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Rhodium

CAS No.:
7440-16-6
Catalog Number:
AG0035KF
Molecular Formula:
Rh
Molecular Weight:
102.9055
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
5g
5 wt% on Carbon
In Stock USA
United States
$193
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Product Description
Catalog Number:
AG0035KF
Chemical Name:
Rhodium
CAS Number:
7440-16-6
Molecular Formula:
Rh
Molecular Weight:
102.9055
MDL Number:
MFCD00011201
IUPAC Name:
rhodium
InChI:
InChI=1S/Rh
InChI Key:
MHOVAHRLVXNVSD-UHFFFAOYSA-N
SMILES:
[Rh]
EC Number:
231-125-0
UNII:
DMK383DSAC
UN Number:
3089
Properties
Complexity:
0
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
102.905g/mol
Formal Charge:
0
Heavy Atom Count:
1  
Hydrogen Bond Acceptor Count:
0
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
102.905g/mol
Monoisotopic Mass:
102.905g/mol
Rotatable Bond Count:
0
Topological Polar Surface Area:
0A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
Literature
Title Journal
Transition metal-α-amino acid complexes with antibiotic activity against Mycobacterium spp. Antimicrobial agents and chemotherapy 20130701
Synthesis and antiplasmodial evaluation of novel (4-aminobutyloxy)quinolines. Bioorganic & medicinal chemistry letters 20130101
Aqueous-phase hydroformylation of 1-octene using hydrophilic sulfonate salicylaldimine dendrimers. Dalton transactions (Cambridge, England : 2003) 20121207
Efficient synthesis of oxazoles by dirhodium(II)-catalyzed reactions of styryl diazoacetate with oximes. Chemical communications (Cambridge, England) 20121207
Rhodium(II) catalyzed diastereoselective reactions of diazoacetamides with isatins: an efficient approach to 3-hydroxy-3,3'-bioxindoles. Organic & biomolecular chemistry 20121128
Pyridine synthesis by reactions of allyl amines and alkynes proceeding through a Cu(OAc)2 oxidation and Rh(III)-catalyzed N-annulation sequence. Chemical communications (Cambridge, England) 20121128
A chelating tetrapeptide rhodium complex comprised of a histidylidene residue: biochemical tailoring of an NHC-Rh hydrosilylation catalyst. Chemical communications (Cambridge, England) 20121118
Novel C,N-chelate rhodium(III) and iridium(III) antitumor complexes incorporating a lipophilic steroidal conjugate and their interaction with DNA. Dalton transactions (Cambridge, England : 2003) 20121107
Dirhodium carboxylates catalyzed enantioselective coupling reactions of α-diazophosphonates, anilines, and electron-deficient aldehydes. Angewandte Chemie (International ed. in English) 20121105
Enantioselective synthesis of β-aryloxycarboxylic esters via asymmetric hydrogenation of β-aryloxy-α,β-unsaturated esters. Organic letters 20121102
Rh(I)-catalyzed Pauson-Khand-type cycloaddition reaction of ene-vinylidenecyclopropanes with carbon monoxide (CO). Organic letters 20121102
Chemistry. Lending handedness to the cyclopentadienyl ligand. Science (New York, N.Y.) 20121026
Biotinylated Rh(III) complexes in engineered streptavidin for accelerated asymmetric C-H activation. Science (New York, N.Y.) 20121026
Synthesis of enaminones by rhodium-catalyzed denitrogenative rearrangement of 1-(N-sulfonyl-1,2,3-triazol-4-yl)alkanols. Journal of the American Chemical Society 20121024
Rhodium-catalyzed ring opening of benzocyclobutenols with site-selectivity complementary to thermal ring opening. Journal of the American Chemical Society 20121024
Modular construction of a porous organometallic network based on rhodium olefin complexation. Journal of the American Chemical Society 20121024
Synthesis of phenol derivatives from cyclohex-2-enones bearing an alkyne through Lewis acid-catalyzed enolization and intramolecular Alder-Rickert reaction. The Journal of organic chemistry 20121019
Rhodium-catalyzed synthesis of diaryl sulfides using aryl fluorides and sulfur/organopolysulfides. Organic letters 20121019
Chemo- and enantioselective Rh-catalysed hydrogenation of 3-methylene-1,2-diazetidines: application to vicinal diamine synthesis. Chemical communications (Cambridge, England) 20121011
A rhodium complex-linked β-barrel protein as a hybrid biocatalyst for phenylacetylene polymerization. Chemical communications (Cambridge, England) 20121009
Rhodium-catalyzed cross-aldol reaction: in situ aldehyde-enolate formation from allyloxyboranes and primary allylic alcohols. Angewandte Chemie (International ed. in English) 20121008
Abnormal oxazol-4-ylidene and thiazol-4-ylidene rhodium complexes: synthesis, structure, and properties. Chemical communications (Cambridge, England) 20121007
Development and testing of a compact basis set for use in effective core potential calculations on rhodium complexes. Journal of computational chemistry 20121005
Determination of orientational isomerism in rhodium(II) metallopeptides by pyrene fluorescence. Organic & biomolecular chemistry 20121003
Synthesis and resolution of the biaryl-like diphosphine (S)-Me2-CATPHOS, preparation of a derived rhodium precatalyst and applications in asymmetric hydrogenation. Nature protocols 20121001
Mechanistic study of a one-step catalytic conversion of fructose to 2,5-dimethyltetrahydrofuran. Chemistry (Weinheim an der Bergstrasse, Germany) 20120924
Rhodium-catalyzed direct C-H amination of benzamides with aryl azides: a synthetic route to diarylamines. Angewandte Chemie (International ed. in English) 20120924
Reductive cleavage of the Csp2-Csp3 bond of secondary benzyl alcohols: rhodium catalysis directed by N-containing groups. Angewandte Chemie (International ed. in English) 20120924
Rhodium-catalyzed [2 + 2] cycloaddition of ynamides with nitroalkenes. Organic letters 20120921
Scope and mechanistic analysis of the enantioselective synthesis of allenes by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and propargylic alcohols. Journal of the American Chemical Society 20120919
Catalytic mechanism in artificial metalloenzyme: QM/MM study of phenylacetylene polymerization by rhodium complex encapsulated in apo-Ferritin. Journal of the American Chemical Society 20120919
Hydrodefluorination and hydrogenation of fluorobenzene under mild aqueous conditions. Environmental science & technology 20120918
Investigations into the formation and stability of cationic rhodium diphosphane η6-arene complexes. Chemistry (Weinheim an der Bergstrasse, Germany) 20120917
Rhodium-phosphoramidite catalyzed alkene hydroacylation: mechanism and octaketide natural product synthesis. Journal of the American Chemical Society 20120912
Organic carbonates as stabilizing solvents for transition-metal nanoparticles. Dalton transactions (Cambridge, England : 2003) 20120828
Screening rhodium metallopeptide libraries 'on bead': asymmetric cyclopropanation and a solution to the enantiomer problem. Angewandte Chemie (International ed. in English) 20120820
Stereoselective intermolecular C-H amination reactions. Chemical communications (Cambridge, England) 20120814
Selective rhodium(III)-catalyzed cross-dehydrogenative coupling of furan and thiophene derivatives. Angewandte Chemie (International ed. in English) 20120813
Enantioselective rhodium-catalyzed nucleophilic allylation of cyclic imines with allylboron reagents. Angewandte Chemie (International ed. in English) 20120813
Stereospecific synthesis and catalytic activity of L-histidylidene metal complexes. Dalton transactions (Cambridge, England : 2003) 20120807
New tetraphosphorus ligands for highly linear selective hydroformylation of allyl and vinyl derivatives. Chemistry (Weinheim an der Bergstrasse, Germany) 20120806
Sequence-specific inhibition of a designed metallopeptide catalyst. Chemical communications (Cambridge, England) 20120804
Rhodium-catalyzed carbonylation of cyclopropyl substituted propargyl esters: a tandem 1,3-acyloxy migration [5 + 1] cycloaddition. The Journal of organic chemistry 20120803
Regioselective Rh(I)-catalyzed sequential hydrosilylation toward the assembly of silicon-based peptidomimetic analogues. The Journal of organic chemistry 20120720
Diastereoselective [4 + 1] cycloaddition of alkenyl propargyl acetates with CO catalyzed by [RhCl(CO)2]2. The Journal of organic chemistry 20120720
Synthesis of aza-fused polycyclic quinolines via double C-H bond activation. Chemistry (Weinheim an der Bergstrasse, Germany) 20120716
C sp 3-H bond activation triggered by formation of metallacycles: rhodium(I)-catalyzed cyclopropanation/cyclization of allenynes. Angewandte Chemie (International ed. in English) 20120716
Rhodium-catalyzed intramolecular formation of N-sulfamoyl 2,3-aziridino-γ-lactones and their use for the enantiospecific synthesis of α,β-diamino acid derivatives. The Journal of organic chemistry 20120706
Rh-catalyzed intermolecular reactions of cyclic α-diazocarbonyl compounds with selectivity over tertiary C-H bond migration. Journal of the American Chemical Society 20120704
Highly stereoselective C-C bond formation by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and chiral allylic alcohols. Journal of the American Chemical Society 20120704
Modular functionalization of allenes to aminated stereotriads. Journal of the American Chemical Society 20120704
Oxygen reduction reactions of monometallic rhodium hydride complexes. Inorganic chemistry 20120702
Interaction between water-soluble rhodium complex RhCl(CO)(TPPTS)₂ and surfactants probed by spectroscopic methods. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20120701
The chemoselective reactions of tyrosine-containing G-protein-coupled receptor peptides with [Cp*Rh(H2O)3](OTf)2, including 2D NMR structures and the biological consequences. Journal of the American Chemical Society 20120627
Conformational, steric and electronic effects on the site- and chemoselectivity of the metal-catalyzed reaction of N-bis(trimethylsilyl)methyl, N-(2-indolyl)methyl α-diazoamides. Organic & biomolecular chemistry 20120621
Catalytic protein modification with dirhodium metallopeptides: specificity in designed and natural systems. Journal of the American Chemical Society 20120620
The combined C-H functionalization/Cope rearrangement: discovery and applications in organic synthesis. Accounts of chemical research 20120619
Stereoselective synthesis of norephedrine and norpseudoephedrine by using asymmetric transfer hydrogenation accompanied by dynamic kinetic resolution. The Journal of organic chemistry 20120615
Convenient method for the functionalization of the 4- and 6-positions of the androgen skeleton. Chemical communications (Cambridge, England) 20120614
Highly regio- and stereoselective dirhodium vinylcarbene induced nitrone cycloaddition with subsequent cascade carbenoid aromatic cycloaddition/N-O cleavage and rearrangement. Angewandte Chemie (International ed. in English) 20120611
Rh(II)2-catalyzed synthesis of α-, β-, or δ-carbolines from aryl azides. Angewandte Chemie (International ed. in English) 20120611
Kinetic and geometric isotope effects originating from different adsorption potential energy surfaces: cyclohexane on Rh(111). The Journal of chemical physics 20120607
Self-assembled hexanuclear organometallic cages: synthesis, characterization, and host-guest properties. Chemistry, an Asian journal 20120601
Kinetics of the oxidation of lactose by copper(II) complexed with bipyridyl in alkaline medium using chloro-complex of rhodium(III) in its nano-concentration range as homogeneous catalyst: a spectrophotometric study. Carbohydrate research 20120601
Preparation of chiral 3-arylpyrrolidines via the enantioselective 1,4-addition of arylboronic acids to fumaric esters catalyzed by Rh(I)/chiral diene complexes. Organic letters 20120601
Ligand-controlled regioselectivity in the hydrothiolation of alkynes by rhodium N-heterocyclic carbene catalysts. Journal of the American Chemical Society 20120516
Halogen oxidation and halogen photoelimination chemistry of a platinum-rhodium heterobimetallic core. Inorganic chemistry 20120507
Rhodium-catalyzed synthesis of branched amines by direct addition of benzamides to imines. Organic letters 20120504
Rh2(II)-catalyzed intramolecular aliphatic C-H bond amination reactions using aryl azides as the N-atom source. Journal of the American Chemical Society 20120502
Formal synthesis of (-)-englerin A and cytotoxicity studies of truncated englerins. Chemistry, an Asian journal 20120501
In-vitro assessment of oxidative stress generated by orthodontic archwires. American journal of orthodontics and dentofacial orthopedics : official publication of the American Association of Orthodontists, its constituent societies, and the American Board of Orthodontics 20120501
Computational study of the adsorption and dissociation of phenol on Pt and Rh surfaces. Physical chemistry chemical physics : PCCP 20120428
Rhodium/copper-catalyzed annulation of benzimides with internal alkynes: indenone synthesis through sequential C-H and C-N cleavage. Angewandte Chemie (International ed. in English) 20120416
Total syntheses of the elusive welwitindolinones with bicyclo[4.3.1] cores. Angewandte Chemie (International ed. in English) 20120416
Reduction of nitrous acid with a macrocyclic rhodium complex that acts as a functional model of nitrite reductase. Inorganic chemistry 20120416
Competitive [2,3]- and [1,2]-oxonium ylide rearrangements. Concerted or stepwise? Organic letters 20120406
Cellular impact and selectivity of half-sandwich organorhodium(III) anticancer complexes and their organoiridium(III) and trichloridorhodium(III) counterparts. Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20120401
Rh-catalyzed intramolecular sp2 C-H bond difluoromethylenation. Chemical communications (Cambridge, England) 20120325
Rh(I)-catalyzed asymmetric synthesis of 3-substituted isoindolinones through CO gas-free aminocarbonylation. The Journal of organic chemistry 20120316
Total synthesis of (-)-anisatin. Organic letters 20120316
Rhodium-catalyzed carbonylation of 3-acyloxy-1,4-enynes for the synthesis of cyclopentenones. Organic letters 20120316
Total synthesis of (-)-kaitocephalin based on a Rh-catalyzed C-H amination. Organic letters 20120316
Extrusion of CO from aryl ketones: rhodium(I)-catalyzed C-C bond cleavage directed by a pyridine group. Angewandte Chemie (International ed. in English) 20120312
Total synthesis of (+)-asteriscanolide: further exploration of the rhodium(I)-catalyzed [(5+2)+1] reaction of ene-vinylcyclopropanes and CO. Chemistry, an Asian journal 20120305
Synthesis of pyridines from ketoximes and terminal alkynes via C-H bond functionalization. The Journal of organic chemistry 20120302
Mechanism of intermolecular hydroacylation of vinylsilanes catalyzed by a rhodium(I) olefin complex: a DFT study. Journal of molecular modeling 20120301
In vitro oxidative stress induced by conventional and self-ligating brackets. The Angle orthodontist 20120301
Theoretical investigations on electronic spectra and the redox-switchable second-order nonlinear optical responses of rhodium(I)-9,10-phenanthrenediimine complexes. Journal of molecular graphics & modelling 20120301
[RhIIICp*]-catalyzed dehydrogenative aryl-aryl bond formation. Angewandte Chemie (International ed. in English) 20120227
Regioselective synthesis of 1,2-dihydropyridines by rhodium-catalyzed hydroboration of pyridines. Journal of the American Chemical Society 20120227
Diastereoselective rhodium-catalyzed ene-cycloisomerization reactions of alkenylidenecyclopropanes: total synthesis of (-)-α-kainic acid. Journal of the American Chemical Society 20120227
Chemoenzymatic synthesis of a mixed phosphine-phosphine oxide catalyst and its application to asymmetric allylation of aldehydes and hydrogenation of alkenes. Organic & biomolecular chemistry 20120221
Rhodium-catalyzed 1,3-acyloxy migration and subsequent intramolecular [4+2] cycloaddition of vinylallene and unactivated alkyne. Chemical communications (Cambridge, England) 20120221
Rhodium-catalyzed and zinc(II)-triflate-promoted asymmetric hydrogenation of tetrasubstituted α,β-unsaturated ketones. Organic letters 20120217
Reaction pathways of Rh+ (3F and 1D) with CH3OCH3 in the gas phase. Rapid communications in mass spectrometry : RCM 20120215
Aryl methyl sulfides as substrates for rhodium-catalyzed alkyne carbothiolation: arene functionalization with activating group recycling. Journal of the American Chemical Society 20120215
Cooperative ligand effects in phase-switching homogeneous catalysts. Angewandte Chemie (International ed. in English) 20120213
Tandem Rh(III)-catalyzed oxidative acylation of secondary benzamides with aldehydes and intramolecular cyclization: the direct synthesis of 3-hydroxyisoindolin-1-ones. Organic letters 20120203
Rhodium-catalyzed xanthone formation from 2-aryloxybenzaldehydes via cross-dehydrogenative coupling (CDC). Organic letters 20120203
Rhodium-catalyzed cleavage reaction of aryl methyl ethers with thioesters. Organic letters 20120203
Rhodium-catalyzed redox allylation reactions of ketones. Chemical communications (Cambridge, England) 20120201
Oxidative amidation of aromatic ethers catalyzed by rhodium acetate. Chemistry (Weinheim an der Bergstrasse, Germany) 20120123
The role of three-center/four-electron bonds in superelectrophilic dirhodium carbene and nitrene catalytic intermediates. Dalton transactions (Cambridge, England : 2003) 20120121
N-Directing group assisted rhodium-catalyzed aryl C-H addition to aryl aldehydes. Organic letters 20120120
Asymmetric Rh(I)-catalyzed intramolecular [3 + 2] cycloaddition of 1-yne-vinylcyclopropanes for bicyclo[3.3.0] compounds with a chiral quaternary carbon stereocenter and density functional theory study of the origins of enantioselectivity. Journal of the American Chemical Society 20120111
Chiral ammonium-capped rhodium(0) nanocatalysts: synthesis, characterization, and advances in asymmetric hydrogenation in neat water. ChemSusChem 20120109
Highly regioselective isomerization-hydroaminomethylation of internal olefins catalyzed by Rh complex with Tetrabi-type phosphorus ligands. Organic letters 20120106
One-pot synthesis of isoquinolinium salts by rhodium-catalyzed C-H bond activation: application to the total synthesis of oxychelerythrine. Angewandte Chemie (International ed. in English) 20120102
