Home Other Building Blocks 1,1,3,3-Tetramethylguanidine

1,1,3,3-Tetramethylguanidine

CAS No.:
80-70-6
Catalog Number:
AG003D6J
Molecular Formula:
C5H13N3
Molecular Weight:
115.1768
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
10g
97%
1 week
United States
$7
- +
25g
97%
1 week
United States
$10
- +
Product Description
Catalog Number:
AG003D6J
Chemical Name:
1,1,3,3-Tetramethylguanidine
CAS Number:
80-70-6
Molecular Formula:
C5H13N3
Molecular Weight:
115.1768
MDL Number:
MFCD00075588
IUPAC Name:
1,1,3,3-tetramethylguanidine
InChI:
InChI=1S/C5H13N3/c1-7(2)5(6)8(3)4/h6H,1-4H3
InChI Key:
KYVBNYUBXIEUFW-UHFFFAOYSA-N
SMILES:
CN(C(=N)N(C)C)C
EC Number:
201-302-7
UNII:
VEZ101E7ZU
NSC Number:
148309
Properties
Complexity:
75.7  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
115.111g/mol
Formal Charge:
0
Heavy Atom Count:
8  
Hydrogen Bond Acceptor Count:
1  
Hydrogen Bond Donor Count:
1  
Isotope Atom Count:
0
Molecular Weight:
115.18g/mol
Monoisotopic Mass:
115.111g/mol
Rotatable Bond Count:
2  
Topological Polar Surface Area:
30.3A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
0.4  
Literature
Title Journal
Pt(II)-mediated imine-nitrile coupling leading to symmetrical (1,3,5,7,9-pentaazanona-1,3,6,8-tetraenato)Pt(II) complexes containing the incorporated 1,3-diiminoisoindoline moiety. Inorganic chemistry 20121015
Sensitive analyses of neutral N-glycans using anion-doped liquid matrix G3CA by negative-ion matrix-assisted laser desorption/ionization mass spectrometry. Analytical chemistry 20120717
Accurate and reliable quantification of total microalgal fuel potential as fatty acid methyl esters by in situ transesterification. Analytical and bioanalytical chemistry 20120401
Transcriptional gene silencing of kallikrein 5 and kallikrein 7 using siRNA prevents epithelial cell detachment induced by alkaline shock in an in vitro model of eczema. Biotechnology progress 20120101
Ionic liquid catalysed synthesis of β-hydroxy ketones. ChemSusChem 20110822
Mechanistic considerations of guanidine-catalyzed reactions. Chemical communications (Cambridge, England) 20110807
Distillable acid-base conjugate ionic liquids for cellulose dissolution and processing. Angewandte Chemie (International ed. in English) 20110704
2-Diazo-1-(1,1-dioxothio-morpholin-4-yl)ethanone. Acta crystallographica. Section E, Structure reports online 20110701
Synthesis of 5-chloro-8-hydroxy-6-methoxy-3-pentylisocoumarin. Journal of Asian natural products research 20110601
2-[2-(Benzyl-sulfan-yl)phen-yl]-1,1,3,3-tetra-methyl-guanidine. Acta crystallographica. Section E, Structure reports online 20110501
SO2 capture by guanidinium-based ionic liquids: a theoretical study. The journal of physical chemistry. B 20110407
Organocatalytic sequential Michael reactions: stereoselective synthesis of multifunctionalized tetrahydroindan derivatives. Organic letters 20110304
Systematic investigation on the synthesis of androstane-based 3-, 11- and 17-carboxamides via palladium-catalyzed aminocarbonylation. Steroids 20110201
Intramolecular bromonium ion assisted epoxide ring-opening: capture of the oxonium ion with an added external nucleophile. The Journal of organic chemistry 20110107
Conformationally constrained histidines in the design of peptidomimetics: strategies for the χ-space control. International journal of molecular sciences 20110101
X-ray crystal structure, Raman spectroscopy, and Ab initio density functional theory calculations on 1,1,3,3-tetramethylguanidinium bromide. The journal of physical chemistry. A 20101223
The nature of protic ionic liquids in the gas phase revisited: Fourier transform ion cyclotron resonance mass spectrometry study of 1,1,3,3-tetramethylguanidinium chloride. The journal of physical chemistry. B 20100715
tert-Butyl 4-(2-diazo-acet-yl)piperazine-1-carboxyl-ate. Acta crystallographica. Section E, Structure reports online 20100601
HABA-based ionic liquid matrices for UV-MALDI-MS analysis of heparin and heparan sulfate oligosaccharides. Glycobiology 20100201
