Home Other Building Blocks (R)-(+)-α-Methoxy-α-(trifluoromethyl)phenylacetyl chloride

(R)-(+)-α-Methoxy-α-(trifluoromethyl)phenylacetyl chloride

CAS No.:
39637-99-5
Catalog Number:
AG003CHN
Molecular Formula:
C10H8ClF3O2
Molecular Weight:
252.6175
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
100mg
>99.0%(GC)(T)
1 week
United States
$103
- +
1g
>99.0%(GC)(T)
1 week
United States
$423
- +
5g
1 week
United States
$859
- +
Product Description
Catalog Number:
AG003CHN
Chemical Name:
(R)-(+)-α-Methoxy-α-(trifluoromethyl)phenylacetyl chloride
CAS Number:
39637-99-5
Molecular Formula:
C10H8ClF3O2
Molecular Weight:
252.6175
MDL Number:
MFCD00044400
IUPAC Name:
(2R)-3,3,3-trifluoro-2-methoxy-2-phenylpropanoyl chloride
InChI:
InChI=1S/C10H8ClF3O2/c1-16-9(8(11)15,10(12,13)14)7-5-3-2-4-6-7/h2-6H,1H3/t9-/m0/s1
InChI Key:
PAORVUMOXXAMPL-VIFPVBQESA-N
SMILES:
CO[C@@](C(F)(F)F)(c1ccccc1)C(=O)Cl
UNII:
81UT10UHV3
Properties
Complexity:
261  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
1  
Defined Bond Stereocenter Count:
0
Exact Mass:
252.016g/mol
Formal Charge:
0
Heavy Atom Count:
16  
Hydrogen Bond Acceptor Count:
5  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
252.617g/mol
Monoisotopic Mass:
252.016g/mol
Rotatable Bond Count:
3  
Topological Polar Surface Area:
26.3A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
3.3  
Literature
Title Journal
Stereoselective method development and validation for determination of concentrations of amphetamine-type stimulants and metabolites in human urine using a simultaneous extraction-chiral derivatization approach. Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20110101
Development of a simultaneous liquid-liquid extraction and chiral derivatization method for stereospecific GC-MS analysis of amphetamine-type stimulants in human urine using fractional factorial design. Biomedical chromatography : BMC 20080901
Quantitative and isomeric determination of amphetamine and methamphetamine from urine using a nonprotic elution solvent and R(-)-alpha-methoxy-alpha-trifluoromethylphenylacetic acid chloride derivatization. Journal of analytical toxicology 20051001
Enantiomeric separation and quantitation of (+/-)-amphetamine, (+/-)-methamphetamine, (+/-)-MDA, (+/-)-MDMA, and (+/-)-MDEA in urine specimens by GC-EI-MS after derivatization with (R)-(-)- or (S)-(+)-alpha-methoxy-alpha-(trifluoromethy)phenylacetyl chloride (MTPA). Journal of analytical toxicology 20040901
Synthesis, resolution, and determination of the absolute configuration of the enantiomers of cis-4,5-dihydroxy-1,2-dithiane 1,1-dioxide, an HIV-1NCp7 inhibitor. Bioorganic & medicinal chemistry 20030717
Method development for the high-performance liquid chromatographic enantioseparation of 2-cyanocycloalkanols. Journal of chromatographic science 20010501
Properties