Enhanced Pd pillared clays by Rh inclusion for the catalytic hydrodechlorination of chlorophenols in water. Water science and technology : a journal of the International Association on Water Pollution Research 20120101
Degradation of azo dye with dirhodium(II) caprolactamate as heterogeneous catalyst. Water science and technology : a journal of the International Association on Water Pollution Research 20120101
Potential of gold nanoparticles for oxidation in fine chemical synthesis. Annual review of chemical and biomolecular engineering 20120101
Stripping voltammetric determination of palladium, platinum and rhodium in freshwater and sediment samples from South African water resources. Journal of environmental science and health. Part A, Toxic/hazardous substances & environmental engineering 20120101
Selective cytotoxicity of rhodium metalloinsertors in mismatch repair-deficient cells. Biochemistry 20111220
Total synthesis of (-)-virginiamycin M2: application of crotylsilanes accessed by enantioselective Rh(II) or Cu(I) promoted carbenoid Si-H insertion. The Journal of organic chemistry 20111216
Highly regioselective hydroaminomethylation of terminal olefins to linear amines using Rh complexes with a Tetrabi phosphorus ligand. Chemistry (Weinheim an der Bergstrasse, Germany) 20111216
Total synthesis of sialic acid by a sequential rhodium-catalyzed aziridination and Barbier allylation of D-glycal. Angewandte Chemie (International ed. in English) 20111209
Stitching phospholanes together piece by piece: new modular di- and tridentate stereodirecting ligands. Chemistry (Weinheim an der Bergstrasse, Germany) 20111209
Unravelling the mechanism of glycerol hydrogenolysis over rhodium catalyst through combined experimental-theoretical investigations. Chemistry (Weinheim an der Bergstrasse, Germany) 20111209
Insight into the photoinduced ligand exchange reaction pathway of cis-[Rh2(μ-O2CCH3)2(CH3CN)6]2+ with a DNA model chelate. Inorganic chemistry 20111205
Quantitative trace analysis of benzene using an array of plasma-treated metal-decorated carbon nanotubes and fuzzy adaptive resonant theory techniques. Analytica chimica acta 20111205
D2-symmetric dirhodium catalyst derived from a 1,2,2-triarylcyclopropanecarboxylate ligand: design, synthesis and application. Journal of the American Chemical Society 20111130
Selective hydroformylation-hydrogenation tandem reaction of isoprene to 3-methylpentanal. Dalton transactions (Cambridge, England : 2003) 20111128
Rhodium(III)-catalyzed oxidative carbonylation of benzamides with carbon monoxide. Chemical communications (Cambridge, England) 20111128
Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp(t) provide complementary selectivity. Chemical communications (Cambridge, England) 20111121
Synthesis of isochromene and related derivatives by rhodium-catalyzed oxidative coupling of benzyl and allyl alcohols with alkynes. The Journal of organic chemistry 20111118
Chiral allene-containing phosphines in asymmetric catalysis. Journal of the American Chemical Society 20111116
Mechanistic studies of O2 reduction effected by group 9 bimetallic hydride complexes. Journal of the American Chemical Society 20111109
Unravelling the reaction path of rhodium-MonoPhos-catalysed olefin hydrogenation. Chemistry (Weinheim an der Bergstrasse, Germany) 20111104
Rhodium-catalyzed annulation of N-benzoylsulfonamide with isocyanide through C-H activation. Chemistry (Weinheim an der Bergstrasse, Germany) 20111104
A general synthesis of dirhodium metallopeptides as MDM2 ligands. Chemical communications (Cambridge, England) 20111021
Stereoselective rhodium-catalyzed amination of alkenes. Organic letters 20111021
Zinc-catalyzed allenylations of aldehydes and ketones. Organic letters 20111021
Synthesis of α,α-disubstituted aryl amines by rhodium-catalyzed amination of tertiary allylic trichloroacetimidates. Organic letters 20111021
Asymmeric formal [3 + 3]-cycloaddition reactions of nitrones with electrophilic vinylcarbene intermediates. Journal of the American Chemical Society 20111019
Mesoionic thiazol-5-ylidenes as ligands for transition metal complexes. Chemical communications (Cambridge, England) 20111014
Optimizing dirhodium(II) tetrakiscarboxylates as chiral NMR auxiliaries. Organic & biomolecular chemistry 20111007
Rhodium-catalyzed cross-coupling reaction of arylboronates and diazoesters and tandem alkylation reaction for the synthesis of quaternary α,α-heterodiaryl carboxylic esters. Organic letters 20111007
Addition of arylboronic acids to arylpropargyl alcohols en route to indenes and quinolines. Organic letters 20111007
Sensitive and selective chromogenic sensing of carbon monoxide via reversible axial CO coordination in binuclear rhodium complexes. Journal of the American Chemical Society 20111005
Highly enantioselective rhodium-catalyzed asymmetric 1,4-addition reactions of arylboronic acids to acyclic α,β-unsaturated compounds: the formal synthesis of (-)-indatraline. Chemistry (Weinheim an der Bergstrasse, Germany) 20111004
Synthesis of indolizidines from optically pure α-amino acids via stereocontrolled rhodium-catalyzed hydroformylation of N-allylpyrroles. Chirality 20111001
Reactivity of N-(1,2,4-triazolyl)-substituted 1,2,3-triazoles. Organic letters 20110916
Rhodium-catalyzed olefin isomerization/enantioselective intramolecular Alder-ene reaction cascade. Organic letters 20110916
Rearrangement of 2-aryloxybenzaldehydes to 2-hydroxybenzophenones by rhodium-catalyzed cleavage of aryloxy C-O bonds. Angewandte Chemie (International ed. in English) 20110912
Bis(metallo) capsules based on two ionic diphosphines. Chemistry, an Asian journal 20110905
Synthesis of 1-aminoisoquinolines via Rh(III)-catalyzed oxidative coupling. Organic letters 20110902
Computational prediction of selectivities in nonreversible and reversible hydroformylation reactions catalyzed by unmodified rhodium-carbonyls. Journal of molecular modeling 20110901
Application of a new amidophosphite ligand to Rh-catalyzed asymmetric hydrogenation of β-dehydroamino acid derivatives in supercritical carbon dioxide: activation effect of protic Co-solvents. Chirality 20110901
New investigations of technical rhodium and iridium catalysts in homogeneous phase employing para-hydrogen induced polarization. Solid state nuclear magnetic resonance 20110901
Interception of a Rautenstrauch intermediate by alkynes for [5+2] cycloaddition: rhodium-catalyzed cycloisomerization of 3-acyloxy-4-ene-1,9-diynes to bicyclo[5.3.0]decatrienes. Angewandte Chemie (International ed. in English) 20110822
Synthesis of the anti-HIV agent (-)-hyperolactone C by using oxonium ylide formation-rearrangement. Chemistry (Weinheim an der Bergstrasse, Germany) 20110822
Theoretical studies on the mechanism and stereoselectivity of Rh(Phebox)-catalyzed asymmetric reductive aldol reaction. Organic & biomolecular chemistry 20110821
Room-temperature Rh-catalyzed asymmetric 1,4-addition of arylboronic acids to maleimides and enones in the presence of CF3-substituted MeOBIPHEP analogues. The Journal of organic chemistry 20110819
Rhodium-catalyzed oxidative ortho-acylation of benzamides with aldehydes: direct functionalization of the sp2 C-H bond. Organic letters 20110819
Highly enantioselective arylation of N-tosylalkylaldimines catalyzed by rhodium-diene complexes. Journal of the American Chemical Society 20110817
Combined C-H functionalization/Cope rearrangement with vinyl ethers as a surrogate for the vinylogous Mukaiyama aldol reaction. Journal of the American Chemical Society 20110810
Chiral sulfoxide-olefin ligands: completely switchable stereoselectivity in rhodium-catalyzed asymmetric conjugate additions. Angewandte Chemie (International ed. in English) 20110808
Hydroboration of an alkene by amine-boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation. Dalton transactions (Cambridge, England : 2003) 20110807
Synthesis of azaheterocycles from aryl ketone O-acetyl oximes and internal alkynes by Cu-Rh bimetallic relay catalysts. The Journal of organic chemistry 20110805
Expedient synthesis of N-acyl anthranilamides and β-enamine amides by the Rh(III)-catalyzed amidation of aryl and vinyl C-H bonds with isocyanates. Journal of the American Chemical Society 20110803
Antileukemic activity and cellular effects of rhodium(III) crown thiaether complexes. Biometals : an international journal on the role of metal ions in biology, biochemistry, and medicine 20110801
Factors affecting the electrochemical regeneration of NADH by (2,2'-bipyridyl) (pentamethylcyclopentadienyl)-rhodium complexes: impact on their immobilization onto electrode surfaces. Bioelectrochemistry (Amsterdam, Netherlands) 20110801
Macrocyclization of oxetane building blocks with diazocarbonyl derivatives under rhodium(II) catalysis. Angewandte Chemie (International ed. in English) 20110801
Profiling the tuneable R-SMS-Phos structure in the rhodium(I)-catalyzed hydrogenation of olefins: the last stand? Organic & biomolecular chemistry 20110721
Control of selectivity in the generation and reactions of oxonium ylides. Chemical communications (Cambridge, England) 20110721
Highly enantioselective cyclopropenation reaction of 1-alkynes with α-alkyl-α-diazoesters catalyzed by dirhodium(II) carboxylates. Angewandte Chemie (International ed. in English) 20110718
Hydride mobility in trinuclear sulfido clusters with the core [Rh3(μ-H)(μ3-S)2]: molecular models for hydrogen migration on metal sulfide hydrotreating catalysts. Chemistry (Weinheim an der Bergstrasse, Germany) 20110711
Highly cytotoxic substitutionally inert rhodium(III) tris(chelate) complexes: DNA binding modes and biological impact on human cancer cells. Journal of inorganic biochemistry 20110701
The development of Laue techniques for single-pulse diffraction of chemical complexes: time-resolved Laue diffraction on a binuclear rhodium metal-organic complex. Acta crystallographica. Section A, Foundations of crystallography 20110701
Enantioselective addition of allyltin reagents to amino aldehydes catalyzed with bis(oxazolinyl)phenylrhodium(III) aqua complexes. Molecules (Basel, Switzerland) 20110627
Solvent enhancement of reaction selectivity: a unique property of cationic chiral dirhodium carboxamidates. Journal of the American Chemical Society 20110622
Synthesis of β- and γ-carbolines via ruthenium and rhodium catalysed [2+2+2] cycloadditions of yne-ynamides with methylcyanoformate. Chemical communications (Cambridge, England) 20110621
Asymmetric Rh(II)-catalyzed cyclopropanation of alkenes with diacceptor diazo compounds: p-methoxyphenyl ketone as a general stereoselectivity controlling group. Journal of the American Chemical Society 20110615
Relationship between electrochemical potentials and substitution reaction rates of ferrocene-containing β-diketonato rhodium(I) complexes; cytotoxicity of [Rh(FcCOCHCOPh)(cod)]. Dalton transactions (Cambridge, England : 2003) 20110614
Diastereoselectively switchable enantioselective trapping of carbamate ammonium ylides with imines. Journal of the American Chemical Society 20110608
Rhodium-catalyzed decarboxylative cycloaddition route to substituted anilines. The Journal of organic chemistry 20110603
Burkavidin: a novel secreted biotin-binding protein from the human pathogen Burkholderia pseudomallei. Protein expression and purification 20110601
Adamantanes as spherical nanosondes in adducts with a chiral dirhodium complex-discriminating enantiomers and probing spatial proximities. Magnetic resonance in chemistry : MRC 20110601
Enantioselective total synthesis of aperidine. Organic letters 20110520
Rhodium-catalyzed selective olefination of arene esters via C-H bond activation. Organic letters 20110506
Rhodium-catalyzed highly enantioselective addition of arylboronic acids to 2-nitrostyrenes by tert-butanesulfinylphosphine ligand. Chemistry (Weinheim an der Bergstrasse, Germany) 20110502
Immobilization of urease on nanostructured polymer membrane and preparation of urea amperometric biosensor. International journal of biological macromolecules 20110501
Preparation, characterization and pH-metric measurements of 4-hydroxysalicylidenechitosan Schiff-base complexes of Fe(III), Co(II), Ni(II), Cu(II), Zn(II), Ru(III), Rh(III), Pd(II) and Au(III). Carbohydrate research 20110501
Metalloradical-catalyzed rearrangement of cycloheptatrienyl to benzyl. Chemical communications (Cambridge, England) 20110428
Selectivity manipulation of bicyclization reactions of 1,5-bis(1,2-allenylketone)s: Pd versus Rh and electronic effect. Chemistry (Weinheim an der Bergstrasse, Germany) 20110426
Regioselective synthesis of indenols by rhodium-catalyzed C-H activation and carbocyclization of aryl ketones and alkynes. Angewandte Chemie (International ed. in English) 20110426
Interconversion between formic acid and H(2)/CO(2) using rhodium and ruthenium catalysts for CO(2) fixation and H(2) storage. ChemSusChem 20110418
Hydrogen and methanol exchange processes for (TMP)Rh-OCH3(CH3OH) in binary solutions of methanol and benzene. Inorganic chemistry 20110418
Isolation, characterization, and DNA binding kinetics of three dirhodium(II,II) carboxyamidate complexes: Rh2(μ-L)(HNOCCF3)3 where L= [OOCCH3]-, [OOCCF3]-, or [HNOCCF3]-. Inorganic chemistry 20110418
High turnover in a photocatalytic system for water reduction to produce hydrogen using a Ru,  Rh,  Ru photoinitiated electron collector. ChemSusChem 20110418
Development of amperometric α-ketoglutarate biosensor based on ruthenium-rhodium modified carbon fiber enzyme microelectrode. Biosensors & bioelectronics 20110415
Dirhodium-catalyzed phenol and aniline oxidations with T-HYDRO. Substrate scope and mechanism of oxidation. The Journal of organic chemistry 20110415
Highly cis-selective Rh(I)-catalyzed cyclopropanation reactions. The Journal of organic chemistry 20110415
Highly enantioselective and efficient synthesis of flavanones including pinostrobin through the rhodium-catalyzed asymmetric 1,4-addition. Organic letters 20110415
Sequential aldol condensation-transition metal-catalyzed addition reactions of aldehydes, methyl ketones, and arylboronic acids. Organic letters 20110415
Zeolite-supported rhodium complexes and clusters: switching catalytic selectivity by controlling structures of essentially molecular species. Journal of the American Chemical Society 20110406
Rh2(II)-catalyzed nitro-group migration reactions: selective synthesis of 3-nitroindoles from β-nitro styryl azides. Journal of the American Chemical Society 20110406
Conformational studies on chiral rhodium complexes by ECD and VCD spectroscopy. Chirality 20110401
o-Semiquinonato and o-iminosemiquinonato rhodium complexes. EPR study of the reactions in coordination sphere of rhodium. Journal of magnetic resonance (San Diego, Calif. : 1997) 20110401
Rhodium(II) acetate-catalyzed stereoselective synthesis, SAR and anti-HIV activity of novel oxindoles bearing cyclopropane ring. European journal of medicinal chemistry 20110401
The coupling of arylboronic acids with nitroarenes catalyzed by rhodium. Organic letters 20110401
Dihydropyranone formation by ipso C-H activation in a glucal 3-carbamate-derived rhodium acyl nitrenoid. The Journal of organic chemistry 20110401
Mechanism and origins of regio- and enantioselectivities in RhI-catalyzed hydrogenative couplings of 1,3-diynes and activated carbonyl partners: intervention of a cumulene intermediate. Chemistry (Weinheim an der Bergstrasse, Germany) 20110328
Kinetico-mechanistic studies of the acidolysis of Rh-C bonds in monocyclometallated dirhodium(II) acetato complexes; influence of electronic and steric effects. Dalton transactions (Cambridge, England : 2003) 20110321
Study of the conformationally flexible, wide bite-angle diphosphine 4,6-bis(3-diisopropylphosphinophenyl)dibenzofuran in rhodium(I) and palladium(II) coordination complexes. Inorganic chemistry 20110321
Synthesis of the cytotrienin A core via metal catalyzed C-C coupling. Organic letters 20110318
Aliphatic C-H to C-C conversion: synthesis of (-)-cameroonan-7α-ol. The Journal of organic chemistry 20110318
Rhodium-catalyzed enantioselective addition of boronic acids to N-benzylnicotinate salts. Journal of the American Chemical Society 20110309
Cellular selectivity and biological impact of cytotoxic rhodium(III) and iridium(III) complexes containing methyl-substituted phenanthroline ligands. ChemMedChem 20110307
Catalytic thia-Sommelet-Hauser rearrangement: application to the synthesis of oxindoles. Organic letters 20110304
Stereocontrolled synthesis of (+)-methoxyphenylkainic acid and (+)-phenylkainic acid. Organic letters 20110304
O-substituted alkyl aldehydes for rhodium-catalyzed intermolecular alkyne hydroacylation: the utility of methylthiomethyl ethers. Organic letters 20110304
Rh(III)-catalyzed directed C-H olefination using an oxidizing directing group: mild, efficient, and versatile. Journal of the American Chemical Society 20110302
Redox-neutral atom-economic rhodium-catalyzed coupling of terminal alkynes with carboxylic acids toward branched allylic esters. Journal of the American Chemical Society 20110302
Rhodium-catalyzed 1,4-addition of lithium 2-furyltriolborates to unsaturated ketones and esters for enantioselective synthesis of γ-oxo-carboxylic acids by oxidation of the furyl ring with ozone. Chemistry, an Asian journal 20110301
Diverse strategies toward indenol and fulvene derivatives: Rh-catalyzed C-H activation of aryl ketones followed by coupling with internal alkynes. Journal of the American Chemical Society 20110223
C-H activation of 2,4,6-triphenylphosphinine: unprecedented formation of cyclometalated [(P^C)Ir(III)] and [(P^C)Rh(III)] complexes. Chemical communications (Cambridge, England) 20110221
Asymmetric synthesis of β-substituted γ-lactams via rhodium/diene-catalyzed 1,4-additions: application to the synthesis of (R)-baclofen and (R)-rolipram. Organic letters 20110218
Rhodium-catalyzed synthesis of 2,3-disubstituted indoles from β,β-disubstituted stryryl azides. Angewandte Chemie (International ed. in English) 20110211