1,1,3,3-Tetramethylguanidine solvated lanthanide aryloxides: pre-catalysts for intramolecular hydroalkoxylation. Dalton transactions (Cambridge, England : 2003) 20091221
One-step synthesis and bioassay of N-phosphoramidophosphonates. Chemical & pharmaceutical bulletin 20091201
Use of a novel ionic liquid matrix for MALDI-MS analysis of glycopeptides and glycans out of total tryptic digests. Journal of mass spectrometry : JMS 20091101
Structurally characterized 1,1,3,3-tetramethylguanidine solvated magnesium aryloxide complexes: [Mg(mu-OEt)(DBP)(H-TMG)]2, [Mg(mu-OBc)(DBP)(H-TMG)]2, [Mg(mu-TMBA)(DBP)(H-TMG)]2, [Mg(mu-DPP)(DBP)(H-TMG)]2, [Mg(BMP)2(H-TMG)2], [Mg(O-2,6-Ph2C6H3)2 (H-TMG)2]. Inorganic chemistry 20090406
The synthesis of 13alpha-androsta-5,16-diene derivatives with carboxylic acid, ester and carboxamido functionalities at position-17 via palladium-catalyzed carbonylation. Steroids 20090101
Synthetic applications of polystyrene-supported 1,1,3,3-tetramethylguanidine. Combinatorial chemistry & high throughput screening 20081201
Formation of an ion-pair molecule with a single NH(+)...Cl(-) hydrogen bond: Raman spectra of 1,1,3,3-tetramethylguanidinium chloride in the solid state, in solution, and in the vapor phase. The journal of physical chemistry. A 20080918
The synthesis of 17-alkoxycarbonyl- and 17-carboxamido-13alpha-estra-1,3,5(10),16-tetraene derivatives via palladium-catalyzed carbonylation reactions. Steroids 20080701
Stable analogs of the uranyl ion containing 1,1,3,3-tetramethylguanidine. Dalton transactions (Cambridge, England : 2003) 20071107
Facile synthesis of 11-carboxamido-androst-4,9(11)-dienes via palladium-catalyzed aminocarbonylation. Steroids 20070701
Pt(II)-mediated nitrile-tetramethylguanidine coupling as a key step for a novel synthesis of 1,6-dihydro-1,3,5-dihydrotriazines. Inorganic chemistry 20070305
Structural and theoretical investigation of 2-iminoimidazolines--carbene analogues of iminophosphoranes. Organic & biomolecular chemistry 20070207
Similarities and differences between organic cation inhibition of the Na,K-ATPase and PMCA. Biochemistry 20061107
Facile synthesis of 12-carboxamido-11-spirostenes via palladium-catalyzed carbonylation reactions. Steroids 20061001
New force field for molecular simulation of guanidinium-based ionic liquids. The journal of physical chemistry. B 20060622
[Study on the vibrational spectra of two nitrobenzoyl substituted guanidines]. Guang pu xue yu guang pu fen xi = Guang pu 20060401
Microwave-assisted synthesis of pt nanocrystals and deposition on carbon nanotubes in ionic liquids. Journal of nanoscience and nanotechnology 20060101
Guanidinophosphazenes: design, synthesis, and basicity in THF and in the gas phase. Journal of the American Chemical Society 20051221
Practical synthesis of the new carbapenem antibiotic ertapenem sodium. The Journal of organic chemistry 20050916
Sustained serine proteases activity by prolonged increase in pH leads to degradation of lipid processing enzymes and profound alterations of barrier function and stratum corneum integrity. The Journal of investigative dermatology 20050901
A new, efficient method for direct alpha-alkenylation of beta-dicarbonyl compounds and phenols using alkenyltriarylbismuthonium salts. The Journal of organic chemistry 20040806
Recommended methods of fatty acid methylester preparation for conjugated dienes and trienes in food and biological samples. Journal of nutritional science and vitaminology 20040401
pH directly regulates epidermal permeability barrier homeostasis, and stratum corneum integrity/cohesion. The Journal of investigative dermatology 20030801
A novel and convenient chemoselective deprotection method for both silyl and acetyl groups on acidic hydroxyl groups such as phenol and carboxylic acid by using a nitrogen organic base, 1,1,3,3-tetramethylguanidine. Organic letters 20030123
Properties