Home Other Building Blocks tert-Butyldimethylsilyl chloride

tert-Butyldimethylsilyl chloride

CAS No.:
18162-48-6
Catalog Number:
AG0035NH
Molecular Formula:
C6H15ClSi
Molecular Weight:
150.7218
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
5g
98%
In Stock USA
United States
$19
- +
25g
98%
In Stock USA
United States
$44
- +
100g
98%
In Stock USA
United States
$125
- +
500g
98%
In Stock USA
United States
$300
- +
Product Description
Catalog Number:
AG0035NH
Chemical Name:
tert-Butyldimethylsilyl chloride
CAS Number:
18162-48-6
Molecular Formula:
C6H15ClSi
Molecular Weight:
150.7218
MDL Number:
MFCD00000501
IUPAC Name:
tert-butyl-chloro-dimethylsilane
InChI:
InChI=1S/C6H15ClSi/c1-6(2,3)8(4,5)7/h1-5H3
InChI Key:
BCNZYOJHNLTNEZ-UHFFFAOYSA-N
SMILES:
C[Si](C(C)(C)C)(Cl)C
EC Number:
242-042-4
UNII:
550OPF5Z9F
Properties
Complexity:
81  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
150.063g/mol
Formal Charge:
0
Heavy Atom Count:
8  
Hydrogen Bond Acceptor Count:
0
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
150.721g/mol
Monoisotopic Mass:
150.063g/mol
Rotatable Bond Count:
1  
Topological Polar Surface Area:
0A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
Literature
Title Journal
2'-Azido RNA, a versatile tool for chemical biology: synthesis, X-ray structure, siRNA applications, click labeling. ACS chemical biology 20120316
Injection port silylation of γ-hydroxybutyrate and trans-hydroxycrotonic acid: conditions optimisation and characterisation of the di-tert-butyldimethylsilyl derivatives by GC-MS. The Analyst 20120107
Novel model of neuronal bioenergetics: postsynaptic utilization of glucose but not lactate correlates positively with Ca2+ signalling in cultured mouse glutamatergic neurons. ASN neuro 20120101
¹³C metabolic flux analysis identifies an unusual route for pyruvate dissimilation in mycobacteria which requires isocitrate lyase and carbon dioxide fixation. PLoS pathogens 20110701
Excretion of 2,3-dihydroxy-propionamide (OH-PA), the hydrolysis product of glycidamide, in human urine after single oral dose of deuterium-labeled acrylamide. Archives of toxicology 20110601
A fully validated method for the determination of vardenafil in blood using gas chromatography/mass spectrometry. Journal of mass spectrometry : JMS 20110101
Effect of iclR and arcA knockouts on biomass formation and metabolic fluxes in Escherichia coli K12 and its implications on understanding the metabolism of Escherichia coli BL21 (DE3). BMC microbiology 20110101
Conformationally constrained histidines in the design of peptidomimetics: strategies for the χ-space control. International journal of molecular sciences 20110101
A comprehensive metabolic profile of cultured astrocytes using isotopic transient metabolic flux analysis and C-labeled glucose. Frontiers in neuroenergetics 20110101
Synthesis and structure-activity relationship of 3-O-acylated (-)-epigallocatechins as 5α-reductase inhibitors. European journal of medicinal chemistry 20101201
A practical Delta 1-dehydrogenation of Delta 4-3-keto-steroids with DDQ in the presence of TBDMSCl at room temperature. Steroids 20100701
A ratiometric fluorescent probe for fluoride ion employing the excited-state intramolecular proton transfer. Talanta 20091115
Development and validation of a gas chromatography/mass spectrometry method for the assessment of genomic DNA methylation. Rapid communications in mass spectrometry : RCM 20090901
Investigation of the synthetic route to pepstatin analogues by SPPS using O-protected and O-unprotected statine as building blocks. Journal of peptide science : an official publication of the European Peptide Society 20090401
Uric acid is a mediator of the Plasmodium falciparum-induced inflammatory response. PloS one 20090101
2-(Benzoyl-amino-meth-yl)pyridinium chloride. Acta crystallographica. Section E, Structure reports online 20081201
N-[3-(tert-Butyl-dimethyl-siloxymeth-yl)-5-nitro-phen-yl]acetamide. Acta crystallographica. Section E, Structure reports online 20081001
Solid phase microextraction procedure for the determination of alkylphenols in water by on-fiber derivatization with N-tert-butyl-dimethylsilyl-N-methyltrifluoroacetamide. Analytica chimica acta 20080829
N-methylation of the c3' amide of taxanes: synthesis of N-methyltaxol C and N-methylpaclitaxel. The Journal of organic chemistry 20080620
Novel fluorogenic probe for fluoride ion based on the fluoride-induced cleavage of tert-butyldimethylsilyl ether. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20070601
Derivatization of organophosphorus nerve agent degradation products for gas chromatography with ICPMS and TOF-MS detection. Analytical and bioanalytical chemistry 20070601
A fluorescein-based fluorogenic probe for fluoride ion based on the fluoride-induced cleavage of tert-butyldimethylsilyl ether. Journal of fluorescence 20070101
Regioselective and stereospecific amination of iridoids: conversion of aucubin into aminoside antibiotic analogues. Journal of natural products 20070101
Syntheses of 19-[O-(carboxymethyl)oxime] haptens of epipregnanolone and pregnanolone. Steroids 20060201
Synthesis of 6I-amino-6I-deoxy-2I-VII,3I-VII-tetradeca-O-methyl-cyclomaltoheptaose. Carbohydrate research 20040517
Synthesis of D-altritol nucleosides with a 3'-O-tert-butyldimethylsilyl protecting group. Nucleosides, nucleotides & nucleic acids 20040101
Analysis of O,S-dimethyl hydrogen phosphorothioate in urine, a specific biomarker for methamidophos. Journal of agricultural and food chemistry 20031008
Synthesis of 2'-O-substituted ribonucleosides. Nucleosides, nucleotides & nucleic acids 20030101
Identification of a novel family of nucleosides that specifically inhibit HIV-1 reverse transcriptase. Bioorganic & medicinal chemistry letters 20011203
Sorption of nonpolar aromatic contaminants by chlorosilane surface modified natural minerals. Environmental science & technology 20011101
Properties