Exploring a reaction mechanism for acetato ligand replacement in paddlewheel tetrakisacetatodirhodium (II,II) complex by ammonia: computational density functional theory study. The journal of physical chemistry. A 20110210
Rhodium(III)-catalyzed arylation of Boc-imines via C-H bond functionalization. Journal of the American Chemical Society 20110209
The vinyl moiety as a handle for regiocontrol in the preparation of unsymmetrical 2,3-aliphatic-substituted indoles and pyrroles. Angewandte Chemie (International ed. in English) 20110207
Synthesis of highly functionalized cyclohexenone rings: rhodium-catalyzed 1,3-acyloxy migration and subsequent [5+1] cycloaddition. Angewandte Chemie (International ed. in English) 20110207
Telomestatin: formal total synthesis and cation-mediated interaction of its seco-derivatives with G-quadruplexes. Journal of the American Chemical Society 20110202
Asymmetric transfer hydrogenation of prochiral ketones in aqueous media with chiral water-soluble and heterogenized bifunctional catalysts of the RhCp*-type ligand. Chirality 20110201
Ionic liquid ultrasound assisted dispersive liquid-liquid microextraction method for preconcentration of trace amounts of rhodium prior to flame atomic absorption spectrometry determination. Journal of hazardous materials 20110130
Stereoselective coordination of C5-symmetric corannulene derivatives with an enantiomerically pure [Rh(I)(nbd*)] metal complex. Angewandte Chemie (International ed. in English) 20110124
Artificial metalloenzymes based on the biotin-avidin technology: enantioselective catalysis and beyond. Accounts of chemical research 20110118
Photocatalytic production of hydrogen by disproportionation of one-electron-reduced rhodium and iridium-ruthenium complexes in water. Angewandte Chemie (International ed. in English) 20110117
Cooperative catalysis in highly enantioselective Mannich-type three-component reaction of a diazoacetophenone with an alcohol and an imine. Chemical communications (Cambridge, England) 20110114
Rh-catalyzed [7 + 1] cycloaddition of buta-1,3-dienylcyclopropanes and CO for the synthesis of cyclooctadienones. Organic letters 20110107
Design and synthesis of α-carboxy phosphononucleosides. The Journal of organic chemistry 20110107
Synthetic and mechanistic pathways of cis and trans-hydroxytamoxifen drug derivatives reacting with Cp*Rh complexes that involve η1-N, η2-N,O, η1-O, and η6 bonding modes, via a novel N-π rearrangement; relative binding affinities and computer docking studies of cis and trans-η6-Cp*Rh-hydroxytamoxifen complexes at the estrogen, ERα and ERβ receptors, and growth inhibition to breast cancer cells. Inorganic chemistry 20110103
Tetradentate bis-phosphine ligands (P(2)N(2) and P(2)S(2)) and their Rh(III), Ni(II) and (105)Rh complexes: X-ray crystal structures of trans-[RhCl(2)(L2)]PF(6), [Ni(L2)](PF(6))(2) and μ-O(2)SO(2)-[Ni(L5)](2)(PF(6))(2). Nuclear medicine and biology 20110101
Free Rhodium (II) citrate and rhodium (II) citrate magnetic carriers as potential strategies for breast cancer therapy. Journal of nanobiotechnology 20110101
Chirality responsive helical poly(phenylacetylene) bearing L-proline pendants. Chirality 20110101
Highly selective rhodium catalyzed domino C-H activation/cyclizations. Chimia 20110101
Rhodium(III)-catalyzed arene and alkene C-H bond functionalization leading to indoles and pyrroles. Journal of the American Chemical Society 20101229
C2-symmetric chiral disulfoxide ligands in rhodium-catalyzed 1,4-addition: from ligand synthesis to the enantioselection pathway. Chemistry (Weinheim an der Bergstrasse, Germany) 20101227
Comparing the enantioselective power of steric and electrostatic effects in transition-metal-catalyzed asymmetric synthesis. Chemistry (Weinheim an der Bergstrasse, Germany) 20101227
Mechanistically driven development of iridium catalysts for asymmetric allylic substitution. Accounts of chemical research 20101221
Concise synthesis of the Erythrina alkaloid 3-demethoxyerythratidinone via combined rhodium catalysis. Organic letters 20101217
Design and synthesis of cyclic sulfonamides and sulfamates as new calcium sensing receptor agonists. Bioorganic & medicinal chemistry letters 20101215
Design and synthesis of a novel three-hindered quadrant bisphosphine ligand and its application in asymmetric hydrogenation. Chemical communications (Cambridge, England) 20101207
Solid-state (15)N CPMAS NMR and computational analysis of ligand hapticity in rhodium(η-diene) poly(pyrazolyl)borate complexes. Inorganic chemistry 20101206
Synthesis of 2-pyridones and iminoesters via Rh(III)-catalyzed oxidative coupling between acrylamides and alkynes. Organic letters 20101203
Di- and trisubstituted γ-lactams via Rh(II)-carbenoid reaction of N-Cα-branched, N-bis(trimethylsilyl)methyl α-diazoamides. Synthesis of (±)-α-allokainic acid. Organic letters 20101203
Hydride ion-carrier ability in Rh(I) complexes of a nicotinamide-functionalised N-heterocyclic carbene ligand. Dalton transactions (Cambridge, England : 2003) 20101128
Enantioselective desymmetrization of cyclopropenes by hydroacylation. Journal of the American Chemical Society 20101124
N-methylephedrium salts as chiral surfactants for asymmetric hydrogenation in neat water with rhodium(0) nanocatalysts. ChemSusChem 20101122
Rhodium-catalysed conjugate addition of arylboronic acids to enantiopure dehydroamino acid derivatives. Organic & biomolecular chemistry 20101121
Linear-selective rhodium(I)-catalyzed addition of arylboronic acids to allyl sulfones. Angewandte Chemie (International ed. in English) 20101115
The complexation of rhodium(III) with acyclic diaminedithioether (DADTE) ligands. Dalton transactions (Cambridge, England : 2003) 20101114
Catalytic asymmetric dihydroxylation of enamides and application to the total synthesis of (+)-tanikolide. Angewandte Chemie (International ed. in English) 20101108
Rh-catalyzed oxidative coupling between primary and secondary benzamides and alkynes: synthesis of polycyclic amides. The Journal of organic chemistry 20101105
Concise and enantioselective total synthesis of 15-deoxy-Δ-(12,14)-prostaglandin J(2). The Journal of organic chemistry 20101105
Seedless polyol synthesis and CO oxidation activity of monodisperse (111)- and (100)-oriented rhodium nanocrystals in sub-10 nm sizes. Langmuir : the ACS journal of surfaces and colloids 20101102
Trapping unstable benzoquinone analogues by coordination to a [(η(5)-C(5)Me(5))Ir] fragment and the anticancer activity of the resulting complexes. Angewandte Chemie (International ed. in English) 20101102
Probing the stereo-electronic properties of cationic rhodium complexes bearing chiral diphosphine ligands by 103Rh NMR. Magnetic resonance in chemistry : MRC 20101101
Asymmetric transfer hydrogenation of ketones catalyzed by rhodium complexes containing amino acid triazole ligands. Organic & biomolecular chemistry 20101021
Rhodium-catalyzed regioselective amination of secondary allylic trichloroacetimidates with unactivated aromatic amines. Organic letters 20101015
Comparison of Rh-OCH3 and Rh-CH2OH bond dissociation energetics from methanol C-H and O-H bond reactions with rhodium(II) porphyrins. Journal of the American Chemical Society 20101006
Intramolecular hydroamination of unbiased and functionalized primary aminoalkenes catalyzed by a rhodium aminophosphine complex. Journal of the American Chemical Society 20101006
Rhodium-catalyzed organothio exchange reaction of α-organothioketones with disulfides. Chemical & pharmaceutical bulletin 20101001
Synthesis of hybrid transition-metalloproteins via thiol-selective covalent anchoring of Rh-phosphine and Ru-phenanthroline complexes. Dalton transactions (Cambridge, England : 2003) 20100928
An approach to bimetallic catalysts by ligand design. Dalton transactions (Cambridge, England : 2003) 20100928
Stereoselective synthesis of vinyl-substituted (Z)-stilbenes by rhodium-catalysed addition of arylboronic acids to allenic alcohols. Organic & biomolecular chemistry 20100921
Utilization of aldoses as a carbonyl source in cyclocarbonylation of enynes. The Journal of organic chemistry 20100917
Aerobic oxidation of alcohols catalyzed by rhodium(III) porphyrin complexes in water: reactivity and mechanistic studies. Chemical communications (Cambridge, England) 20100914
Catalyst-controlled formal [4 + 3] cycloaddition applied to the total synthesis of (+)-barekoxide and (-)-barekol. Journal of the American Chemical Society 20100908
Catalytic asymmetric synthesis of the endo-6-aryl-8-oxabicyclo[3.2.1]oct-3-en-2-one natural product from Ligusticum chuanxing via 1,3-dipolar cycloaddition of a formyl-derived carbonyl ylide using Rh2(S-TCPTTL)4. The Journal of organic chemistry 20100903
Enantioselective formal synthesis of (-)-englerin A via a Rh-catalyzed [4 + 3] cycloaddition reaction. Organic letters 20100820
Synthesis and structural characterization of binuclear half-sandwich iridium, rhodium and ruthenium complexes containing 4,4'-dipyridyldisulfide (4DPDS) ligands. Dalton transactions (Cambridge, England : 2003) 20100814
Synthesis of the guaianolide ring system via cycloaddition of a bicyclic carbonyl ylide with allyl propiolate. Organic letters 20100806
Origin of pressure effects on regioselectivity and enantioselectivity in the rhodium-catalyzed hydroformylation of styrene with (S,S,S)-BisDiazaphos. Journal of the American Chemical Society 20100804
Rhodium-catalyzed oxidative cycloaddition of benzamides and alkynes via C-H/N-H activation. Journal of the American Chemical Society 20100804
Solvent and temperature induced switching between structural isomers of Rh(I) phosphinoalkyl thioether (PS) complexes. Inorganic chemistry 20100802
Regiodivergent ligand-controlled rhodium-catalyzed [(2+2)+2] carbocyclization reactions with alkyl substituted methyl propiolates. Angewandte Chemie (International ed. in English) 20100802
Rhodium-catalyzed asymmetric conjugate addition of organoboronic acids to nitroalkenes using chiral bicyclo[3.3.0] diene ligands. Angewandte Chemie (International ed. in English) 20100802
Rh catalyzed olefination and vinylation of unactivated acetanilides. Journal of the American Chemical Society 20100728
Versatile new C(3)-symmetric tripodal tetraphosphine ligands; structural flexibility to stabilize Cu(I) and Rh(I) species and tune their reactivity. Inorganic chemistry 20100719
A rhodium IBiox[(-)-menthyl] complex as a highly selective catalyst for the asymmetric hydroarylation of azabicyles: an alternative route to epibatidine. Organic letters 20100716
Metallopeptides for asymmetric dirhodium catalysis. Journal of the American Chemical Society 20100714
Cell-selective, apoptosis-inducing rhodium(III) crown thiaether complexes. ChemMedChem 20100705
Hydrogenolysis of 1,2-propanediol for the production of biopropanols from glycerol. ChemSusChem 20100621
Photophysical properties, DNA photocleavage, and photocytotoxicity of a series of dppn dirhodium(II,II) complexes. Inorganic chemistry 20100621
Tunable aqueous phase synthesis and shape-dependent electrochemical properties of rhodium nanostructures. Inorganic chemistry 20100621
Solid-state NMR characterization of Wilkinson's catalyst immobilized in mesoporous SBA-3 silica. Chemistry (Weinheim an der Bergstrasse, Germany) 20100618
Helix induction by dirhodium: access to biocompatible metallopeptides with defined secondary structure. Chemistry (Weinheim an der Bergstrasse, Germany) 20100611
Rhodium-catalyzed linear codimerization and cycloaddition of ketenes with alkynes. Molecules (Basel, Switzerland) 20100609
Rhodium-catalyzed cyclopropenation of alkynes: synthesis of trifluoromethyl-substituted cyclopropenes. Angewandte Chemie (International ed. in English) 20100607
Design of luminescent biotinylation reagents derived from cyclometalated iridium(III) and rhodium(III) bis(pyridylbenzaldehyde) complexes. Inorganic chemistry 20100607
Regioselective rhodium(I)-catalyzed hydroarylation of protected allylic amines with arylboronic acids. Organic letters 20100604
Chiral Induction by cinchona alkaloids in the rhodium(II) catalyzed O-H insertion reaction. Chemical & pharmaceutical bulletin 20100601
Rhodium(III)-catalyzed isoquinolone synthesis: the N-O bond as a handle for C-N bond formation and catalyst turnover. Journal of the American Chemical Society 20100526
Chiral 1-phenylethylamine-derived phosphine-phosphoramidite ligands for highly enantioselective Rh-catalyzed hydrogenation of beta-(acylamino)acrylates: significant effect of substituents on 3,3'-positions of binaphthyl moiety. Organic & biomolecular chemistry 20100521
Structure-selective modification of aromatic side chains with dirhodium metallopeptide catalysts. Journal of the American Chemical Society 20100519
Rh(I)-catalyzed cycloisomerization of vinyl bicyclopropyl compounds to azabicyclo[3.2.2]nona-2,8-dienes. Chemistry (Weinheim an der Bergstrasse, Germany) 20100510
Highly efficient Rh(I)-catalyzed asymmetric hydrogenation of beta-amino acrylonitriles. Chemistry (Weinheim an der Bergstrasse, Germany) 20100510
Rhodium-catalyzed cascade reaction: aryl addition/intramolecular esterification to access 3-aryl and 3-alkenyl phthalides. Angewandte Chemie (International ed. in English) 20100510
Rhodium-catalyzed oxidative coupling/cyclization of 2-phenylindoles with alkynes via C-H and N-H bond cleavages with air as the oxidant. Organic letters 20100507
Asymmetric Rh(I)-catalyzed addition of MIDA boronates to N-tert-butanesulfinyl aldimines: development and comparison to trifluoroborates. The Journal of organic chemistry 20100507
A recyclable nanoparticle-supported rhodium catalyst for hydrogenation reactions. Molecules (Basel, Switzerland) 20100505
Rh(II)-catalyzed reaction of alpha-diazocarbonyl compounds bearing beta-trichloroacetylamino substituent: C-H insertion versus 1,2-H shift. Chemistry, an Asian journal 20100503
Rhodium(I)-catalyzed intramolecular carbonylative [2+2+1] cycloadditions and cycloisomerizations of bis(sulfonylallene)s. Chemistry (Weinheim an der Bergstrasse, Germany) 20100503
The intramolecular amination of allenes. Chemical communications (Cambridge, England) 20100428
Synthesis and application of tetraphosphane ligands in rhodium-catalyzed hydroformylation of terminal olefins: high regioselectivity at high temperature. Chemistry (Weinheim an der Bergstrasse, Germany) 20100426
Conjugated diene-assisted allylic C-H bond activation: cationic Rh(I)-catalyzed syntheses of polysubstituted tetrahydropyrroles, tetrahydrofurans, and cyclopentanes from ene-2-dienes. Journal of the American Chemical Society 20100407
Rhodium-catalyzed [2+2+2] cycloaddition of various fluorine-containing alkynes--novel synthesis of multi-substituted fluoroalkylated aromatic compounds. Organic & biomolecular chemistry 20100407
A C(2)-symmetric chiral bis-sulfoxide ligand in a rhodium-catalyzed reaction: asymmetric 1,4-addition of sodium tetraarylborates to chromenones. Journal of the American Chemical Society 20100407
Rhodium(NHC)-catalyzed amination of aryl bromides. Organic letters 20100402
Synthesis of naphtho[1,8-bc]pyran derivatives and related compounds through hydroxy group directed C-H bond cleavage under rhodium catalysis. Chemistry, an Asian journal 20100401
Chemoenzymatic synthesis and application of bicyclo[2.2.2]octadiene ligands: increased efficiency in rhodium-catalyzed asymmetric conjugate additions by electronic tuning. Angewandte Chemie (International ed. in English) 20100401
Surface and catalytic elucidation of Rh/gamma-Al2O3 catalysts during NO reduction by C3H8 in the presence of excess O2, H2O, and SO2. The journal of physical chemistry. A 20100325
Crystal transformation and host molecular motions in CO2 adsorption process of a metal benzoate pyrazine (M(II) = Rh, Cu). Journal of the American Chemical Society 20100324
Characterization of a rhodium-sparteine complex, [((-)-sparteine)Rh(eta4-COD)]+: crystal structure and DNMR/DFT studies on ligand-rotation dynamics. Dalton transactions (Cambridge, England : 2003) 20100321
Asymmetric synthesis and photophysical properties of benzopyrano- or naphthopyrano-fused helical phosphafluorenes. Organic letters 20100319
Origins of the selectivity for borylation of primary over secondary C-H bonds catalyzed by Cp*-rhodium complexes. Journal of the American Chemical Society 20100310
Rhodium carbenoid approach for introduction of 4-substituted (Z)-pent-2-enoates into sterically encumbered pyrroles and indoles. Organic letters 20100305
Novel and efficient chiral bisphosphorus ligands for rhodium-catalyzed asymmetric hydrogenation. Organic letters 20100305
Synthesis and reactivity of rhodium(II) N-triflyl azavinyl carbenes. Journal of the American Chemical Society 20100303
Platinum, palladium, and rhodium deposition to the Prunus laurus cerasus leaf surface as an indicator of the vehicular traffic pollution in the city of Varese area: an easy and reliable method to detect PGEs released from automobile catalytic converters. Environmental science and pollution research international 20100301
Optimization of cotton seed biodiesel quality (critical properties) through modification of its FAME composition by highly selective homogeneous hydrogenation. Bioresource technology 20100301
Domino rhodium/palladium-catalyzed dehydrogenation reactions of alcohols to acids by hydrogen transfer to inactivated alkenes. Chemistry (Weinheim an der Bergstrasse, Germany) 20100301
Rhodium(III) and iridium(III) complexes with 1,2-naphthoquinone-1-oximate as a bidentate ligand: synthesis, structure, and biological activity. Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry 20100301
Diastereo- and enantioselective hydrogenation of a challenging enamide derived from 4-phenyl-2-tetralone: an appealing shortcut towards enantiopure cis-2-aminotetraline derivatives. Chemistry, an Asian journal 20100301
Catalytic oxyamidation of indoles. Angewandte Chemie (International ed. in English) 20100222
Large-scale asymmetric synthesis of a cathepsin S inhibitor. The Journal of organic chemistry 20100219
Time-resolved electron paramagnetic resonance study of rhodium(III) corrole excited states. The journal of physical chemistry. A 20100211
