Home Other Building Blocks Titanium(IV) isopropoxide

Titanium(IV) isopropoxide

CAS No.:
546-68-9
Catalog Number:
AG0035WN
Molecular Formula:
C12H28O4Ti
Molecular Weight:
284.2153
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
5g
95%
In Stock USA
United States
$13
- +
25g
95%
In Stock USA
United States
$19
- +
100g
95%
In Stock USA
United States
$50
- +
500g
95%
In Stock USA
United States
$188
- +
Product Description
Catalog Number:
AG0035WN
Chemical Name:
Titanium(IV) isopropoxide
CAS Number:
546-68-9
Molecular Formula:
C12H28O4Ti
Molecular Weight:
284.2153
MDL Number:
MFCD00008871
IUPAC Name:
propan-2-olate;titanium(4+)
InChI:
InChI=1S/4C3H7O.Ti/c4*1-3(2)4;/h4*3H,1-2H3;/q4*-1;+4
InChI Key:
VXUYXOFXAQZZMF-UHFFFAOYSA-N
SMILES:
[O-]C(C)C.[O-]C(C)C.[O-]C(C)C.[O-]C(C)C.[Ti+4]
EC Number:
208-909-6
UNII:
76NX7K235Y
UN Number:
1993
Properties
Complexity:
10.8  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
5  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
284.147g/mol
Formal Charge:
0
Heavy Atom Count:
17  
Hydrogen Bond Acceptor Count:
4  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
284.219g/mol
Monoisotopic Mass:
284.147g/mol
Rotatable Bond Count:
0
Topological Polar Surface Area:
92.2A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
Literature
Title Journal
Development and application of a new solid-phase microextraction fiber by sol-gel technology on titanium wire. Analytica chimica acta 20120912
One-pot deposition of palladium on hybrid TiO2 nanoparticles and catalytic applications in hydrogenation. Journal of colloid and interface science 20120301
Assessment of by-products of chlorination and photoelectrocatalytic chlorination of an azo dye. Journal of hazardous materials 20120227
Enhanced visible light photocatalytic disinfection of gram negative, pathogenic Escherichia coli bacteria with Ag/TiV oxide nanoparticles. Colloids and surfaces. B, Biointerfaces 20110801
Cyclopropylamines from N,N-dialkylcarboxamides and Grignard reagents in the presence of titanium tetraisopropoxide or methyltitanium triisopropoxide. Chemistry (Weinheim an der Bergstrasse, Germany) 20101210
Catalytic reactions of titanium alkoxides with Grignard reagents and imines: a mechanistic study. Chemistry, an Asian journal 20100802
Concerning the potential reversibility of carbometalation in alkoxide-directed Ti(Oi-Pr)4-mediated reductive cross-coupling of homoallylic alcohols with aromatic imines. Chemical communications (Cambridge, England) 20100521
Titanium(IV) isopropoxide mediated synthesis of pyrimidin-4-ones. Organic letters 20100521
Effects of bias voltage on diamond like carbon coatings deposited using titanium isopropoxide (TIPOT) and acetylene/argon mixtures onto various substrate materials. Journal of nanoscience and nanotechnology 20100401
Controlled oxidation of organic sulfides to sulfoxides under ambient conditions by a series of titanium isopropoxide complexes using environmentally benign H2O2 as an oxidant. Dalton transactions (Cambridge, England : 2003) 20100307
Highly enantioselective addition of terminal alkynes to aldehydes catalyzed by a new chiral beta-sulfonamide alcohol/Ti(OiPr)4/Et2Zn/R3N catalyst system. Chirality 20090201
Fabrication of platy apatite nanocrystals loaded with TiO2 nanoparticles by two-step emulsion method and their photocatalytic activity. Journal of colloid and interface science 20081015
A theoretical analysis of the Ti(IV)-catalyzed glycoaminocyanation reaction. Carbohydrate research 20080721
Catalytic asymmetric aryl transfer reactions to aldehydes with Grignard reagents as the aryl source. Chemistry (Weinheim an der Bergstrasse, Germany) 20080101
Active cytotoxic reagents based on non-metallocene non-diketonato well-defined C2-symmetrical titanium complexes of tetradentate bis(phenolato) ligands. Journal of the American Chemical Society 20071010
Highly enantioselective alkynylation of aldehydes using a new BINOL/Ti(OiPr)4/chiral sulfonamide catalyst system. Chirality 20070801
Highly concentrated catalytic asymmetric allylation of ketones. Organic letters 20070201
Transformation of D-(-)-ribose into a natural product-like scaffold via a Lewis acid catalyzed intramolecular hetero-Diels-Alder reaction. Nucleosides, nucleotides & nucleic acids 20070101
Titanium, zinc and alkaline-earth metal complexes supported by bulky O,N,N,O-multidentate ligands: syntheses, characterisation and activity in cyclic ester polymerisation. Dalton transactions (Cambridge, England : 2003) 20060114
Synthesis of TiO2 photocatalysts in supercritical CO2 via a non-hydrolytic route. The journal of physical chemistry. B 20051013
Palladium-catalyzed allylation of acidic and less nucleophilic anilines using allylic alcohols directly. Chemical & pharmaceutical bulletin 20051001
The rhodium catalyzed three-component reaction of diazoacetates, titanium(IV) alkoxides and aldehydes. Chemical communications (Cambridge, England) 20050528
Readily available sulfamide-amine alcohols for enantioselective phenylacetylene addition to aldehydes in the absence of Ti(O(i)Pr)4. Chirality 20050515
Controlled delivery of paclitaxel from stent coatings using poly(hydroxystyrene-b-isobutylene-b-hydroxystyrene) and its acetylated derivative. Biomacromolecules 20050101
Photodegradation of surfactants on the nanosized TiO2 prepared by hydrolysis of the alkoxide titanium. Chemosphere 20040101
Reagentless amperometric immunosensors based on direct electrochemistry of horseradish peroxidase for determination of carcinoma antigen-125. Analytical chemistry 20031015
Highly enantioselective reductive amination of simple aryl ketones catalyzed by Ir-f-Binaphane in the presence of titanium(IV) isopropoxide and iodine. The Journal of organic chemistry 20030516
A convenient synthesis of 1,1-disubstituted 1,2,3,4-tetrahydroisoquinolines via Pictet-Spengler reaction using titanium(IV) isopropoxide and acetic-formic anhydride. Chemical & pharmaceutical bulletin 20020201
Properties