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Vinyltrimethylsilane

CAS No.:
754-05-2
Catalog Number:
AG0035SO
Molecular Formula:
C5H12Si
Molecular Weight:
100.2343
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
5g
95%
In Stock USA
United States
$44
- +
25g
95%
In Stock USA
United States
$110
- +
100g
95%
In Stock USA
United States
$304
- +
Product Description
Catalog Number:
AG0035SO
Chemical Name:
Vinyltrimethylsilane
CAS Number:
754-05-2
Molecular Formula:
C5H12Si
Molecular Weight:
100.2343
MDL Number:
MFCD00008606
IUPAC Name:
ethenyl(trimethyl)silane
InChI:
InChI=1S/C5H12Si/c1-5-6(2,3)4/h5H,1H2,2-4H3
InChI Key:
GCSJLQSCSDMKTP-UHFFFAOYSA-N
SMILES:
C=C[Si](C)(C)C
EC Number:
212-042-9
UNII:
H5HJ2RET1N
NSC Number:
93553
Properties
Complexity:
49.4  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
100.071g/mol
Formal Charge:
0
Heavy Atom Count:
6  
Hydrogen Bond Acceptor Count:
0
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
100.236g/mol
Monoisotopic Mass:
100.071g/mol
Rotatable Bond Count:
1  
Topological Polar Surface Area:
0A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
Literature
Title Journal
Iron-catalyzed unexpected easy access to stereodefined trimethylsilyl vinyl ketenes. Organic letters 20120817
(E)-9-(2-iodovinyl)-9H-carbazole: a new coupling reagent for the synthesis of π-conjugated carbazoles. Organic letters 20110415
Room-temperature regioselective C-H/olefin coupling of aromatic ketones using an activated ruthenium catalyst with a carbonyl ligand and structural elucidation of key intermediates. Journal of the American Chemical Society 20101222
Development of a general, sequential, ring-closing metathesis/intramolecular cross-coupling reaction for the synthesis of polyunsaturated macrolactones. Journal of the American Chemical Society 20100825
Cobalt-catalyzed regio- and stereoselective intermolecular enyne coupling: an efficient route to 1,3-diene derivatives. Chemical communications (Cambridge, England) 20100321
Quantum chemical studies on substitution effects within silyl group in the silylative coupling of olefins. Journal of molecular modeling 20100301
Palladium-catalyzed cyclopropanation of alkenyl silanes by diazoalkanes: evidence for a Pd(0) mechanism. Chemistry (Weinheim an der Bergstrasse, Germany) 20090101
Why does fluoride anion accelerate transmetalation between vinylsilane and palladium(II)-vinyl complex? Theoretical study. Journal of the American Chemical Society 20081001
Scope and mechanism of the intermolecular addition of aromatic aldehydes to olefins catalyzed by Rh(I) olefin complexes. Journal of the American Chemical Society 20070221
Part 3. Triethylborane-air: a suitable initiator for intermolecular radical additions of S-2-oxoalkyl-thionocarbonates (S-xanthates) to olefins. Beilstein journal of organic chemistry 20070101
Cobalt-mediated cross-coupling reactions of primary and secondary alkyl halides with 1-(trimethylsilyl)ethenyl- and 2-trimethylsilylethynylmagnesium reagents. Organic letters 20060706
Vinyltrimethylsilane (VTMS) as a probe of chemical reactivity of a TiCN diffusion barrier-covered silicon surface. The journal of physical chemistry. B 20060316
Complex thermal chemistry of vinyltrimethylsilane on Si(100)-2x1. The journal of physical chemistry. B 20050505
Photochemical reactions of [CH2(eta5-C5H4)2][Rh(C2H4)2]2 with silanes: evidence for Si-C and C-H activation pathways. Dalton transactions (Cambridge, England : 2003) 20050221
Cationic carbohydroxylation of alkenes and alkynes using the cation pool method. Organic letters 20040805
Synthesis and structure of polymeric networks of silver hexafluoroacetylacetonate complexes of THF, toluene, and vinyltrimethylsilane. Inorganic chemistry 20031215
Preparation of optically pure propargylic and allylic alcohols from 2-(trimethylsilyl)vinyl sulfoxides as a chiral ethynyl anion synthon: computational studies on elimination reaction of 2-(trimethylsilyl)vinyl sulfoxides. The Journal of organic chemistry 20020208
Trimethylsilyl group migrations in cryogenic ozonolysis of trimethylsilylethene: evidence for nonconcerted primary ozonide decomposition pathway. The Journal of organic chemistry 20011019
Properties