Base-catalyzed insertion of dioxygen into rhodium-hydrogen bonds: kinetics and mechanism. Inorganic chemistry 20100201
Synthesis, substitution kinetics, and electrochemistry of the first tetrathiafulvalene-containing beta-diketonato complexes of rhodium(I). Inorganic chemistry 20100201
Fully and partially coherent pathways in multiply enhanced odd-order wave-mixing spectroscopy. The journal of physical chemistry. A 20100121
Rhodium-catalyzed [3 + 2] annulation of indoles. Journal of the American Chemical Society 20100120
The organometallic fluorine chemistry of palladium and rhodium: studies toward aromatic fluorination. Accounts of chemical research 20100119
Synthesis and application of modular phosphine-phosphoramidite ligands in asymmetric hydroformylation: structure-selectivity relationship. Chemistry (Weinheim an der Bergstrasse, Germany) 20100118
Catalytic enantioselective hydrogenation of N-alkoxycarbonyl hydrazones: a practical synthesis of chiral hydrazines. Organic letters 20100115
Rhodium(I)-catalyzed intramolecular ene reaction of vinylidenecyclopropanes and alkenes for the formation of bicyclo[5.1.0]octylenes. Organic letters 20100101
Novel, tunable, and efficient chiral bisdihydrobenzooxaphosphole ligands for asymmetric hydrogenation. Organic letters 20100101
Rhodium carbene routes to oxazoles and thiazoles. Catalyst effects in the synthesis of oxazole and thiazole carboxylates, phosphonates, and sulfones. The Journal of organic chemistry 20100101
Synthesis of methoxyfumimycin with 1,2-addition to ketimines. The Journal of organic chemistry 20100101
Preparation and characterization of Rh catalyst supported on nanoporous alumina for the ethylene hydroformylation. Journal of nanoscience and nanotechnology 20100101
Anticancer activity of heteroleptic diimine complexes of dirhodium: a study of intercalating properties, hydrophobicity and in cellulo activity. Dalton transactions (Cambridge, England : 2003) 20091228
Highly enantioselective hetero-Diels-Alder reactions between Rawal's diene and aldehydes catalyzed by chiral dirhodium(II) carboxamidates. Chemical communications (Cambridge, England) 20091221
Easy access to isoquinolines and tetrahydroquinolines from ketoximes and alkynes via rhodium-catalyzed C-H bond activation. The Journal of organic chemistry 20091218
Synthesis of 1,4-dichloro-1,3-butadienes by rhodium complex catalyzed reaction of terminal alkynes with trichloroacetyl chloride. The Journal of organic chemistry 20091218
Square planar bis{3,6-bis(trimethylsilyl)benzene-1,2-dithiolato}metal complexes of Cr(II), Co(III), and Rh(II): an experimental and density functional theoretical study. Inorganic chemistry 20091207
Regioselective synthesis of halohydrin esters from epoxides: reaction with acyl halides and rhodium-catalyzed three-component coupling reaction with alkyl halides and carbon monoxide. Chemical communications (Cambridge, England) 20091207
Synthesis of non-proteinogenic phenylalanine derivatives by rhodium-catalyzed [2+2+2] cycloaddition reactions. Organic & biomolecular chemistry 20091207
Component match in rhodium catalyzed three-component reactions of ethyl diazoacetate, H2O and aryl imines: a highly diastereoselective one-step synthesis of beta-aryl isoserine derivatives. Organic & biomolecular chemistry 20091207
Total synthesis of platensimycin and related natural products. Journal of the American Chemical Society 20091125
Synthesis of highly substituted naphthalene and anthracene derivatives by rhodium-catalyzed oxidative coupling of arylboronic acids with alkynes. Organic letters 20091119
Experimental evidence for the all-up reactive conformation of chiral rhodium(II) carboxylate catalysts: enantioselective synthesis of cis-cyclopropane alpha-amino acids. Journal of the American Chemical Society 20091118
Flame atomic absorption spectrometry for the determination of trace amount of rhodium after separation and preconcentration onto modified multiwalled carbon nanotubes as a new solid sorbent. Talanta 20091115
ESI-MS, DFT, and synthetic studies on the H(2)-mediated coupling of acetylene: insertion of C=X bonds into rhodacyclopentadienes and Brønsted acid cocatalyzed hydrogenolysis of organorhodium intermediates. Journal of the American Chemical Society 20091111
Supramolecular NHC ligands: on the influence of Zn(II)-templates on the activity of Rh(I)(cod) complexes in 'carbene polymerization'. Dalton transactions (Cambridge, England : 2003) 20091107
Rhodium-catalyzed synthesis of 3-hydroxy-beta-lactams via oxonium ylide generation: three-component reaction between azetidine-2,3-diones, ethyl diazoacetate, and alcohols. The Journal of organic chemistry 20091106
Excess substrate is a spectator ligand in a rhodium-catalyzed asymmetric [2 + 2 + 2] cycloaddition of alkenyl isocyanates with tolanes. Organic letters 20091105
Phthalides by rhodium-catalyzed ketone hydroacylation. Journal of the American Chemical Society 20091104
Enantioselective rhodium-catalyzed [2 + 2 + 2] cycloadditions of terminal alkynes and alkenyl isocyanates: mechanistic insights lead to a unified model that rationalizes product selectivity. Journal of the American Chemical Society 20091104
Rh(II)-Catalyzed skeletal reorganization of 1,6- and 1,7-enynes through electrophilic activation of alkynes. Journal of the American Chemical Society 20091028
Asymmetric transfer hydrogenation of ketones catalyzed by amino acid derived rhodium complexes: on the origin of enantioselectivity and enantioswitchability. Chemistry (Weinheim an der Bergstrasse, Germany) 20091026
Enantioselective rhodium-catalyzed conjugate alkynylation of 5-benzylidene Meldrum's acids with TMS-acetylene. Journal of the American Chemical Society 20091021
Preparation of multisubstituted enamides via rhodium-catalyzed carbozincation and hydrozincation of ynamides. The Journal of organic chemistry 20091016
Rhodium and iridium amido complexes supported by silyl pincer ligation: ammonia N-H bond activation by a [PSiP]Ir complex. Journal of the American Chemical Society 20091014
Hydrogen-deuterium exchange reactions of aromatic compounds and heterocycles by NaBD4-activated rhodium, platinum and palladium catalysts. Chemistry (Weinheim an der Bergstrasse, Germany) 20091012
Rhodium-catalyzed ring-opening reactions of a 3-aza-2-oxabicyclo[2.2.1]hept-5-ene with arylboronic acids. The Journal of organic chemistry 20091002
Organic carbonates as alternative solvents for asymmetric hydrogenation. Chirality 20091001
Rhodium-mediated enantioselective cyclopropanation of allenes. Organic letters 20091001
Steric tuning of the amidomonophosphane-rhodium(I) catalyst in asymmetric addition of arylboroxines to N-phosphinoyl aldimines. Organic letters 20091001
Asymmetric Rh-catalyzed intermolecular hydroacylation of 1,5-hexadiene with salicylaldehyde. Chemical & pharmaceutical bulletin 20091001
Development of a continuous-flow system for asymmetric hydrogenation using self-supported chiral catalysts. Chemistry (Weinheim an der Bergstrasse, Germany) 20090928
Enantioselective rhodium-catalyzed [4+2+2] cycloaddition of dienyl isocyanates for the synthesis of bicyclic azocine rings. Journal of the American Chemical Society 20090923
Total synthesis of alkaloid (+/-)-G. B. 13 using a Rh(I)-catalyzed ketone hydroarylation and late-stage pyridine reduction. Journal of the American Chemical Society 20090923
Easy preparation of Cp*-functionalized N-heterocyclic carbenes and their coordination to rhodium and iridium. Dalton transactions (Cambridge, England : 2003) 20090921
N-heterocyclic carbenes bearing two, one and no nitrogen atoms at the ylidene carbon: insight from theoretical calculations. Dalton transactions (Cambridge, England : 2003) 20090921
Pyrazolyl-N-heterocyclic carbene complexes of rhodium as hydrogenation catalysts: The influence of ligand steric bulk on catalyst activity. Dalton transactions (Cambridge, England : 2003) 20090921
Expanded ring and functionalised expanded ring N-heterocyclic carbenes as ligands in catalysis. Dalton transactions (Cambridge, England : 2003) 20090921
Synthesis, structure and properties of [1,2,4]triazolo[4,3-a]pyridin-3-ylidene rhodium and palladium complexes. Dalton transactions (Cambridge, England : 2003) 20090921
Carbene-anchored/pendent-imidazolium species as precursors to di-N-heterocyclic carbene-bridged mixed-metal complexes. Dalton transactions (Cambridge, England : 2003) 20090921
A critical electrostatic interaction mediates inhibitor recognition by human asparagine synthetase. Bioorganic & medicinal chemistry 20090915
Rhodium-catalyzed oxidative coupling of aromatic imines with internal alkynes via regioselective C-H bond cleavage. Chemical communications (Cambridge, England) 20090914
Methanol as a reaction medium and reagent in substrate reactions of rhodium porphyrins. Inorganic chemistry 20090907
Phosphabarrelene-modified Rh-catalysts: a new and selective route towards hydroxy-functionalized bicyclic imidazoles via tandem reactions. Chemical communications (Cambridge, England) 20090907
Bis(oxazolinylmethyl)pyrrole derivatives and their coordination as chiral 'pincer' ligands to rhodium. Inorganic chemistry 20090907
Rh-catalyzed reductive coupling reaction of aldehydes with conjugated dienes promoted by triethylborane. Organic letters 20090903
Isoquinoline synthesis via rhodium-catalyzed oxidative cross-coupling/cyclization of aryl aldimines and alkynes. Journal of the American Chemical Society 20090902
Chiral amidophosphane-rhodium(i)-catalyzed asymmetric conjugate arylation of acyclic enones with arylboronic acids. Chemical & pharmaceutical bulletin 20090901
Liquid-liquid extraction/separation of platinum(IV) and rhodium(III) from acidic chloride solutions using tri-iso-octylamine. Journal of hazardous materials 20090830
Synthesis of functionalized alpha-pyrone and butenolide derivatives by rhodium-catalyzed oxidative coupling of substituted acrylic acids with alkynes and alkenes. The Journal of organic chemistry 20090821
Formal aromatic C-H insertion for stereoselective isoquinolinone synthesis and studies on mechanistic insights into the C-C bond formation. The Journal of organic chemistry 20090821
Preparation of a bis(hydrosulfido) complex of Mo having a tetraphosphine co-ligand and its transformation into MoRh2 and MoIr2 mixed-metal sulfido clusters. Dalton transactions (Cambridge, England : 2003) 20090821
Live cell cytotoxicity studies: documentation of the interactions of antitumor active dirhodium compounds with nuclear DNA. Journal of the American Chemical Society 20090819
Synthesis of a core carbon framework of cyanosporasides A and B. The Journal of organic chemistry 20090807
Enantioselective Rh-catalyzed hydrogenation of 3-aryl-2-phosphonomethylpropenoates by a new class of chiral ferrocenyl diphosphine ligands. Organic letters 20090806
Eta(5)-1,2,3-trisilacyclopentadienyl--a ligand for transition metal complexes: rhodium half-sandwich and ruthenium sandwich. Journal of the American Chemical Society 20090729
Room-temperature hydrogen generation from hydrous hydrazine for chemical hydrogen storage. Journal of the American Chemical Society 20090729
A highly enantioselective allylic amination reaction using a commercially available chiral rhodium catalyst: resolution of racemic allylic carbonates. Organic letters 20090716
Divergent and expeditious access to fused skeletons inspired by indole alkaloids and transtaganolides. Organic letters 20090716
Metal nanoparticle/ionic liquid/cellulose: new catalytically active membrane materials for hydrogenation reactions. Biomacromolecules 20090713
Efficient and practical arene hydrogenation by heterogeneous catalysts under mild conditions. Chemistry (Weinheim an der Bergstrasse, Germany) 20090713
Unlocking ylide reactivity in the metal-catalyzed allylic substitution reaction: stereospecific construction of primary allylic amines with aza-ylides. Journal of the American Chemical Society 20090701
Catalytic synthesis of amino acid and peptide derivatized gadonanotubes. Journal of the American Chemical Society 20090624
Asymmetric [4 + 3] cycloadditions between vinylcarbenoids and dienes: application to the total synthesis of the natural product (-)-5-epi-vibsanin E. Journal of the American Chemical Society 20090617
A DFT study on the mechanism of a novel, regioselective, intramolecular N-pi rearrangement of cis and trans-eta1-N-Cp*Rh-hydroxytamoxifen complexes to their eta6 derivatives; potential breast cancer pharmaceuticals, and fluorescent probes. Dalton transactions (Cambridge, England : 2003) 20090614
Exceptional sensitivity of metal-aryl bond energies to ortho-fluorine substituents: influence of the metal, the coordination sphere, and the spectator ligands on M-C/H-C bond energy correlations. Journal of the American Chemical Society 20090610
Asymmetric synthesis of neolignans (-)-epi-conocarpan and (+)-conocarpan via Rh(II)-catalyzed C-H insertion process and revision of the absolute configuration of (-)-epi-conocarpan. The Journal of organic chemistry 20090605
Flexible synthesis of fused benzofuran derivatives by rhodium-catalyzed [2 + 2 + 2] cycloaddition with phenol-linked 1,6-diynes. Organic letters 20090604
Chiral crown conformation of Rh(2)(S-PTTL)(4): enantioselective cyclopropanation with alpha-alkyl-alpha-diazoesters. Journal of the American Chemical Society 20090603
Mechanistic investigations into the asymmetric transfer hydrogenation of ketones catalyzed by pseudo-dipeptide ruthenium complexes. Chemistry (Weinheim an der Bergstrasse, Germany) 20090602
In situ time-resolved XAFS studies of metal particle formation by photoreduction in polymer solutions. Langmuir : the ACS journal of surfaces and colloids 20090602
Synthesis of phthalocyanine stabilized rhodium nanoparticles and their application in biosensing of cytochrome c. Bioelectrochemistry (Amsterdam, Netherlands) 20090601
Syntheses and crystal structures of ruthenium and rhodium olefin complexes containing GaCp. Inorganic chemistry 20090601
Polymerization of phenylacetylene by rhodium complexes within a discrete space of apo-ferritin. Journal of the American Chemical Society 20090527
A bulky rhodium complex bound to an adenosine-adenosine DNA mismatch: general architecture of the metalloinsertion binding mode. Biochemistry 20090526
Redox-regulated Inhibition of T7 RNA polymerase via establishment of disulfide linkages by substituted Dppz dirhodium(II,II) complexes. Inorganic chemistry 20090518
Electrochemical and electrogenerated chemiluminescent studies of a trinuclear complex, [((phen)2Ru(dpp))2RhCl2]5+, and its interactions with calf thymus DNA. Analytical chemistry 20090515
Chemoselective tryptophan labeling with rhodium carbenoids at mild pH. Journal of the American Chemical Society 20090506
Structure-activity relationships and DNA binding properties of apoptosis inducing cytotoxic rhodium(III) polypyridyl complexes containing the cyclic thioether [9]aneS(3). Journal of inorganic biochemistry 20090501
Chemoselective hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol. Chemical communications (Cambridge, England) 20090421
Rh(2)(II)-catalyzed synthesis of carbazoles from biaryl azides. The Journal of organic chemistry 20090417
Synthesis and isolation of a stable, axially-chiral seven-membered N-heterocyclic carbene. Dalton transactions (Cambridge, England : 2003) 20090407
Highly stereoselective synthesis of aminoglycosides via rhodium-catalyzed and substrate-controlled aziridination of glycals. Organic & biomolecular chemistry 20090407
Asymmetric synthesis of diamine derivatives via sequential palladium and rhodium catalysis. Journal of the American Chemical Society 20090401
First total synthesis of antiostatin A1, a potent carbazole-based naturally occurring antioxidant. Chemical communications (Cambridge, England) 20090328
Stereoselective synthesis of multisubstituted enamides via rhodium-catalyzed carbozincation of ynamides. Journal of the American Chemical Society 20090325
Synthesis of (+)-coronafacic acid. The Journal of organic chemistry 20090320
Rhodium-catalyzed vinylcyclopropanation/cyclopentenation of strained alkenes via a sequential carborhodation process. The Journal of organic chemistry 20090320
Rhodium(I)-catalyzed cyclization reaction of o-alkynyl phenols and anilines. Domino approach to 2,3-disubstituted benzofurans and indoles. Organic letters 20090319
The reopening rate of the fingers domain is a determinant of base selectivity for RB69 DNA polymerase. Biochemistry 20090317
Effect of A and B metal ion site occupancy on conformational changes in an RB69 DNA polymerase ternary complex. Biochemistry 20090317
Rh-catalyzed isomerization and intramolecular redox reaction of alkynyl ethers affording dihydropyrans and ketoolefins. Journal of the American Chemical Society 20090311
Rhodium-catalyzed reductive cleavage of carbon-cyano bonds with hydrosilane: a catalytic protocol for removal of cyano groups. Journal of the American Chemical Society 20090311
Application of a rhodium-catalyzed addition/cyclization sequence toward the synthesis of polycyclic heteroaromatics. The Journal of organic chemistry 20090220
Rhodium(I)-catalyzed synthesis of indoles: amino-Claisen rearrangement of N-propargylanilines. The Journal of organic chemistry 20090220
DNA mismatch binding and antiproliferative activity of rhodium metalloinsertors. Journal of the American Chemical Society 20090218
An acyclic dimer of cyclodiphosphazane {(t)BuHN((t)BuNP)2OCH2}2 containing alkoxo and amido functionalities: synthesis, derivatization, Bi- (Pd(II), Rh(I)), and tetranuclear (Pd(II), Au(I), Rh(I)Au(I)) transition metal complexes. Inorganic chemistry 20090216
Discovery of mu-opioid selective ligands derived from 1-aminotetralin scaffolds made via metal-catalyzed ring-opening reactions. Bioorganic & medicinal chemistry letters 20090215
Highly cis-selective cyclopropanations with ethyl diazoacetate using a novel Rh(I) catalyst with a chelating N-heterocyclic iminocarbene ligand. Organic letters 20090205
Rhodium-catalyzed methylthio transfer reaction between ketone alpha-positions: reversible single-bond metathesis of C-S and C-H bonds. Organic letters 20090205
