new pyridine-2,6-bis(oxazoline) for efficient and flexible lanthanide-based catalysts of enantioselective reactions with 3-alkenoyl-2-oxazolidinones. Chemistry (Weinheim an der Bergstrasse, Germany) 20050620
Simple diastereoselectivity of the BF3.OEt2-catalyzed vinylogous Mukaiyama aldol reaction of 2-(trimethylsiloxy)furans with aldehydes. The Journal of organic chemistry 20050429
Regio- and stereoselective construction of gamma-butenolides through phosphine-catalyzed substitution of Morita-Baylis-Hillman acetates: an organocatalytic allylic alkylation. Angewandte Chemie (International ed. in English) 20041210
Synthesis of regioisomeric analogues of crisamicin A. Organic & biomolecular chemistry 20031207
Synthesis of 3-azido-2,3,6-trideoxy-beta-D-arabino-hexopyranosyl pyranonaphthoquinone analogues of medermycin. Organic & biomolecular chemistry 20030521
Nucleophilic addition reaction of 2-trimethylsilyloxyfuran to N-gulosyl-C-alkoxymethylnitrones: synthetic approach to polyoxin C. Organic letters 20020404
Stereoselective synthesis of heterocyclic cage compounds by domino conjugate additions. Chemistry (Weinheim an der Bergstrasse, Germany) 20020104
Properties