Home Other Building Blocks 2-(Diphenylphosphino)benzoic acid

2-(Diphenylphosphino)benzoic acid

CAS No.:
17261-28-8
Catalog Number:
AG0037ZK
Molecular Formula:
C19H15O2P
Molecular Weight:
306.2950
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
1g
98%
In Stock USA
United States
$17
- +
5g
98%
In Stock USA
United States
$50
- +
10g
98%
In Stock USA
United States
$82
- +
25g
98%
In Stock USA
United States
$169
- +
100g
98%
In Stock USA
United States
$525
- +
Product Description
Catalog Number:
AG0037ZK
Chemical Name:
2-(Diphenylphosphino)benzoic acid
CAS Number:
17261-28-8
Molecular Formula:
C19H15O2P
Molecular Weight:
306.2950
MDL Number:
MFCD00674024
IUPAC Name:
2-diphenylphosphanylbenzoic acid
InChI:
InChI=1S/C19H15O2P/c20-19(21)17-13-7-8-14-18(17)22(15-9-3-1-4-10-15)16-11-5-2-6-12-16/h1-14H,(H,20,21)
InChI Key:
UYRPRYSDOVYCOU-UHFFFAOYSA-N
SMILES:
OC(=O)c1ccccc1P(c1ccccc1)c1ccccc1
EC Number:
241-293-7
Properties
Complexity:
340  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
306.081g/mol
Formal Charge:
0
Heavy Atom Count:
22  
Hydrogen Bond Acceptor Count:
2  
Hydrogen Bond Donor Count:
1  
Isotope Atom Count:
0
Molecular Weight:
306.301g/mol
Monoisotopic Mass:
306.081g/mol
Rotatable Bond Count:
4  
Topological Polar Surface Area:
37.3A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
4.1  
Literature
Title Journal
Stereoselective synthesis of trisubstituted olefins by a directed allylic substitution strategy. Chemistry (Weinheim an der Bergstrasse, Germany) 20111010
Stereoselective and diversity-oriented synthesis of trisubstituted allylic alcohols and amines. Chemistry (Weinheim an der Bergstrasse, Germany) 20111010
Ruthenium-catalysed linear-selective allylic alkylation of allyl acetates. Chemical communications (Cambridge, England) 20070121
Electronic differentiation competes with transition state sensitivity in palladium-catalyzed allylic substitutions. Beilstein journal of organic chemistry 20070101
Predicting the stereochemistry of diphenylphosphino benzoic acid (DPPBA)-based palladium-catalyzed asymmetric allylic alkylation reactions: a working model. Accounts of chemical research 20061001
Hybridization dependent cleavage of internally modified disulfide-peptide nucleic acids. Bioorganic & medicinal chemistry letters 20050201
Synthesis, characterization and antioxidant activity of new copper(I) complexes of scorpionate and water soluble phosphane ligands. Dalton transactions (Cambridge, England : 2003) 20040907
Heterodimerization of olefins. 1. Hydrovinylation reactions of olefins that are amenable to asymmetric catalysis. The Journal of organic chemistry 20031031
Dynamic kinetic asymmetric cycloadditions of isocyanates to vinylaziridines. Journal of the American Chemical Society 20031001
New diphosphine ligands containing ethyleneglycol and amino alcohol spacers for the rhodium-catalyzed carbonylation of methanol. Chemistry (Weinheim an der Bergstrasse, Germany) 20020802
Geminal dicarboxylates as carbonyl surrogates for asymmetric synthesis. Part I. Asymmetric addition of malonate nucleophiles. Journal of the American Chemical Society 20010425
Properties