Chelation-assisted carbon-halogen bond activation by a rhodium(I) complex. Inorganic chemistry 20090202
Highly effective degradation of polychlorinated biphenyls in soil mediated by a Ca/Rh bicatalytic system. Chemosphere 20090201
Cytotoxic rhodium(III) and iridium(III) polypyridyl complexes: structure-activity relationships, antileukemic activity, and apoptosis induction. ChemMedChem 20090201
Rhodium-catalyzed direct oxidative carbonylation of aromatic C-H bond with CO and alcohols. Journal of the American Chemical Society 20090121
Reagent-controlled regiodivergent resolution of unsymmetrical oxabicyclic alkenes using a cationic rhodium catalyst. Journal of the American Chemical Society 20090121
Synthesis of enamides via Rh/C-catalyzed direct hydroacylation of ketoximes. Organic letters 20090115
Catalyzed addition of diazoacetoacetates to imines: synthesis of highly functionalized aziridines. Organic & biomolecular chemistry 20090107
Stereoselective rhodium-catalyzed conjugate addition of boronic acids to unprotected delta-hydroxy-gamma-butenolides. Synthesis of (-)-7-oxamuricatacin and beta-substituted derivatives. The Journal of organic chemistry 20090102
Highly regioselective hydroformylation of styrene and its derivatives catalyzed by Rh complex with tetraphosphorus ligands. Organic letters 20090101
Stereoselective hydrogenation of olefins using rhodium-substituted carbonic anhydrase--a new reductase. Chemistry (Weinheim an der Bergstrasse, Germany) 20090101
Autothermal catalytic partial oxidation of glycerol to syngas and to non-equilibrium products. ChemSusChem 20090101
Rhodium(I)-catalyzed intramolecular carbonylative [2+2+1] cycloaddition of bis(allene)s: bicyclo[6.3.0]undecadienones and bicyclo[5.3.0]decadienones. Angewandte Chemie (International ed. in English) 20090101
Total synthesis of indolizidine alkaloid (-)-209D: overriding substrate bias in the asymmetric rhodium-catalyzed [2+2+2] cycloaddition. Angewandte Chemie (International ed. in English) 20090101
Rh(I)-catalyzed regio- and stereospecific carbonylation of 1-(1-alkynyl)cyclopropyl ketones: a modular entry to highly substituted 5,6-dihydrocyclopenta[c]furan-4-ones. Chemistry (Weinheim an der Bergstrasse, Germany) 20090101
Methyleneimidazoline complexes of iridium, rhodium, and palladium from selective C(sp3)-H bond activation. Chemistry (Weinheim an der Bergstrasse, Germany) 20090101
Rhodium-catalyzed enantioselective and diastereoselective hydrogenation of beta-ketoenamides: efficient access to anti 1,3-amino alcohols. Angewandte Chemie (International ed. in English) 20090101
Rhodium-catalyzed asymmetric enyne cycloisomerization of terminal alkynes and formal total synthesis of (-)-platensimycin. Angewandte Chemie (International ed. in English) 20090101
Chemistry of ethylene glycol on a Rh(100) single-crystal surface. ChemSusChem 20090101
Tandem silylformylation-crotylsilylation/Tamao oxidation of internal alkynes: a remarkable example of generating complexity from simplicity. Organic letters 20081218
Rhodium(I)-catalyzed one-pot synthesis of dialkyl ketones from methanol and alkenes through directed sp3 C-H bond activation of N-methylamine. Chemical communications (Cambridge, England) 20081130
Solar energy in production of L-glutamate through visible light active photocatalyst--redox enzyme coupled bioreactor. Chemical communications (Cambridge, England) 20081114
Rh(I)-catalyzed direct arylation of pyridines and quinolines. Journal of the American Chemical Society 20081112
Back-electron transfer suppresses the periodic length dependence of DNA-mediated charge transport across adenine tracts. Journal of the American Chemical Society 20081112
Synthesis of D- and L-carbocyclic nucleosides via rhodium-catalyzed asymmetric hydroacylation as the key step. Organic letters 20081106
Metal-catalyzed reaction of N-(2-indolyl)methyl, N-bis(trimethylsilyl)methyl diazoamides: an entry into the beta-carboline ring system. Chemical communications (Cambridge, England) 20081021
Synthesis, characterization, and reactivity of rhodium(I) acetylacetonato complexes containing pyridinecarboxaldimine ligands. Inorganic chemistry 20081006
Sterically hindered benzophenones via rhodium-catalyzed oxidative arylation of aldehydes. The Journal of organic chemistry 20081003
Synthesis of (-)-hamigeran B. The Journal of organic chemistry 20081003
Chiral recognition of Schiff bases by 15N NMR spectroscopy in the presence of a dirhodium complex. Deuterium isotope effect on 15N chemical shift of the optically active Schiff bases and their dirhodium tetracarboxylate adducts. Magnetic resonance in chemistry : MRC 20081001
Synthesis, structure and antitumor activity of [RhCl3(N-N)(DMSO)] polypyridyl complexes. Journal of inorganic biochemistry 20081001
Fused tetracycles with a benzene or cyclohexadiene core: [2 + 2 + 2] cycloadditions on macrocyclic systems. Chemical communications (Cambridge, England) 20080928
Branch-selective reductive coupling of 2-vinyl pyridines and imines via rhodium catalyzed C-C bond forming hydrogenation. Journal of the American Chemical Society 20080924
An efficient low-temperature route to polycyclic isoquinoline salt synthesis via C-H activation with [Cp*MCl2]2 (M = Rh, Ir). Journal of the American Chemical Society 20080917
Rhodium-catalyzed substitution reaction of aryl fluorides with disulfides: p-orientation in the polyarylthiolation of polyfluorobenzenes. Journal of the American Chemical Society 20080917
Electron-transfer reactions of nitrosyl and superoxo metal complexes. Inorganic chemistry 20080915
Transition-metal-catalyzed chemoselective methylenation of dicarbonyl substrates. The Journal of organic chemistry 20080905
Asymmetric enamide hydrogenation using phosphinite thioglycosides: synthesis of D- and L-aminoesters using D-sugars as catalyst precursors. Organic letters 20080904
PCR-like cascade reactions in the context of an allosteric enzyme mimic. Journal of the American Chemical Society 20080903
Rhodium-catalyzed asymmetric addition of terminal alkynes to diarylphosphinylallenes. Chemistry, an Asian journal 20080901
Synthesis of bulky arylphosphanes by rhodium-catalyzed formal [2+2+2] cycloaddition reaction and their use as ligands. Chemistry, an Asian journal 20080901
Catalytic C-H amination for the preparation of substituted 1,2-diamines. Journal of the American Chemical Society 20080827
Catalytic enantioselective intermolecular cycloaddition of 2-diazo-3,6-diketoester-derived carbonyl ylides with alkynes and styrenes using chiral dirhodium(II) carboxylates. Organic letters 20080821
Highly regioselective isomerization-hydroformylation of internal olefins to linear aldehyde using rh complexes with tetraphosphorus ligands. Organic letters 20080821
Iron(II) bromide-catalyzed synthesis of benzimidazoles from aryl azides. Organic letters 20080807
Metal complexes with the ligand derived from 6-acetyl-1,3,7-trimethyllumazine and benzohydrazide. Molecular structures of two new Co(II) and Rh(III) complexes and analysis of in vitro antitumor activity. Journal of inorganic biochemistry 20080801
Direct functionalization of nitrogen heterocycles via Rh-catalyzed C-H bond activation. Accounts of chemical research 20080801
Structure-activity relationships of 2-aryl-1H-indole inhibitors of the NorA efflux pump in Staphylococcus aureus. Bioorganic & medicinal chemistry letters 20080801
A chiral rhodium carboxamidate catalyst for enantioselective C-H amination. Journal of the American Chemical Society 20080723
Rhodium(II)-catalyzed decomposition of 3-O-(2-diazo-2-phenylacetyl)-1,2;5,6-di-O-isopropylidene-alpha-D-allofuranose: diastereoselective ether formation. Carbohydrate research 20080721
Rh-catalyzed intermolecular cyclopropanation with alpha-alkyl-alpha-diazoesters: catalyst-dependent chemo- and diastereoselectivity. Organic letters 20080717
A convenient synthesis and the asymmetric hydrogenation of N-phthaloyl dehydroamino acid esters. Organic letters 20080717
Synthesis, biological activity, and structure-activity relationships for potent cytotoxic rhodium(III) polypyridyl complexes. Journal of medicinal chemistry 20080710
One-pot synthesis of highly functionalized pyridines via a rhodium carbenoid induced ring expansion of isoxazoles. Journal of the American Chemical Society 20080709
Synthesis of enantiomerically pure 1,2,3,4-tetrahydro-beta-carbolines and N-acyl-1-aryl ethylamines by rhodium-catalyzed hydrogenation. Chemistry, an Asian journal 20080707
Synthesis, structural characterization, and ligand replacement reactions of gem-dithiolato-bridged rhodium and iridium complexes. Inorganic chemistry 20080707
Dendrimer templated synthesis of one nanometer Rh and Pt particles supported on mesoporous silica: catalytic activity for ethylene and pyrrole hydrogenation. Nano letters 20080701
Stereoselective total syntheses of uncommon sesquiterpenoids isolated from Jatropha neopauciflora. Organic letters 20080619
Simultaneous determination of Pt and Rh by catalytic adsorptive stripping voltammetry, using hexamethylene tetramine (HMTA) as complexing agent. Talanta 20080615
Rh(I)-catalyzed intramolecular [3 + 2] cycloaddition of trans-vinylcyclopropane-enes. Journal of the American Chemical Society 20080611
Toward autonomously operating molecular machines driven by transition-metal catalyst. Molecular bioSystems 20080601
High throughput screening arrays of rhodium and iridium complexes as catalysts for intramolecular hydroamination using parallel factor analysis. The Analyst 20080601
Cobalt/rhodium heterobimetallic nanoparticle-catalyzed carbonylative [2+2+1] cycloaddition of allenes and bisallenes to Pauson-Khand-type reaction products. Chemical communications (Cambridge, England) 20080528
Asymmetric synthesis of (-)-incarvillateine employing an intramolecular alkylation via Rh-catalyzed olefinic C-H bond activation. Journal of the American Chemical Society 20080521
Access to enantioenriched alpha-amino esters via rhodium-catalyzed 1,4-addition/enantioselective protonation. Journal of the American Chemical Society 20080514
Theoretical elucidation of the rhodium-catalyzed [4 + 2] annulation reactions. Journal of computational chemistry 20080415
Syntheses of novel di- and trinucleating ligands having a triethylbenzene core with N,N-bidentate tethers: their complexation toward Pd and Rh organometallic fragments. Dalton transactions (Cambridge, England : 2003) 20080414
General access to the vinca and tacaman alkaloids using a Rh(II)-catalyzed cyclization/cycloaddition cascade. The Journal of organic chemistry 20080404
A theoretical study on the trans-addition intramolecular hydroacylation of 4-alkynals catalyzed by cationic rhodium complexes. The Journal of organic chemistry 20080404
Rhodium(II)-catalyzed transylidation of aryliodonium ylides: electronic effects of aryl groups determine their thermodynamic stabilities. Organic letters 20080403
Tandem Rh(i)-catalyzed [(5+2)+1] cycloaddition/aldol reaction for the construction of linear triquinane skeleton: total syntheses of (+/-)-hirsutene and (+/-)-1-desoxyhypnophilin. Journal of the American Chemical Society 20080402
BINOL-derived phosphoramidites in asymmetric hydrogenation: can the presence of a functionality in the amino group influence the catalytic outcome? Chemical Society reviews 20080401
Synthesis and dynamic structure of multinuclear Rh complexes of porphyrinoids. Chemical communications (Cambridge, England) 20080328
Efficient amide-directed catalytic asymmetric hydroboration. Journal of the American Chemical Society 20080326
Rhodium-catalyzed kinetic resolution of tertiary homoallyl alcohols via stereoselective carbon-carbon bond cleavage. Organic letters 20080320
Enantioselective synthesis of beta2-amino acids via Rh-catalyzed asymmetric hydrogenation with BoPhoz-type ligands: important influence of an N-H proton in the ligand on the enantioselectivity. The Journal of organic chemistry 20080307
Mo(CO)6- and [Rh(CO)2Cl]2-catalyzed allenic cyclocarbonylation reactions of alkynones: efficient access to bicyclic dienediones. Organic letters 20080306
Diastereo- and enantioselective hydrogenative aldol coupling of vinyl ketones: design of effective monodentate TADDOL-like phosphonite ligands. Journal of the American Chemical Society 20080305
Asymmetric hydrogenation catalyzed by a rhodium complex of (R)-(tert-butylmethylphosphino)(di-tert-butylphosphino)methane: scope of enantioselectivity and mechanistic study. Journal of the American Chemical Society 20080227
Rh(I)-catalyzed arylation of heterocycles via C-H bond activation: expanded scope through mechanistic insight. Journal of the American Chemical Society 20080227
Simple rhodium-chlorophosphine pre-catalysts for the ortho-arylation of phenols. Chemical communications (Cambridge, England) 20080227
2D NMR study of the DNA duplex d(CTCTC*A*ACTTCC).d(GGAAGTTGAGAG) cross-linked by the antitumor-active dirhodium(II,II) unit at the cytosine-adenine step. Biochemistry 20080226
Adsorption of naphthalene and quinoline on Pt, Pd and Rh: a DFT study. Chemphyschem : a European journal of chemical physics and physical chemistry 20080222
The application of BTEM to UV-vis and UV-vis CD spectroscopies: the reaction of Rh4(CO)12 with chiral and achiral ligands. Talanta 20080215
Carbon-carbon bond activation of 2,2,6,6-tetramethyl-piperidine-1-oxyl by a Rh(II) metalloradical: a combined experimental and theoretical study. Journal of the American Chemical Society 20080213
Sequential Rh(I)/Pd-catalyzed 1,4-addition/intramolecular allylation: stereocontrolled construction of gamma-butyrolactones and cyclopropanes. Organic letters 20080207
Bis-(2,5-diphenylphospholanes) with sp2 carbon linkers: synthesis and application in asymmetric hydrogenation. The Journal of organic chemistry 20080201
Total synthesis of (+)-achalensolide based on the rh(i)-catalyzed allenic Pauson-Khand-type reaction. The Journal of organic chemistry 20080201
Template-assisted synthesis of shape-controlled Rh2P nanocrystals. Inorganic chemistry 20080121
Asymmetric hydrogenation of unsaturated ureas with the BIPI ligands. Organic letters 20080117
Rhodium-catalyzed oxidative coupling of triarylmethanols with internal alkynes via successive C-H and C-C bond cleavages. The Journal of organic chemistry 20080104
Oxidative coupling of arylboronic acids with arenes via Rh-catalyzed direct C-H arylation. Organic letters 20080103
A computational study on DNA bases interactions with dinuclear tetraacetato-diaqua-dirhodium(II,II) complex. Journal of inorganic biochemistry 20080101
Thermal desorption of polychlorobiphenyls from contaminated soils and their hydrodechlorination using Pd- and Rh-supported catalysts. Chemosphere 20080101
Intramolecular alkyl phosphine dehydrogenation in cationic rhodium complexes of tris(cyclopentylphosphine). Chemistry (Weinheim an der Bergstrasse, Germany) 20080101
Stereoselective isomerisation of N-allyl aziridines into geometrically stable Z enamines by using rhodium hydride catalysis. Chemistry (Weinheim an der Bergstrasse, Germany) 20080101
Rhodium-complex-catalyzed asymmetric hydrogenation: transformation of precatalysts into active species. Chemistry (Weinheim an der Bergstrasse, Germany) 20080101
Highly Enantio- and s-trans C=C bond selective catalytic hydrogenation of cyclic enones: alternative synthesis of (-)-menthol. Chemistry (Weinheim an der Bergstrasse, Germany) 20080101
Rh III- and Ir III-catalyzed asymmetric transfer hydrogenation of ketones in water. Chemistry (Weinheim an der Bergstrasse, Germany) 20080101
Exploiting self-assembly for ligand-scaffold optimization: substrate-tailored ligands for efficient catalytic asymmetric hydroboration. Angewandte Chemie (International ed. in English) 20080101
Gold-catalyzed allyl-allyl coupling. Angewandte Chemie (International ed. in English) 20080101
Novel contributions to the mechanism of the enantioselective hydrogenation of dimethyl itaconate with rhodium complexes. Chemistry (Weinheim an der Bergstrasse, Germany) 20080101
A carbonyl ylide cycloaddition approach to platensimycin. Angewandte Chemie (International ed. in English) 20080101
Fluorescent naphthyl- and anthrylazoles from the catalytic coupling of phenylazoles with internal alkynes through the cleavage of multiple C-H bonds. Angewandte Chemie (International ed. in English) 20080101
Nickel, palladium and rhodium induced IFN-gamma and IL-10 production as assessed by in vitro ELISpot-analysis in contact dermatitis patients. BMC immunology 20080101
N-tosyloxycarbamates as reagents in rhodium-catalyzed C-H amination reactions. Chemistry (Weinheim an der Bergstrasse, Germany) 20080101
[Synthesis and luminescent spectral characteristics of porphyrin complexes with platinum group metals]. Bioorganicheskaia khimiia 20080101
Organic carbonates as alternative solvents for palladium-catalyzed substitution reactions. ChemSusChem 20080101
Modular chiral bidentate phosphonites: design, synthesis, and application in catalytic asymmetric hydroformylation reactions. Chemistry (Weinheim an der Bergstrasse, Germany) 20080101
Efficient catalytic decomposition of formic acid for the selective generation of H2 and H/D exchange with a water-soluble rhodium complex in aqueous solution. ChemSusChem 20080101
Head-to-head right-handed cross-links of the antitumor-active bis(mu-N,N'-di-p-tolylformamidinato)dirhodium(II,II) unit with the dinucleotides d(GpA) and d(ApG). Chemistry (Weinheim an der Bergstrasse, Germany) 20080101
The reaction of mixtures of [Rh4(CO)12] and triphenylphosphite with carbon monoxide or syngas as studied by high-resolution, high-pressure NMR spectroscopy. Magnetic resonance in chemistry : MRC 20080101
Rh-catalyzed asymmetric hydrogenation of unsaturated lactate precursors in propylene carbonate. ChemSusChem 20080101
Converting unprotected monosaccharides into functionalised lactols in aqueous media: metal-mediated allylation combined with tandem hydroformylation-cyclisation. Chemistry (Weinheim an der Bergstrasse, Germany) 20080101
Evaluation of C4 diphosphine ligands in rhodium catalysed methanol carbonylation under a syngas atmosphere: synthesis, structure, stability and reactivity of rhodium(I) carbonyl and rhodium(III) acetyl intermediates. Dalton transactions (Cambridge, England : 2003) 20071221
