Home Halogens boron trifluoride ethyl ether

boron trifluoride ethyl ether

CAS No.:
109-63-7
Catalog Number:
AG0035VH
Molecular Formula:
C4H10BF3O
Molecular Weight:
141.9278
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
Product Description
Catalog Number:
AG0035VH
Chemical Name:
boron trifluoride ethyl ether
CAS Number:
109-63-7
Molecular Formula:
C4H10BF3O
Molecular Weight:
141.9278
MDL Number:
MFCD00013194
IUPAC Name:
ethoxyethane;trifluoroborane
InChI:
InChI=1S/C4H10O.BF3/c1-3-5-4-2;2-1(3)4/h3-4H2,1-2H3;
InChI Key:
KZMGYPLQYOPHEL-UHFFFAOYSA-N
SMILES:
FB(F)F.CCOCC
EC Number:
203-689-8
Properties
Complexity:
19.1  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
2  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
142.078g/mol
Formal Charge:
0
Heavy Atom Count:
9  
Hydrogen Bond Acceptor Count:
4  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
141.928g/mol
Monoisotopic Mass:
142.078g/mol
Rotatable Bond Count:
2  
Topological Polar Surface Area:
9.2A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
Literature
Title Journal
Benzoylated ethyl 1-thioglycosides: direct preparation from per-O-benzoylated sugars. Carbohydrate research 20120801
BF₃·Et₂O-induced stereoselective aldol reaction with benzaldehyde, and steroid sapogenins and its application to a convenient synthesis of dinorcholanic lactones. Steroids 20120601
Rapid conversion of spirostans into furostan skeletons at room temperature. Steroids 20120101
The cephalostatins. 21. Synthesis of bis-steroidal pyrazine rhamnosides (1). Journal of natural products 20110923
(1-Alkynyl)dicarbonylcyclopentadienyliron complexes as electron-rich alkynes in organic synthesis: BF3-mediated [2+2] cycloaddition/ring-opening providing (2-alkenyl-1-imino)iron complexes. Chemistry (Weinheim an der Bergstrasse, Germany) 20110725
Unexpectedly convenient and stereoselective synthesis of 4α-acyloxy-2-chloropodophyllotoxins in the presence of BF₃ ·Et₂O. Bioorganic & medicinal chemistry letters 20110701
Synthesis of oxabicyclo[3.3.1]nonenes and substituted tetrahydropyrans via (3,5)-oxonium-ene reaction. Organic & biomolecular chemistry 20110621
Studies on the BF3·Et2O catalyzed Baeyer-Villiger reaction of spiroketalic steroidal ketones. Steroids 20110201
Synthesis and antiproliferative activities of novel 5'-Schiff-base group substituted psoralen derivatives. Yao xue xue bao = Acta pharmaceutica Sinica 20110101
Revisiting the aldol reaction of cis-α,β-epoxyaldehyde promoted by BF(3)·Et(2)O: direct access to 2-deoxy-2-fluoro heptulosonic ester analogues. Carbohydrate research 20101122
Stereochemical surprises in the Lewis acid-mediated allylation of isatins. The Journal of organic chemistry 20101001
BF3-promoted synthesis of diarylhexahydrobenzo[f]isoquinoline. Organic letters 20100319
Stereoselective radical addition of an acetal to sterically tuned enantiomerically pure N-sulfinyl imines. Chemical & pharmaceutical bulletin 20100201
One-pot cross-coupling of N-acyl N,O-acetals with alpha,beta-unsaturated compounds. Chemical communications (Cambridge, England) 20091207
Stereoselective one-pot, three-component synthesis of 4-aryltetrahydropyran via Prins-Friedel-Crafts reaction. The Journal of organic chemistry 20090320
C-H bond functionalization via hydride transfer: Lewis acid catalyzed alkylation reactions by direct intramolecular coupling of sp3 C-H bonds and reactive alkenyl oxocarbenium intermediates. Journal of the American Chemical Society 20090121
One-pot synthesis of chemically modified vegetable oils. Journal of agricultural and food chemistry 20080514
The O-acylation of ketone enolates by allyl 1H-imidazole-1-carboxylate mediated with boron trifluoride etherate: a convenient procedure for the synthesis of substituted allyl enol carbonates. The Journal of organic chemistry 20071123
Synthesis and anti-inflammatory activity of N-phthalimidomethyl 2,3-dideoxy- and 2,3-unsaturated glycosides. Carbohydrate research 20070702
Delocalized carotenoid cations in relation to the soliton model. Journal of the American Chemical Society 20040728
Reaction of mono-epoxidized conjugated linoleic acid ester with boron trifluoride etherate complex. Lipids 20040601
Novel halo-oxo-allenic fatty ester derivatives from epoxidized methyl santalbate (methyl trans-11-octadecen-9-ynoate). Chemistry and physics of lipids 20031001
Glycosylation of sialyl acetates with a novel catalyst combination: bismuth triflate and BF3.OEt2 system. Bioorganic & medicinal chemistry 20030717
Beta-anomeric selectivity in the glycosidation of D-mannofuranurono-6,3-lactone catalyzed by boron trifluoride diethyl etherate. Carbohydrate research 20030207
A synthesis of 3-phenyl-1,2,3,4-tetrahydroisoquinoline and 2-phenyl-1,2,4,5-tetrahydro-3H-3-benzazepine via Pummerer-type cyclization: enhancing effect of boron trifluoride diethyl etherate on the cyclization. Chemical & pharmaceutical bulletin 20010801
Properties