Home Other Building Blocks Tri-o-tolylphosphine

Tri-o-tolylphosphine

CAS No.:
6163-58-2
Catalog Number:
AG0035RL
Molecular Formula:
C21H21P
Molecular Weight:
304.3652
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
5g
97%
In Stock USA
United States
$13
- +
25g
97%
In Stock USA
United States
$35
- +
100g
97%
In Stock USA
United States
$94
- +
500g
97%
In Stock USA
United States
$350
- +
Product Description
Catalog Number:
AG0035RL
Chemical Name:
Tri-o-tolylphosphine
CAS Number:
6163-58-2
Molecular Formula:
C21H21P
Molecular Weight:
304.3652
MDL Number:
MFCD00008514
IUPAC Name:
tris(2-methylphenyl)phosphane
InChI:
InChI=1S/C21H21P/c1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3/h4-15H,1-3H3
InChI Key:
COIOYMYWGDAQPM-UHFFFAOYSA-N
SMILES:
Cc1ccccc1P(c1ccccc1C)c1ccccc1C
EC Number:
228-193-9
UNII:
5M32DK8XA8
NSC Number:
116667
Properties
Complexity:
287  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
304.138g/mol
Formal Charge:
0
Heavy Atom Count:
22  
Hydrogen Bond Acceptor Count:
0
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
304.373g/mol
Monoisotopic Mass:
304.138g/mol
Rotatable Bond Count:
3  
Topological Polar Surface Area:
0A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
5.7  
Literature
Title Journal
Effects of phosphorus substituents on reactions of α-alkoxyphosphonium salts with nucleophiles. Chemistry (Weinheim an der Bergstrasse, Germany) 20120903
Mechanochemical and solution synthesis, X-ray structure and IR and 31P solid state NMR spectroscopic studies of copper(I) thiocyanate adducts with bulky monodentate tertiary phosphine ligands. Dalton transactions (Cambridge, England : 2003) 20120707
Palladium-catalyzed cross-coupling of sterically demanding boronic acids with α-bromocarbonyl compounds. The Journal of organic chemistry 20111007
Synthesis and antibacterial activity of 2, 3-dehydro-3-O-(3-aryl-E-prop-2-enyl)-10, 11-anhydroclarithromycin derivatives. The Journal of antibiotics 20110401
Imaging of I2-imidazoline receptors by small-animal PET using 2-(3-fluoro-[4-11C]tolyl)-4,5-dihydro-1H-imidazole ([11C]FTIMD). Nuclear medicine and biology 20100701
Remarkable effect of phosphine on the reactivity of O,P-acetal--efficient substitution reaction of O,P-acetal. Chemical communications (Cambridge, England) 20100614
Synthesis of InP nanofibers from tri(m-tolyl)phosphine: an alternative route to metal phosphide nanostructures. Dalton transactions (Cambridge, England : 2003) 20100107
Palladium-catalyzed intramolecular C(sp(3))--H functionalization: catalyst development and synthetic applications. Chemistry (Weinheim an der Bergstrasse, Germany) 20070101
Bulky triarylarsines are effective ligands for palladium catalysed Heck olefination. Dalton transactions (Cambridge, England : 2003) 20050421
Palladium-catalyzed intramolecular coupling between aryl iodides and allyl moieties via thermal and microwave-assisted conditions. Journal of the American Chemical Society 20050112
Unexpected hydrodeiodo Sonogashira-Heck-Casser coupling reaction of 2,2'-diiodobiphenyls with acetylenes. The Journal of organic chemistry 20020308
Properties