Enantioselective synthesis of chiral sulfones by Rh-catalyzed asymmetric addition of boronic acids to alpha,beta-unsaturated 2-pyridyl sulfones. The Journal of organic chemistry 20071221
Optimal TBHP allylic oxidation of Delta5-steroids catalyzed by dirhodium caprolactamate. Organic letters 20071220
Allyl deprotection of galacturonic acid derivatives: mechanistic aspects of mercuric-catalyzed prop-1-enyl acetal cleavage. Carbohydrate research 20071210
DNA binding and topoisomerase II inhibitory activity of water-soluble ruthenium(II) and rhodium(III) complexes. Inorganic chemistry 20071210
Rhodium-catalyzed decarbonylation of aldoses. The Journal of organic chemistry 20071207
Rhodium-catalyzed cyclohydrocarbonylation approach to the syntheses of enantiopure homokainoids. The Journal of organic chemistry 20071207
Addition of alkynes to aldehydes and activated ketones catalyzed by rhodium-phosphine complexes. The Journal of organic chemistry 20071207
Developing chiral ligands for asymmetric hydrogenation. Accounts of chemical research 20071201
Asymmetric hydrogenation using monodentate phosphoramidite ligands. Accounts of chemical research 20071201
Thioether-functionalized ferrocenyl-bis(phosphonite), Fe{(C5H4)P(-OC10H6(micro-S)C10H6O-)}2: synthesis, coordination behavior, and application in Suzuki-Miyaura cross-coupling reactions. Inorganic chemistry 20071126
Features and applications of [Rh(CO)(2)Cl](2)-catalyzed alkylations of unsymmetrical allylic substrates. The Journal of organic chemistry 20071123
Anti-Markovnikov addition of both primary and secondary amines to terminal alkynes catalyzed by the TpRh(C2H4)2/PPh3 system. Journal of the American Chemical Society 20071114
Rh-catalyzed asymmetric hydrogenation of gamma-phthalimido-substituted alpha,beta-unsaturated carboxylic acid esters: an efficient enantioselective synthesis of beta-aryl-gamma-amino acids. Organic letters 20071108
Rh-catalyzed highly enantioselective formation of functionalized cyclopentanes and cyclopentanones. Organic & biomolecular chemistry 20071107
Stereochemical features making deoxycholic acid derived tropos biphenylphosphites efficient chiral ligands for rhodium: the asymmetric hydrogenation of dimethylitaconate as a case study. The Journal of organic chemistry 20071026
Catalytic enantioselective amination of silyl enol ethers using chiral dirhodium(II) carboxylates: asymmetric formal synthesis of (-)-metazocine. Organic letters 20071025
Site-selective modification of peptides using rhodium and palladium catalysis: complementary electrophilic and nucleophilic arylation. Chemical communications (Cambridge, England) 20071014
Transition-metal-catalyzed group transfer reactions for selective C-H bond functionalization of artemisinin. Organic letters 20071011
Delta-sultone formation through Rh-catalyzed C-H insertion. Organic letters 20071011
Insertion of a bulky rhodium complex into a DNA cytosine-cytosine mismatch: an NMR solution study. Journal of the American Chemical Society 20071010
Simultaneous arming and structure/activity studies of natural products employing O-H insertions: an expedient and versatile strategy for natural products-based chemical genetics. Journal of the American Chemical Society 20071010
Adducts of rhodium(II) tetraacetate with some nitrogenous organic ligands: application of natural abundance 15N and 13C CPMAS NMR spectroscopy. Solid state nuclear magnetic resonance 20071001
Heterogeneous catalytic synthesis of ethanol from biomass-derived syngas. Chemical Society reviews 20070901
Dirhodium(II)-catalyzed C-H amination reaction of (S)-3-(tert-butyldimethylsilyloxy)-2-methylpropyl carbamate: a facile preparation of optically active monoprotected 2-amino-2-methyl-1,3-propanediol. Chemical & pharmaceutical bulletin 20070901
Allosterically regulated supramolecular catalysis of acyl transfer reactions for signal amplification and detection of small molecules. Journal of the American Chemical Society 20070822
Synthesis of (+/-)-3H-epivincamine via a Rh(II)-triggered cyclization/cycloaddition cascade. Organic letters 20070816
One-step RhCl3-catalyzed deprotection of acyclic N-allyl amides. The Journal of organic chemistry 20070803
Inhibition of endonuclease cleavage and DNA replication of E. coli plasmid by the antitumor rhodium(II) complex. Archives of biochemistry and biophysics 20070801
Rhodium-catalyzed enantioselective desymmetrization of meso-3,5-dimethyl glutaric anhydride: a general strategy to syn-deoxypolypropionate synthons. Journal of the American Chemical Society 20070801
Enantioselective synthesis of pachastrissamine (jaspin B) using dirhodium(II)-catalyzed C-H amination and asymmetric dihydroxylation as key steps. Chemical & pharmaceutical bulletin 20070801
Nanometer sized tridecylamine capped Rhodium dispersed on high surface area support: catalytic investigations. Journal of nanoscience and nanotechnology 20070801
Binuclear and trinuclear complexes of exoO(2)-cyclam. Dalton transactions (Cambridge, England : 2003) 20070721
Rhodium-catalyzed reductive mannich coupling of vinyl ketones to N-sulfonylimines mediated by hydrogen. The Journal of organic chemistry 20070720
Surface processes occurring on Rh/alumina during chiral modification by cinchonidine: an ATR-IR spectroscopy study. Langmuir : the ACS journal of surfaces and colloids 20070717
Formate as a CO surrogate for cascade processes: Rh-catalyzed cooperative decarbonylation and asymmetric Pauson-Khand-type cyclization reactions. Chemical communications (Cambridge, England) 20070707
Computational prediction of the regio- and diastereoselectivity in a rhodium-catalyzed hydroformylation/cyclization domino process. Journal of molecular modeling 20070701
Intermolecular reactions of electron-rich heterocycles with copper and rhodium carbenoids. Chemical Society reviews 20070701
Designed evolution of artificial metalloenzymes: protein catalysts made to order. Organic & biomolecular chemistry 20070621
Enantioselective reductive coupling of acetylene to N-arylsulfonyl imines via rhodium catalyzed C-C bond-forming hydrogenation: (Z)-dienyl allylic amines. Journal of the American Chemical Society 20070613
Dynamic axial ligand-site exchange in facially discriminated ruthenium(II) carbonyl and rhodium(III) halide metalloporphyrins. Inorganic chemistry 20070611
A rhodium(I)-catalyzed demethylation-cyclization of o-anisole-substituted ynamides in the synthesis of chiral 2-amido benzofurans. Organic letters 20070607
Synthesis of bulky phosphines by rhodium-catalyzed formal [2+2+2] cycloaddition reactions of tethered diynes with 1-alkynylphosphine sulfides. Journal of the American Chemical Society 20070606
Covalent binding and conformational change of pUC19 DNA by rhodium (II) metal complex. Journal of biomolecular structure & dynamics 20070601
Rhodium-catalyzed hydroformylation of 1-hexene in an ionic liquid: a molecular dynamics study of the hexene/[BMI][PF6] interface. The journal of physical chemistry. B 20070510
Rh(I)-catalyzed carbonylative cyclization reactions of alkynes with 2-bromophenylboronic acids leading to indenones. Journal of the American Chemical Society 20070502
Design of C2-symmetric tetrahydropentalenes as new chiral diene ligands for highly enantioselective Rh-catalyzed arylation of N-tosylarylimines with arylboronic acids. Journal of the American Chemical Society 20070502
The total synthesis of siphonazole, a structurally unusual bis-oxazole natural product. Chemical communications (Cambridge, England) 20070421
Preparation of Pt/Rh bimetallic colloidal particles in polymer solutions using borohydride-reduction. Journal of colloid and interface science 20070415
Synthesis of densely functionalised arenes using [2 + 2 + 2] cycloaddition reactions. Organic & biomolecular chemistry 20070407
Ovarian cancer activity of cyclic amine and thiaether metal complexes. Journal of medicinal chemistry 20070405
A general phase transfer protocol for synthesizing alkylamine-stabilized nanoparticles of noble metals. Analytica chimica acta 20070404
Nitrile-promoted Rh-catalyzed intermolecular hydroacylation of olefins with salicylaldehyde. The Journal of organic chemistry 20070330
Rhodium-catalyzed asymmetric one-pot transesterification and [2 + 2 + 2] cycloaddition leading to enantioenriched 3,3-disubstituted phthalides. Organic letters 20070329
Kinetics of oxidation of nitroxyl radicals with superoxometal complexes of chromium and rhodium. Inorganic chemistry 20070319
Benzylic substitution of gramines with boronic acids and rhodium or iridium catalysts. Organic letters 20070315
Highly selective supramolecular catalyzed allylic alcohol isomerization. Journal of the American Chemical Society 20070314
Behaviour of palladium(II), platinum(IV), and rhodium(III) in artificial and natural waters: influence of reactor surface and geochemistry on metal recovery. Analytica chimica acta 20070307
Catalytic multicomponent reactions for the synthesis of N-aryl trisubstituted pyrroles. The Journal of organic chemistry 20070302
Reversible switching of the sol-gel transition with ultrasound in rhodium(I) and iridium(I) coordination networks. Journal of the American Chemical Society 20070227
Scope and mechanism of the intermolecular addition of aromatic aldehydes to olefins catalyzed by Rh(I) olefin complexes. Journal of the American Chemical Society 20070221
Oxidation of secondary amines catalyzed by dirhodium caprolactamate. Chemical communications (Cambridge, England) 20070221
Asymmetric synthesis of the epimeric (3S)-3-((E)-hex-1-enyl)-2-methylcyclohexanones. Molecules (Basel, Switzerland) 20070221
Evaluation of functionalized silica's for the adsorptive recovery of homogenous catalysts through interaction with the metal centre. Journal of chromatography. A 20070216
De novo synthesis of Troc-protected amines: intermolecular rhodium-catalyzed C-H amination with N-tosyloxycarbamates. Organic letters 20070215
Ligand and substrate effects on the mechanism of rhodium-catalyzed hydrogenation of enamides. The Journal of organic chemistry 20070202
Synthesis of the pyrrolidinone core of KSM-2690 B. Organic letters 20070201
High-throughput nanoparticle catalysis: partial oxidation of propylene. Combinatorial chemistry & high throughput screening 20070201
Potential mobilization of platinum-group elements by siderophores in surface environments. Environmental science & technology 20070201
Rh(I)-catalyzed bimolecular cyclization between two different 1,5-bisallenes: a combinatorial one-step approach to heterosteroids and mechanistic implications. Chemistry, an Asian journal 20070108
1H, 13C and 15N NMR coordination shifts in gold(III), cobalt(III), rhodium(III) chloride complexes with pyridine, 2,2'-bipyridine and 1,10-phenanthroline. Magnetic resonance in chemistry : MRC 20070101
Hydroaminomethylation with novel rhodium-carbene complexes: an efficient catalytic approach to pharmaceuticals. Chemistry (Weinheim an der Bergstrasse, Germany) 20070101
Rh-catalyzed enantioselective conjugate addition of arylboronic acids with a dynamic library of chiral tropos phosphorus ligands. Chemistry (Weinheim an der Bergstrasse, Germany) 20070101
Dipyrrolyl-functionalized bipyridine-based anion receptors for emission-based selective detection of dihydrogen phosphate. Chemistry (Weinheim an der Bergstrasse, Germany) 20070101
Hydrogen-atom transfer in open-shell organometallic chemistry: the reactivity of Rh(II)(cod) and Ir(II)(cod) radicals. Chemistry (Weinheim an der Bergstrasse, Germany) 20070101
Rhodium-catalyzed cycloisomerization: formation of indoles, benzofurans, and enol lactones. Angewandte Chemie (International ed. in English) 20070101
Rh-catalyzed highly enantioselective synthesis of 3-arylbutanoic acids. Angewandte Chemie (International ed. in English) 20070101
Synthesis of 2,3-disubstituted indoles by a rhodium-catalyzed aromatic amino-Claisen rearrangement of N-propargyl anilines. Angewandte Chemie (International ed. in English) 20070101
Propylene carbonate as a solvent for asymmetric hydrogenations. Angewandte Chemie (International ed. in English) 20070101
A one-pot synthesis of (E)-disubstituted alkenes by a bimetallic [Rh-Pd]-catalyzed hydrosilylation/hiyama cross-coupling sequence. Chemistry (Weinheim an der Bergstrasse, Germany) 20070101
Immunotoxicity and sensitizing capacity of metal compounds depend on speciation. International journal of immunopathology and pharmacology 20070101
Solvent-dependent interconversions between Rh(I), Rh(II), and Rh(III) complexes of an aryl-monophosphine ligand. Chemistry (Weinheim an der Bergstrasse, Germany) 20070101
Preparation of arylzinc reagents and their use in the rhodium-catalyzed asymmetric 1,4-addition for the synthesis of 2-aryl-4-piperidones. Nature protocols 20070101
Counter propagation artificial neural networks modeling of an enantioselectivity of artificial metalloenzymes. Molecular diversity 20070101
Enantioselective reductive coupling of 1,3-enynes to heterocyclic aromatic aldehydes and ketones via rhodium-catalyzed asymmetric hydrogenation: mechanistic insight into the role of Brønsted acid additives. Journal of the American Chemical Society 20061227
Asymmetric induction in hydrogen-mediated reductive aldol additions to alpha-amino aldehydes catalyzed by rhodium: selective formation of syn-stereotriads directed by intramolecular hydrogen-bonding. Journal of the American Chemical Society 20061227
Supramolecular allosteric cofacial porphyrin complexes. Journal of the American Chemical Society 20061220
Rhodium-catalyzed arylative and alkenylative cyclization of 1,5-enynes induced by geminal carbometalation of alkynes. Journal of the American Chemical Society 20061213
Elucidation of structural isomers from the homogeneous rhodium-catalyzed isomerization of vegetable oils. Journal of agricultural and food chemistry 20061213
Highly selective hydroaminomethylation of internal alkenes to give linear amines. Chemistry (Weinheim an der Bergstrasse, Germany) 20061204
Synthesis and characterization of a trigonal bipyramidal supramolecular cage based upon rhodium and platinum metal centers. Chemical communications (Cambridge, England) 20061128
Reductive aldol coupling of divinyl ketones via rhodium-catalyzed hydrogenation: syn-diastereoselective construction of beta-hydroxyenones. Organic letters 20061123
Cyclopentadienone synthesis by rhodium(I)-catalyzed [3 + 2] cycloaddition reactions of cyclopropenones and alkynes. Journal of the American Chemical Society 20061122
Tandem cyclization of alkynes via rhodium alkynyl and alkenylidene catalysis. Journal of the American Chemical Society 20061122
Dirhodium(II,II) complexes: molecular characteristics that affect in vitro activity. Journal of medicinal chemistry 20061116
Hydrogen bonding makes a difference in the rhodium-catalyzed enantioselective hydrogenation using monodentate phosphoramidites. Journal of the American Chemical Society 20061108
Aqueous-phase hydroformylation of 1-octene: styrene latices as phase-transfer agents. Angewandte Chemie (International ed. in English) 20061106
Rhodium N-confused porphyrin-catalyzed alkene cyclopropanation. Chemical communications (Cambridge, England) 20061104
Dirhodium(II) tetrakis(perfluorobutyrate)-catalyzed 1,4-hydrosilylation of alpha,beta-unsaturated carbonyl compounds. Chemical & pharmaceutical bulletin 20061101
[Synthesis of fluorine compounds based on special properties of fluorine compounds]. Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan 20061101
Dirhodium tetracarboxylates derived from adamantylglycine as chiral catalysts for enantioselective C-h aminations. Organic letters 20061026
Cycloaddition protocol for the assembly of the hexacyclic framework associated with the kopsifoline alkaloids. Organic letters 20061026
Targeting DNA mismatches with rhodium intercalators functionalized with a cell-penetrating peptide. Biochemistry 20061010
Asymmetric hydrogenation with antibody-achiral rhodium complex. Organic & biomolecular chemistry 20061007
Comparison of the anti-neoplastic effects of dirhodium(II) tetrapropionate and its adducts with nicotinate and isonicotinate anions in mice bearing Ehrlich tumors. European journal of medicinal chemistry 20061001
Controlled synthesis of (S,S)-2,7-diaminosuberic acid: a method for regioselective construction of dicarba analogues of multicystine-containing peptides. The Journal of organic chemistry 20060929
Rh-catalyzed asymmetric hydrogenation of alpha-aryl imino esters: an efficient enantioselective synthesis of aryl glycine derivatives. Angewandte Chemie (International ed. in English) 20060925
NiN(2)S(2) complexes as metallodithiolate ligands to Rh(I), Rh(II) and Rh(III). Dalton transactions (Cambridge, England : 2003) 20060921
Expanding the useful range of ionic liquids: melting point depression of organic salts with carbon dioxide for biphasic catalytic reactions. Chemical communications (Cambridge, England) 20060921
A theoretical study of rhodium(I) catalyzed carbonylative ring expansion of aziridines to beta-lactams: crucial activation of the breaking C-N bond by hyperconjugation. The Journal of organic chemistry 20060915
Synthesis of the tetracyclic framework of the erythrina alkaloids using a [4 + 2]-cycloaddition/Rh(I)-catalyzed cascade of 2-imidofurans. The Journal of organic chemistry 20060915
Direct C-H arylation of (hetero)arenes with aryl iodides via rhodium catalysis. Journal of the American Chemical Society 20060913
Rhodium-catalyzed stereoselective formation of Z-enamines from allylaziridines. Journal of the American Chemical Society 20060913
Highly efficient Rh(I)-catalyzed asymmetric hydrogenation of enamines using monodente spiro phosphonite ligands. Journal of the American Chemical Society 20060913
Asymmetric transfer hydrogenation catalysed by hydrophobic dendritic DACH-rhodium complex in water. Organic & biomolecular chemistry 20060907
Phosphabarrelenes as ligands in rhodium-catalyzed hydroformylation of internal alkenes essentially free of alkene isomerization. Chemistry (Weinheim an der Bergstrasse, Germany) 20060906
