Home Other Building Blocks Tris(pentafluorophenyl)borane

Tris(pentafluorophenyl)borane

CAS No.:
1109-15-5
Catalog Number:
AG003661
Molecular Formula:
C18BF15
Molecular Weight:
511.9796
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
1g
95%
In Stock USA
United States
$88
- +
5g
95%
In Stock USA
United States
$319
- +
10g
95%
In Stock USA
United States
$619
- +
25g
95%
In Stock USA
United States
$1438
- +
Product Description
Catalog Number:
AG003661
Chemical Name:
Tris(pentafluorophenyl)borane
CAS Number:
1109-15-5
Molecular Formula:
C18BF15
Molecular Weight:
511.9796
MDL Number:
MFCD00269813
IUPAC Name:
tris(2,3,4,5,6-pentafluorophenyl)borane
InChI:
InChI=1S/C18BF15/c20-4-1(5(21)11(27)16(32)10(4)26)19(2-6(22)12(28)17(33)13(29)7(2)23)3-8(24)14(30)18(34)15(31)9(3)25
InChI Key:
OBAJXDYVZBHCGT-UHFFFAOYSA-N
SMILES:
Fc1c(B(c2c(F)c(F)c(c(c2F)F)F)c2c(F)c(F)c(c(c2F)F)F)c(F)c(c(c1F)F)F
UNII:
I3WU5E2578
Properties
Complexity:
566  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
511.985g/mol
Formal Charge:
0
Heavy Atom Count:
34  
Hydrogen Bond Acceptor Count:
15  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
511.984g/mol
Monoisotopic Mass:
511.985g/mol
Rotatable Bond Count:
3  
Topological Polar Surface Area:
0A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
Literature
Title Journal
Highly sensitive NH3 detection based on organic field-effect transistors with tris(pentafluorophenyl)borane as receptor. Journal of the American Chemical Society 20120912
[2.2]Paracyclophane derived bisphosphines for the activation of hydrogen by FLPs: application in domino hydrosilylation/hydrogenation of enones. Dalton transactions (Cambridge, England : 2003) 20120814
The structure and chemistry of tris(pentafluorophenyl)borane protected mononuclear nitridotitanium complexes. Dalton transactions (Cambridge, England : 2003) 20120514
Tri-tert-butyl-phospho-nium hy-droxy-tris-(penta-fluoro-phen-yl)borate. Acta crystallographica. Section E, Structure reports online 20120501
Dispersion energy enforced dimerization of a cyclic disilylated plumbylene. Journal of the American Chemical Society 20120411
2-Vinyl-pyridine-tris-(penta-fluoro-phen-yl)borane hexane monosolvate. Acta crystallographica. Section E, Structure reports online 20120401
Liquid triarylamines: the scope and limitations of Piers-Rubinsztajn conditions for obtaining triarylamine-siloxane hybrid materials. The Journal of organic chemistry 20120217
Mechanistic aspects of bond activation with perfluoroarylboranes. Inorganic chemistry 20111219
Dihydrogen activation by frustrated carbene-borane Lewis pairs: an experimental and theoretical study of carbene variation. Inorganic chemistry 20110801
Extent of M2 δ to ligand π-conjugation in neutral and mixed valence states of bis(4-isonicotinate)-bis(2,4,6-triisopropylbenzoate) dimetal complexes (MM), where M = Mo or W, and their adducts with tris(pentafluorophenyl)boron. Journal of the American Chemical Society 20110420
Siloxane-triarylamine hybrids: discrete room temperature liquid triarylamines via the Piers-Rubinsztajn reaction. Organic letters 20110107
Tandem frustrated Lewis pair/tris(pentafluorophenyl)borane-catalyzed deoxygenative hydrosilylation of carbon dioxide. Journal of the American Chemical Society 20100811
Facile synthesis of dichlorosilane by metathesis reaction and dehydrogenation of dihydrogermane by a frustrated Lewis pair. Dalton transactions (Cambridge, England : 2003) 20100721
Synthesis, structure, and stability of adducts between phosphide and amide anions and the Lewis acids borane, tris(pentafluorophenyl)borane, and tris(pentafluorophenyl)alane. Inorganic chemistry 20091207
On the possibility of catalytic reduction of carbonyl moieties with tris(pentafluorophenyl)borane and H2: a computational study. Dalton transactions (Cambridge, England : 2003) 20090807
The synthesis, molecular structure and supramolecular architecture of complexes between the ammonia adduct of tris(pentafluorophenyl)boron and a series of mono and polydentate hydrogen-bond acceptors. Dalton transactions (Cambridge, England : 2003) 20081207
Metal-free catalytic hydrogenation of imines with tris(perfluorophenyl)borane. Chemical communications (Cambridge, England) 20080514
Reversible, metal-free hydrogen activation. Science (New York, N.Y.) 20061117
From carbon dioxide to methane: homogeneous reduction of carbon dioxide with hydrosilanes catalyzed by zirconium-borane complexes. Journal of the American Chemical Society 20060927
Regulation of stereoselectivity using Lewis acid in the cyclization of allenic aldehydes catalyzed by palladium complex. Organic letters 20050818
Intra- and intermolecular N-H...F-C hydrogen-bonding interactions in amine adducts of tris(pentafluorophenyl)borane and -alane. Inorganic chemistry 20050808
Oxygen-bridged borate anions from tris(pentafluorophenyl)borane: synthesis, NMR characterization, and reactivity. Inorganic chemistry 20050711
Tris(pentafluorophenyl)borane: a special boron Lewis acid for special reactions. Dalton transactions (Cambridge, England : 2003) 20050607
Ring-opening reactions of nonactivated aziridines catalyzed by tris(pentafluorophenyl)borane. The Journal of organic chemistry 20030627
Reactions of titanium and zirconium derivatives of Bis(trimethylsilyl)acetylene with Tris(pentafluorophenyl)borane: a titanium(III) complex of an alkynylboranate. Angewandte Chemie (International ed. in English) 20030328
Rapid access to polyketide scaffolds via vinylogous Mukaiyama aldol reactions. Organic letters 20011101
Living polymerization and block copolymerization of alpha-olefins by an amine bis(phenolate) titanium catalyst. Chemical communications (Cambridge, England) 20011021
Synthesis, structures, and reactivity of weakly coordinating anions with delocalized borate structure: the assessment of anion effects in metallocene polymerization catalysts. Journal of the American Chemical Society 20010117
Properties