(Trifluoromethyl)trimethylsilane
| Title | Journal |
|---|---|
| Copper-catalyzed nucleophilic trifluoromethylation of allylic halides: a simple approach to allylic trifluoromethylation. | Chemistry (Weinheim an der Bergstrasse, Germany) 20121015 |
| Copper-catalyzed oxidative trifluoromethylation of terminal alkenes using nucleophilic CF3SiMe3: efficient C(sp3)-CF3 bond formation. | Organic letters 20120420 |
| Stereoselective access to fluorinated and non-fluorinated quaternary piperidines: synthesis of pipecolic acid and iminosugar derivatives. | Chemistry (Weinheim an der Bergstrasse, Germany) 20120319 |
| Copper-catalyzed oxidative trifluoromethylthiolation of aryl boronic acids with TMSCF3 and elemental sulfur. | Angewandte Chemie (International ed. in English) 20120305 |
| Copper-catalyzed oxidative trifluoromethylation of terminal alkynes and aryl boronic acids using (trifluoromethyl)trimethylsilane. | The Journal of organic chemistry 20120203 |
| Silver-mediated trifluoromethylation of arenes using TMSCF3. | Organic letters 20111021 |
| The role of the counterion and of silicon chelation in the selective mono(trifluoromethylation) of tartaric acid derived 1,4-diketones. | Chemistry (Weinheim an der Bergstrasse, Germany) 20110912 |
| Synthesis of gem-difluorinated cyclopropanes and cyclopropenes: trifluoromethyltrimethylsilane as a difluorocarbene source. | Angewandte Chemie (International ed. in English) 20110725 |
| Cinchona alkaloid-catalyzed asymmetric trifluoromethylation of alkynyl ketones with trimethylsilyl trifluoromethane. | Organic letters 20101119 |
| Copper-mediated oxidative trifluoromethylation of boronic acids. | Organic letters 20101105 |
| Benzoyl peroxide (BPO)-promoted oxidative trifluoromethylation of tertiary amines with trimethyl(trifluoromethyl)silane. | Chemical communications (Cambridge, England) 20100914 |
| Catalytic enantioselective trifluoromethylation of azomethine imines with trimethyl(trifluoromethyl)silane. | Angewandte Chemie (International ed. in English) 20090101 |
| Enantiopure quaternary alpha-trifluoromethyl-alpha-alkoxyaldehydes from L-tartaric acid derived ketoamides. | The Journal of organic chemistry 20081017 |
| Copper-catalyzed silylation of cyclopropenes using (trifluoromethyl)trimethylsilane. | Chemical communications (Cambridge, England) 20080307 |
| Addition of trifluoromethyltrimethylsilane to acyl phosphonates: synthesis of TMS-protected 1-alkyl-1-trifluoromethyl-1-hydroxyphosphonates and 1-aryldifluoroethenyl phosphates. | The Journal of organic chemistry 20071026 |
| Synthesis of enantiopure trifluoromethyl building blocks via a highly chemo- and diastereoselective nucleophilic trifluoromethylation of tartaric acid-derived diketones. | The Journal of organic chemistry 20070216 |
| Facile synthesis of TMS-protected trifluoromethylated alcohols using trifluoromethyltrimethylsilane (TMSCF3) and various nucleophilic catalysts in DMF. | The Journal of organic chemistry 20060901 |
| Preparation of tri- and difluoromethylated amines from aldimines using (trifluoromethyl)trimethylsilane. | Organic letters 20060803 |
| An efficient synthesis of enantiomerically enriched trifluoromethylated 1,2-diols and 1,2-amino alcohols with quaternary stereocenters by diastereoselective addition of TMSCF3 to chiral 2-acyl-1,3-perhydrobenzoxazines. | The Journal of organic chemistry 20060303 |
| How trimethyl(trifluoromethyl)silane reacts with itself in the presence of naked fluoride--a one-pot synthesis of bis([15]crown-5)cesium 1,1,1,3,5,5,5-heptafluoro-2,4-bis(trifluoromethyl)pentenide. | Chemistry (Weinheim an der Bergstrasse, Germany) 20051104 |
| Gas phase structure of Ruppert's reagent, CF3SiMe3. | The journal of physical chemistry. A 20050922 |
| Trifluoromethyl derivatives of pentacyclo[5.4.0.0(2,6).0(3,10).0(5,9)]undecane. | Acta crystallographica. Section C, Crystal structure communications 20050401 |
| The first Cu(I)-mediated nucleophilic trifluoromethylation reactions using (trifluoromethyl)trimethylsilane in ionic liquids. | Organic & biomolecular chemistry 20041007 |
| Early transition-metal perfluoroalkyl complexes. | Journal of the American Chemical Society 20031203 |
| Regioselective nucleophilic 1,4-trifluoromethylation of 2-polyfluoroalkylchromones with (trifluoromethyl)trimethylsilane. Synthesis of fluorinated analogs of natural 2,2-dimethylchroman-4-ones and 2,2-dimethylchromenes. | The Journal of organic chemistry 20031003 |
| Preparation of tri- and difluoromethylsilanes via an unusual magnesium metal-mediated reductive tri- and difluoromethylation of chlorosilanes using tri- and difluoromethyl sulfides, sulfoxides, and sulfones. | The Journal of organic chemistry 20030530 |
| Stereoselective synthesis of trifluoromethylated vicinal ethylenediamines with alpha-amino N-tert-butanesulfinimines and TMSCF3. | Journal of the American Chemical Society 20020612 |
| Abstracts of the XV International Ecdysone Workshop. June 30- July 6, 2002. Kolymbari Crete, Greece. | Journal of insect science (Online) 20020101 |
| Bis(acylsilanes) and trifluoromethyltrimethylsilane: a useful system for the synthesis of cyclic 2,2-difluoro-3-trialkylsilyl-1,3-ketols and cyclic 2-fluoro-1,3-diketones(1). | The Journal of organic chemistry 20010629 |
| Acetyltrimethylsilane, trifluoromethyltrimethylsilane, and prenyl esters: a three-component system for the synthesis of gem-difluoroanalogues of monoterpenes. | The Journal of organic chemistry 20010615 |
| Mixed organofluorine-organosilicon chemistry. 13. One-pot synthesis of difluoroaldols from acylsilanes and trifluoromethyltrimethylsilane. application to the synthesis of a difluoro analogue of egomaketone. | The Journal of organic chemistry 20010323 |
| A simple and efficient approach for the synthesis of fluorinated and nonfluorinated octaethylporphyrin-based benzochlorins with variable lipophilicity, their in vivo tumor uptake, and the preliminary in vitro photosensitizing efficacy. | The Journal of organic chemistry 20010223 |
| Diketo compounds with (trifluoromethyl)trimethylsilane: double nucleophilic trifluoromethylation reactions. | The Journal of organic chemistry 20010223 |
| Reactions of difluoroenoxysilanes with glycosyl donors: synthesis of difluoro-C-glycosides and difluoro-C-disaccharides. | Chemistry (Weinheim an der Bergstrasse, Germany) 20010101 |