High-precision catalysts: regioselective hydroformylation of internal alkenes by encapsulated rhodium complexes. Journal of the American Chemical Society 20060906
Studies of interaction between Rh(I) and human serum albumin in a 'nanostructured biocatalyst' active in the hydroformylation reaction. Journal of inorganic biochemistry 20060901
Phosphine-olefin ligands: a facile dehydrogenative route to catalytically active rhodium complexes. Chemical communications (Cambridge, England) 20060828
Catalytic hydrodechlorination of 2,4-dichlorophenol on Pd/Rh/C catalysts. Journal of hazardous materials 20060825
Head-to-head cross-linked adduct between the antitumor unit bis(mu-N,N'-di-p-tolylformamidinato)dirhodium(II,II) and the DNA fragment d(GpG). Chemistry (Weinheim an der Bergstrasse, Germany) 20060825
Cationic Rh(I) catalyst in fluorinated alcohol: mild intramolecular cycloaddition reactions of ester-tethered unsaturated compounds. The Journal of organic chemistry 20060818
Alpha-hydroxy esters via enantioselective hydrogen-mediated C-C coupling: regiocontrolled reactions of silyl-substituted 1,3-diynes. Organic letters 20060817
Enantioselective synthesis of beta-amino esters and its application to the synthesis of the enantiomers of the antidepressant Venlafaxine. Chemical communications (Cambridge, England) 20060807
Polymer-bound dirhodium tetracarboxylate films for fluorescent detection of nitric oxide. Inorganic chemistry 20060807
Dirhodium tetracarboxylate derived from adamantylglycine as a chiral catalyst for carbenoid reactions. Organic letters 20060803
Diversity synthesis using the complimentary reactivity of rhodium(II)- and palladium(II)-catalyzed reactions. The Journal of organic chemistry 20060721
1,2-migration in rhodium(II) carbene transfer reaction: remarkable steric effect on migratory aptitude. The Journal of organic chemistry 20060721
Application of the Rh(II) cyclization/cycloaddition cascade for the total synthesis of (+/-)-aspidophytine. Organic letters 20060720
Enantioselective C-C bond cleavage creating chiral quaternary carbon centers. Organic letters 20060720
Rhodium(I)-catalyzed carboxylation of aryl- and alkenylboronic esters with CO2. Journal of the American Chemical Society 20060712
Self-supported organometallic rhodium quinonoid nanocatalysts for stereoselective polymerization of phenylacetylene. Journal of the American Chemical Society 20060712
Generation of acyloxyketenes from unstable mesoionic 1,3-dioxolium-4-olates and their reaction with ketenophiles to give [2 + 2] cycloadducts. The Journal of organic chemistry 20060707
TADDOL-derived phosphites and phosphoramidites for efficient rhodium-catalyzed asymmetric hydroboration. Organic letters 20060706
Asymmetric rhodium-catalyzed hydrogenation meets gold-catalyzed cyclization: Enantioselective synthesis of 8-hydroxytetrahydroisoquinolines. Chemistry (Weinheim an der Bergstrasse, Germany) 20060705
Synthesis and characterization of monodispersed rhodium nanoparticles organized in 3-D symmetrical structures soluble in organic media. Journal of nanoscience and nanotechnology 20060701
Rhodium-catalyzed addition of arylboronic acids to isatins: an entry to diversity in 3-aryl-3-hydroxyoxindoles. Organic letters 20060622
Achiral benzophenone ligand-rhodium complex with chiral diamine activator for high enantiocontrol in asymmetric transfer hydrogenation. Chemical communications (Cambridge, England) 20060614
Simple transformation of crystalline chiral natural anions to liquid medium and their use to induce chirality. Chemical communications (Cambridge, England) 20060614
The dirhodium-method in the determination of absolute configurations of phospholene chalcogenides. Chirality 20060601
Light activated compounds as antimicrobial agents - patently obvious? Recent patents on anti-infective drug discovery 20060601
Rhodium-catalyzed ring-opening reactions of N-boc-azabenzonorbornadienes with amine nucleophiles. Journal of the American Chemical Society 20060531
A tetracoordinated rhodium aminyl radical complex. Journal of the American Chemical Society 20060524
Hybrid bidentate ligand for functional recognition: an application to regioselective C=C double bond hydrogenation. Chemical communications (Cambridge, England) 20060521
Asymmetric synthesis of protected arylglycines by rhodium-catalyzed addition of arylboronic acids to N-tert-butanesulfinyl imino esters. Journal of the American Chemical Society 20060517
Rhodium-catalyzed asymmetric addition of aryl- and alkenylboronic acids to isatins. Angewandte Chemie (International ed. in English) 20060512
Rhodium-catalyzed intramolecular, anti-Markovnikov hydroamination. Synthesis of 3-arylpiperidines. Journal of the American Chemical Society 20060510
Cp*Rh-based indicator-displacement assays for the identification of amino sugars and aminoglycosides. Chemistry (Weinheim an der Bergstrasse, Germany) 20060503
The oxidative mannich reaction catalyzed by dirhodium caprolactamate. Journal of the American Chemical Society 20060503
A mismatch-selective bifunctional rhodium-Oregon Green conjugate: a fluorescent probe for mismatched DNA. Journal of the American Chemical Society 20060503
The determination of lead in sugar and sweets without digestion by electrothermal atomic absorption spectrometry (ETAAS) with a rhodium chemical modifier. Food additives and contaminants 20060501
Cellular sensitivity to beta-diketonato complexes of ruthenium(III), chromium(III) and rhodium(III). Medicinal chemistry (Shariqah (United Arab Emirates)) 20060501
Rhodium(I)-catalyzed nucleophilic ring-opening reactions of oxabicyclo adducts derived from the [4 + 2]-cycloaddition of 2-imido-substituted furans. The Journal of organic chemistry 20060414
The direct determination of partial molar volumes and reaction volumes in ultra-dilute non-reactive and reactive multi-component systems using a combined spectroscopic and modified response surface model approach. Dalton transactions (Cambridge, England : 2003) 20060328
Rhodium(I)-catalyzed intramolecular pauson-khand-type [2 + 2 + 1] cycloaddition of allenenes. Organic letters 20060316
Rhodium-catalyzed [2 + 2 + 2] cycloaddition of alkenyl isocyanates and alkynes. Journal of the American Chemical Society 20060308
Enantioselective Rh-catalyzed hydrogenation of N-formyl dehydroamino esters with monodentate phosphoramidite ligands. The Journal of organic chemistry 20060303
Enantioselective reductive coupling of alkynes and alpha-keto aldehydes via rhodium-catalyzed hydrogenation: an approach to bryostatin substructures. Organic letters 20060302
A versatile approach toward the ansamycin antibiotics. Organic letters 20060302
Regioselective and enantiospecific rhodium-catalyzed allylic amination with thymine: synthesis of a new conformationally rigid nucleoside. Chemical communications (Cambridge, England) 20060227
Experimental and computational studies on the mechanism of N-heterocycle C-H activation by Rh(I). Journal of the American Chemical Society 20060222
Mechanistic studies of an unusual epoxide-forming elimination of a beta-hydroxyalkyl rhodium porphyrin. Chemical communications (Cambridge, England) 20060207
Rhodium assisted C-H activation of benzaldehyde thiosemicarbazones and their oxidation via activation of molecular oxygen. Inorganic chemistry 20060206
Hydrogen-mediated aldol reductive coupling of vinyl ketones catalyzed by rhodium: high syn-selectivity through the effect of tri-2-furylphosphine. Organic letters 20060202
Highly enantioselective direct reductive coupling of conjugated alkynes and alpha-ketoesters via rhodium-catalyzed asymmetric hydrogenation. Journal of the American Chemical Society 20060125
A highly selective synthesis of 3-hydroxy-2-methylpropionamide involving a one-pot tandem hydroformylation-hydrogenation sequence. Chemical communications (Cambridge, England) 20060114
Coordination chemistry of phosphanyl amino acids: solid state and solution structures of neutral and cationic rhodium complexes. Dalton transactions (Cambridge, England : 2003) 20060107
Effect of ring methylation on the photophysical, photochemical and photobiological properties of cis-dichlorobis(1,10-phenanthroline)rhodium(III)Chloride. Photochemistry and photobiology 20060101
Photophysical properties of a rhodium tetraphenylporphyrin-tin corrole dyad. The first example of a through metal-metal bond energy transfer. Photochemistry and photobiology 20060101
Synthesis of phosphine containing amino acids: utilization of peptide synthesis in ligand design. Biopolymers 20060101
Radiosensitization of CHO cells by two novel rhodium complexes under oxic and hypoxic conditions. Anticancer research 20060101
Simultaneous determination of palladium, platinum and rhodium by on-line column enrichment and HPLC with 5-(2,4-dihydroxyphenylazo)-rhodanine as pre-column derivatization reagent. Annali di chimica 20060101
Synthesis of (+/-)-brazilin using IBX. Organic letters 20051222
Unprecedented hybrid scorpionate/phosphine ligand able to be anchored to carbosilane dendrimers. Inorganic chemistry 20051212
Synthesis of colloidal dispersions of rhodium nanoparticles under high temperatures and high pressures. Journal of colloid and interface science 20051201
Synthesis and electronic characterization of bipyridine dithiolate rhodium(III) complexes. Inorganic chemistry 20051128
Simultaneous determination of palladium, platinum, rhodium and gold by on-line solid phase extraction and high performance liquid chromatography with 5-(2-hydroxy-5-nitrophenylazo)thiorhodanine as pre-column derivatization regents. Journal of chromatography. A 20051111
Benzylic oxidation catalyzed by dirhodium(II,III) caprolactamate. Organic letters 20051110
Catalytic addition methods for the synthesis of functionalized diazoacetoacetates and application to the construction of highly substituted cyclobutanones. Organic letters 20051110
Rh-catalyzed asymmetric hydrogenation of prochiral olefins with a dynamic library of chiral TROPOS phosphorus ligands. Chemistry (Weinheim an der Bergstrasse, Germany) 20051104
Direct determination of selenium in urine samples by electrothermal atomic absorption spectrometry using a Zr plus Rh-treated graphite tube and co-injection of Rh as chemical modifier. Analytical and bioanalytical chemistry 20051101
Enhanced sensitivity of lithium dithionates doped with rhodium and nickel for EPR dosimetry. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20051101
Syntheses, structures, and reactivity of new pentamethylcyclopentadienyl-rhodium(III) and -iridium(III) 4-acyl-5-pyrazolonate complexes. Inorganic chemistry 20051031
Rhodium-mediated formation of peroxides from dioxygen: isolation of hydroperoxo, silylperoxo, and methylperoxo intermediates. Angewandte Chemie (International ed. in English) 20051028
Synthesis of biologically active amines via rhodium-bisphosphite-catalyzed hydroaminomethylation. Organic letters 20051027
Detection and elimination of product inhibition from the asymmetric catalytic hydrogenation of enamines. Organic letters 20051027
Amplification of asymmetric induction in sequential reactions of bis-diazoacetates catalyzed by chiral dirhodium(II) carboxamidates. Organic letters 20051027
Solution self-assembly and solid state properties of fluorinated amphiphilic calix[4]arenes. Chemical communications (Cambridge, England) 20051021
N-tosyloxycarbamates as a source of metal nitrenes: rhodium-catalyzed C-H insertion and aziridination reactions. Journal of the American Chemical Society 20051019
Catalysis of enantioselective [2+1]-cycloaddition reactions of ethyl diazoacetate and terminal acetylenes using mixed-ligand complexes of the series Rh2(RCO2)n(L*4-n). Stereochemical heuristics for ligand exchange and catalyst synthesis. Journal of the American Chemical Society 20051019
Chemical optimization of artificial metalloenzymes based on the biotin-avidin technology: (S)-selective and solvent-tolerant hydrogenation catalysts via the introduction of chiral amino acid spacers. Chemical communications (Cambridge, England) 20051014
Practical synthesis of Dirhodium(II) tetrakis[N-phthaloyl-(S)-tert-leucinate]. Chemical & pharmaceutical bulletin 20051001
Total synthesis of (-)-colchicine via a Rh-triggered cycloaddition cascade. Organic letters 20050929
Asymmetric synthesis of 5-arylcyclohexenones by rhodium(I)-catalyzed conjugate arylation of racemic 5-(trimethylsilyl)cyclohexenone with arylboronic acids. Organic letters 20050929
Enantioselective 1,3-dipolar cycloaddition of nitrones to methacrolein catalyzed by (eta5-C5Me5)M{(R)-prophos} containing complexes (M = Rh, Ir; (R)-prophos = 1,2-bis(diphenylphosphino)propane): on the origin of the enantioselectivity. Journal of the American Chemical Society 20050928
Redox-active dirhodium(II,II) species covalently entrapped into a methylmethacrylate backbone. Dalton transactions (Cambridge, England : 2003) 20050921
Peripheral SH-functionalisation of carbosilane dendrimers including the synthesis of the model compound dimethylbis(propanethiol)silane and their interaction with rhodium complexes. Dalton transactions (Cambridge, England : 2003) 20050921
Efficient electrochemical conversion of carbon monoxide by rhodium octaethylporphyrin adsorbed on carbon black. Inorganic chemistry 20050919
Enantioselective RH-catalyzed hydrogenation of enol acetates and enol carbamates with monodentate phosphoramidites. Organic letters 20050915
An application of the phosphine-catalyzed [4 + 2] annulation in indole alkaloid synthesis: formal syntheses of (+/-)-alstonerine and (+/-)-macroline. Organic letters 20050915
Beta-aryl eliminations from Rh(I) iminyl complexes. Journal of the American Chemical Society 20050824
Hydrogen-mediated reductive coupling of conjugated alkynes with ethyl (N-Sulfinyl)iminoacetates: synthesis of unnatural alpha-amino acids via rhodium-catalyzed C-C bond forming hydrogenation. Journal of the American Chemical Society 20050817
Asymmetric hydrogenation of prochiral olefins catalysed by furanoside thioether-phosphinite Rh(I) and Ir(I) complexes. Dalton transactions (Cambridge, England : 2003) 20050807
[Cp*Rh(bpy)(H2O)]2+ as a coenzyme substitute in enzymatic oxidations catalyzed by Baeyer-Villiger monooxygenases. Chemical communications (Cambridge, England) 20050807
Control of competing N-H insertion and Wolff rearrangement in dirhodium(II)-catalyzed reactions of 3-indolyl diazoketoesters. synthesis of a potential precursor to the marine 5-(3-indolyl)oxazole martefragin A. The Journal of organic chemistry 20050722
Direct electron transfer between cytochrome P450scc and gold nanoparticles on screen-printed rhodium-graphite electrodes. Biosensors & bioelectronics 20050715
Rh(I)-catalyzed CO gas-free cyclohydrocarbonylation of alkynes with formaldehyde to alpha,beta-butenolides. Chemical communications (Cambridge, England) 20050714
A readily prepared neutral heterobimetallic titanium(IV)-rhodium(I) catalyst for intramolecular hydroacylation. Chemical communications (Cambridge, England) 20050714
Immobilization of chiral ferrocenyl ligands on silica gel and their testing in Pd-catalyzed allylic substitution and Rh-catalyzed hydrogenation. Molecules (Basel, Switzerland) 20050714
Adsorption of [D2]methanol on Ru(001)--O surfaces: the influence of preadsorbed oxygen on the methoxide geometry. Chemphyschem : a European journal of chemical physics and physical chemistry 20050711
Achiral ligands dramatically enhance rate and enantioselectivity in the Rh/phosphoramidite-catalyzed hydrogenation of alpha,beta-disubstituted unsaturated acids. Angewandte Chemie (International ed. in English) 20050704
'Matched/mismatched' diastereomeric dirhodium(II) carboxamidate catalyst pairs. Structure-selectivity correlations in diazo decomposition and hetero-Diels-Alder reactions. The Journal of organic chemistry 20050624
Efficient aziridination of olefins catalyzed by mixed-valent dirhodium(II,III) caprolactamate. Organic letters 20050623
Artificial metalloenzymes for enantioselective catalysis based on the noncovalent incorporation of organometallic moieties in a host protein. Chemistry (Weinheim an der Bergstrasse, Germany) 20050620
Organic phase stabilization of rhodium nanoparticle catalyst by direct phase transfer from aqueous solution to room temperature ionic liquid based on surfactant counter anion exchange. Chemical communications (Cambridge, England) 20050614
Rhodium-catalyzed nondecarbonylative addition reaction of ClCOCOOC2H5 to alkynes. Chemistry (Weinheim an der Bergstrasse, Germany) 20050606
Control of helix sense by composition of chiral-achiral copolymers of N-propargylbenzamides. Chemistry (Weinheim an der Bergstrasse, Germany) 20050606
The rhodium catalyzed three-component reaction of diazoacetates, titanium(IV) alkoxides and aldehydes. Chemical communications (Cambridge, England) 20050528
Rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to coumarins: asymmetric synthesis of (R)-tolterodine. Organic letters 20050526
Alpha-N-acetylmannosamine (ManNAc) synthesis via rhodium(II)-catalyzed oxidative cyclization of glucal 3-carbamates. The Journal of organic chemistry 20050513
Mechanism and origin of enantioselectivity in the Rh2(OAc)(DPTI)3-catalyzed cyclopropenation of alkynes. Journal of the American Chemical Society 20050504
Regioselectivity of rhodium nitrene insertion. Syntheses of protected glycals of l-daunosamine, d-saccharosamine, and l-ristosamine. Organic letters 20050428
A fluorous chiral dirhodium(II) complex as a recyclable asymmetric catalyst. Organic letters 20050428
Asymmetric hydrogenation using chiral Rh complexes immobilised with a new ion-exchange strategy. Organic & biomolecular chemistry 20050421
[Rh(CO)2Cl]2-catalyzed domino reactions involving allylic substitution and subsequent carbocyclization reactions. Organic letters 20050414
A study of [Co2(alkyne)(binap)(CO)4] complexes (BINAP=(1,1'-binaphthalene)-2,2'-diylbis(diphenylphosphine)). Chemistry (Weinheim an der Bergstrasse, Germany) 20050408
Use of viscogens, dNTPalphaS, and rhodium(III) as probes in stopped-flow experiments to obtain new evidence for the mechanism of catalysis by DNA polymerase beta. Biochemistry 20050405
Metal ion catalysis of natural products transformations. Novel aldopentose disproportionation reactions catalyzed by rhodium(III). Inorganic chemistry 20050321
Highly regioselective synthesis of amino-functionalized dendritic polyglycerols by a one-pot hydroformylation/reductive amination sequence. The Journal of organic chemistry 20050318
Cycloaddition chemistry of 2-vinyl-substituted indoles and related heteroaromatic systems. The Journal of organic chemistry 20050318
Synthesis and application of phosphinoferrocenylaminophosphine ligands for asymmetric catalysis. The Journal of organic chemistry 20050304
Effects of rhodium heterogeneous catalyst and isomerization conditions on linoleic acid conjugation of soybean oil. Journal of agricultural and food chemistry 20050223
Diastereoselective and enantioselective Rh(I)-catalyzed additions of arylboronic acids to N-tert-butanesulfinyl and N-diphenylphosphinoyl aldimines. Journal of the American Chemical Society 20050202
Covalent binding and interstrand cross-linking of duplex DNA by dirhodium(II,II) carboxylate compounds. Biochemistry 20050125
The diastereoselective synthesis of quaternary substituted thioindolines from sulfur ylide intermediates. The Journal of organic chemistry 20050121
Chiral 2,6-bis(oxazolinyl)pyridine-rare earth metal complexes as catalysts for highly enantioselective 1,3-dipolar cycloaddition reactions of 2-benzopyrylium-4-olates. The Journal of organic chemistry 20050107
Fluorous mixture synthesis of 4-alkylidene cyclopentenones via a rhodium-catalyzed [2+2+1] cycloaddition of alkynyl allenes. Journal of combinatorial chemistry 20050101
Synthesis and efficiency of a spherical macroporous epoxy-polyamide chelating resin for preconcentrating and separating trace noble metal ions. Annali di chimica 20050101
DNA binding and photocleavage in vitro by new dirhodium(II) dppz complexes: correlation to cytotoxicity and photocytotoxicity. Inorganic chemistry 20041227
Asymmetric synthesis of the central tryptophan residue of stephanotic acid. Organic & biomolecular chemistry 20041221
Catalytic reductive coupling of epoxides and aldehydes: epoxide-ring opening precedes carbonyl reduction. Angewandte Chemie (International ed. in English) 20041217
Ring expansion-annulation strategy for the synthesis of substituted azulenes and oligoazulenes. 2. Synthesis of azulenyl halides, sulfonates, and azulenylmetal compounds and their application in transition-metal-mediated coupling reactions. The Journal of organic chemistry 20041210
N-H insertion reactions of primary ureas: the synthesis of highly substituted imidazolones and imidazoles from diazocarbonyls. The Journal of organic chemistry 20041210
Preparation of axially chiral biphenyl diphosphine ligands and their application in asymmetric hydrogenation. Chemical & pharmaceutical bulletin 20041201
N-h insertion reactions of Boc-amino acid amides: solution- and solid-phase synthesis of pyrazinones and pyrazines. Organic letters 20041125
Novel rhodium-catalyzed reaction of thiazolidine derivatives with carbodiimides. Chemistry (Weinheim an der Bergstrasse, Germany) 20041119
Stereoselective Rh-catalyzed hydrogenation of cyclobutyl chiral enamides: double stereodifferentiation vs catalyst-controlled diastereoselection. The Journal of organic chemistry 20041112
Self-oxidation of a phenolate complex to a bimetallic stilbene quinone. Angewandte Chemie (International ed. in English) 20041112
Artificial metalloenzymes: (strept)avidin as host for enantioselective hydrogenation by achiral biotinylated rhodium-diphosphine complexes. Journal of the American Chemical Society 20041110
Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho-metalated aryl phosphines. Chemical communications (Cambridge, England) 20041107
Preparation of enantiopure norbornane ligands bearing both (2S,3S)-bis(phosphinomethyl) and 7-syn-oxygen functional groups and an application to rhodium-catalyzed asymmetric hydrogenation. Chemical & pharmaceutical bulletin 20041101
C2-symmetric diphosphinite ligands derived from carbohydrates. The strong influence of remote stereocenters on asymmetric rhodium-catalyzed hydrogenation. The Journal of organic chemistry 20041029
Dirhodium(II) caprolactamate: an exceptional catalyst for allylic oxidation. Journal of the American Chemical Society 20041027
Synthesis and coordinating ability of an anionic cobaltabisdicarbollide ligand geometrically analogous to BINAP. Chemistry (Weinheim an der Bergstrasse, Germany) 20041025
Oxidative C-arylation of free (NH)-heterocycles via direct (sp3) C-H bond functionalization. Journal of the American Chemical Society 20041020
Intermolecular coupling of alkenes to heterocycles via C-H bond activation. The Journal of organic chemistry 20041015
Binding of DNA purine sites to dirhodium compounds probed by mass spectrometry. Inorganic chemistry 20041004
Synthesis of new monodentate spiro phosphoramidite ligand and its application in Rh-catalyzed asymmetric hydrogenation reactions. Organic letters 20040930
Rhodium(II)-catalyzed aziridination of allyl-substituted sulfonamides and carbamates. The Journal of organic chemistry 20040917
Chiral norbornadienes as efficient ligands for the rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to fumaric and maleic compounds. Organic letters 20040916
An organometallic chemosensor for the sequence-selective detection of histidine- and methionine-containing peptides in water at neutral pH. Angewandte Chemie (International ed. in English) 20040913
Stereodivergent construction of cyclic ethers by a regioselective and enantiospecific rhodium-catalyzed allylic etherification: total synthesis of gaur acid. Angewandte Chemie (International ed. in English) 20040913
Powder diffraction study of a coordination polymer comprised of rigid building blocks: [Rh2(O2CCH3)4.mu2-Se2C5H8-Se,Se']infinity. Inorganic chemistry 20040906
Synthesis and reactivity of fluoro complexes: Part 2. Rhodium(I) fluoro complexes with alkene and phosphine ligands. Synthesis of the first isolated rhodium(I) bifluoride complexes. Structure of [Rh3(mu3-OH)2(COD)(3)](HF2) by X-ray powder diffraction. Inorganic chemistry 20040906
A short diastereoselective synthesis of orthogonally protected diaminosuccinic acid derivatives. The Journal of organic chemistry 20040903
Reversal of P-glycoprotein-mediated multidrug resistance by Alisol B 23-acetate. Biochemical pharmacology 20040901
103Rh NMR spectroscopy and its application to rhodium chemistry. Magnetic resonance in chemistry : MRC 20040901
Rhodium-103 NMR of [Rh(X)(PPh3)3] [X = Cl, N3, NCO, NCS, N(CN)2, NCBPh3, CNBPh3, CN] and derivatives containing CO, isocyanide, pyridine, H2 and O2. Ligand, solvent and temperature effects. Magnetic resonance in chemistry : MRC 20040901
PGSE diffusion, 1H-19F HOESY and NMR studies on several [Rh(1,5-COD)(Biphemp)]X complexes: detecting positional anion effects. Magnetic resonance in chemistry : MRC 20040901
Selective tryptophan modification with rhodium carbenoids in aqueous solution. Journal of the American Chemical Society 20040825
103Rh NMR chemical shifts in organometallic complexes: a combined experimental and density functional study. Chemistry (Weinheim an der Bergstrasse, Germany) 20040820
Cooperative bimetallic reactivity: hydrogen activation in two-electron mixed-valence compounds. Journal of the American Chemical Society 20040811
Divergence of carbonyl ylide reactions as a function of diazocarbonyl compound and aldehyde substituent: dioxolanes, dioxolenes, and epoxides. The Journal of organic chemistry 20040806
Polyphenols from peanut skins and their free radical-scavenging effects. Phytochemistry 20040801
Bifunctional rhodium intercalator conjugates as mismatch-directing DNA alkylating agents. Journal of the American Chemical Society 20040721
Investigation of the rh-catalyzed asymmetric reductive aldol reaction. Expanded scope based on reaction analysis. Organic letters 20040708
N-Boc-L-valine-connected amidomonophosphane rhodium(I) catalyst for asymmetric arylation of N-tosylarylimines with arylboroxines. Journal of the American Chemical Society 20040707
Effects of the photooxidant on DNA-mediated charge transport. Journal of the American Chemical Society 20040707
Adducts of Rh2[MTPA]4 with some phosphine chalcogenides: nature of binding and ligand exchange. Magnetic resonance in chemistry : MRC 20040701
Rh(I)-catalyzed ring opening of an IMDAF-derived oxabicyclo cycloadduct as the key step in the synthesis of (+/-)-epi-zephyranthine. Organic letters 20040624
Rhodium-catalyzed direct C-H addition of 4,4-dimethyl-2-oxazoline to alkenes. Organic letters 20040513
A new dirhodium(II) carboxamidate complex as a chiral Lewis acid catalyst for enantioselective hetero-Diels-Alder reactions. Angewandte Chemie (International ed. in English) 20040510
Dirhodium tetracarboxylate scaffolds as reversible fluorescence-based nitric oxide sensors. Journal of the American Chemical Society 20040421
Direct DNA photocleavage by a new intercalating dirhodium(II/II) complex: comparison to Rh2(mu-O2CCH3)4. Inorganic chemistry 20040419
Cholesterol amperometric biosensor based on cytochrome P450scc. Biosensors & bioelectronics 20040415
Direct, stereoselective substitution in [Rh(CO)(2)Cl](2)-catalyzed allylic alkylations of unsymmetrical substrates. Organic letters 20040415
A novel class of P-O monophosphite ligands derived from D-mannitol: broad applications in highly enantioselective Rh-catalyzed hydrogenations. The Journal of organic chemistry 20040402
Sweet success: Ionic liquids derived from non-nutritive sweeteners. Chemical communications (Cambridge, England) 20040321
The complete characterization of a rhodium Lewis acid-dipolarophile complex as an intermediate for the enantioselective catalytic 1,3-dipolar cycloaddition of C,N-diphenylnitrone to methacrolein. Journal of the American Chemical Society 20040310
Catalytic addition of metallo-aldehyde enolates to ketones: a new C-C bond-forming hydrogenation. Organic letters 20040304
An expedient and practical method for the synthesis of a diverse series of cyclopropane alpha-amino acids and amines. The Journal of organic chemistry 20040220
Metallo-aldehyde enolates via enal hydrogenation: catalytic cross aldolization with glyoxal partners as applied to the synthesis of 3,5-disubstituted pyridazines. The Journal of organic chemistry 20040220
An alternative approach based on artificial neural networks to study controlled drug release. Journal of pharmaceutical sciences 20040201
Anti-Markovnikov hydrofunctionalization of olefins mediated by rhodium-porphyrin complexes. Angewandte Chemie (International ed. in English) 20040201
Surface-enhanced Raman scattering and micro-Raman imaging of Langmuir-Blodgett films of rhodium phthalocyanine. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20040101
Improvement of catalyst durability by deposition of Rh on TiO2 in photooxidation of aromatic compounds. Environmental science & technology 20040101
Cytotoxicity and cell death pathways invoked by two new rhodium-ferrocene complexes in benign and malignant prostatic cell lines. Anticancer research 20040101
Dirhodium formamidinate compounds with bidentate nitrogen chelating ligands. Inorganic chemistry 20031229
Isotope effects and the nature of selectivity in rhodium-catalyzed cyclopropanations. Journal of the American Chemical Society 20031224
Charge transport in DNA duplex/quadruplex conjugates. Biochemistry 20031209
Synthesis of new chiral monodentate phosphite ligands and their use in catalytic asymmetric hydrogenation. Organic letters 20031016
A novel three-component reaction catalyzed by dirhodium(II) acetate: decomposition of phenyldiazoacetate with arylamine and imine for highly diastereoselective synthesis of 1,2-diamines. Organic letters 20031016
Synthesis of both enantiomers of a P-chirogenic 1,2-bisphospholanoethane ligand via convergent routes and application to rhodium-catalyzed asymmetric hydrogenation of CI-1008 (pregabalin). Journal of the American Chemical Society 20030827
Surface-enhanced Raman scattering in the ultraviolet spectral region: UV-SERS on rhodium and ruthenium electrodes. Journal of the American Chemical Society 20030813
The first triple thiol-thiolate hydrogen bond versus triple diselenide bond that bridges two metal centers. Journal of the American Chemical Society 20030806
Regioselective and enantiospecific rhodium-catalyzed allylic alkylation reactions using copper(I) enolates: synthesis of (-)-sugiresinol dimethyl ether. Journal of the American Chemical Society 20030730
Artificial metalloenzymes for enantioselective catalysis based on biotin-avidin. Journal of the American Chemical Society 20030730
Synthesis, complexation, and coordination oligomerization of 1,8-pyrazine-capped 5,12-dioxocyclams. Inorganic chemistry 20030714
Stereospecific biocatalytic epoxidation: the first example of direct regeneration of a FAD-dependent monooxygenase for catalysis. Journal of the American Chemical Society 20030709
Asymmetric synthesis of cis-5-tert-butylproline with metal carbenoid NH insertion. The Journal of organic chemistry 20030627
A Rh(I)-catalyzed cycloisomerization of homo- and bis-homopropargylic alcohols. Journal of the American Chemical Society 20030625
Spirocyclopropyl beta-lactams as mechanism-based inhibitors of serine beta-lactamases. Synthesis by rhodium-catalyzed cyclopropanation of 6-diazopenicillanate sulfone. Journal of medicinal chemistry 20030619
Regio- and enantiospecific rhodium-catalyzed arylation of unsymmetrical fluorinated acyclic allylic carbonates: inversion of absolute configuration. Journal of the American Chemical Society 20030618
Microwave-assisted C-H bond activation: a rapid entry into functionalized heterocycles. Organic letters 20030612
Rhodium-catalyzed disulfide exchange reaction. Journal of the American Chemical Society 20030604
Synthesis of griseolic acid analogues: regioselective alpha-facial [1,2]-migration in the rhodium acetate catalyzed reaction of D-glucose derived alpha-diazo-beta-keto ester. The Journal of organic chemistry 20030530
New strategic reactions for organic synthesis: catalytic asymmetric C-H activation alpha to nitrogen as a surrogate for the mannich reaction. Journal of the American Chemical Society 20030528
Rh(II) and Rh(I) two-legged piano-stool complexes: structure, reactivity, and electronic properties. Inorganic chemistry 20030519
Rhodium-catalyzed anti-Markovnikov hydroamination of vinylarenes. Journal of the American Chemical Society 20030514
Spectral pattern recognition of in situ FT-IR spectroscopic reaction data using minimization of entropy and spectral similarity (MESS): application to the homogeneous rhodium catalyzed hydroformylation of isoprene. Applied spectroscopy 20030501
Highly selective catalyst-directed pathways to dihydropyrroles from vinyldiazoacetates and imines. Journal of the American Chemical Society 20030423
Asymmetric hydrogenation of a 4,4-diaryl-3-butenoate; a novel approach to sertraline. Organic & biomolecular chemistry 20030407
Asymmetric synthesis of beta-hydroxy acid via stereoselective dirhodium(II)-catalyzed C-H insertion of alpha-alkoxydiazoketone. Chemical & pharmaceutical bulletin 20030401
[Determination of trace platinum, palladium, gold and rhodium in geological samples by ICP-AES after preconcentration by diphenlthiourea immobilized on aluminum oxide]. Guang pu xue yu guang pu fen xi = Guang pu 20030401
Application of chiral mixed phosphorus/sulfur ligands to enantioselective rhodium-catalyzed dehydroamino acid hydrogenation and ketone hydrosilylation processes. Journal of the American Chemical Society 20030326
Convenient synthesis of polyfunctionalized beta-fluoropyrroles from rhodium(II)-catalyzed intramolecular N-H insertion reactions. Organic letters 20030306
Rhodium carbenoid N-H insertion reactions of primary ureas: solution and solid-phase synthesis of imidazolones. Organic letters 20030220
Catalysts with mixed ligands on immobilized supports. Electronic and steric advantages. Organic letters 20030220
Stabilization of duplex DNA structure and suppression of transcription in vitro by bis(quinone diimine) complexes of rhodium(III) and ruthenium(II). Inorganic chemistry 20030210
Asymmetric hydrogenation of itaconic acid and enol acetate derivatives with the Rh-TangPhos catalyst. Organic letters 20030123
Borane-mediated aldol cycloreduction of monoenone monoketones: diastereoselective formation of quaternary centers. The Journal of organic chemistry 20030110
Lipid solubility of the platinum group metals Pt, Pd and Rh in dependence on the presence of complexing agents. Environmental pollution (Barking, Essex : 1987) 20030101
Thermally inert metal ammines as light-inducible DNA-targeted agents. Synthesis, photochemistry, and photobiology of a prototypical rhodium(III)-intercalator conjugate. Inorganic chemistry 20021230
A novel chiral ferrocenyl phosphine ligand from sugar: applications in Rh-catalyzed asymmetric hydrogenation reactions. Organic letters 20021212
Rhodium(II,II) dimer as an efficient catalyst for aziridination of sulfonamides and amidation of steroids. Organic letters 20021212
One-pot sequences of reactions with sol-gel entrapped opposing reagents: an enzyme and metal-complex catalysts. Journal of the American Chemical Society 20021204
Intermolecular coupling of isomerizable alkenes to heterocycles via rhodium-catalyzed C-H bond activation. Journal of the American Chemical Society 20021127
Tandem cyclization-cycloaddition behavior of rhodium carbenoids with carbonyl compounds: stereoselective studies on the construction of novel epoxy-bridged tetrahydropyranone frameworks. The Journal of organic chemistry 20021115
Remote electronic effects in the rhodium-catalyzed nucleophilic ring opening of oxabenzonorbornadienes. The Journal of organic chemistry 20021115
The charge conduction properties of DNA holliday junctions depend critically on the identity of the tethered photooxidant. Journal of the American Chemical Society 20021023
Stereochemistry of new nitrogen containing heterocyclic aldehyde. IX. Spectroscopic studies on novel mixed-ligand complexes of Rh(III). Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20021001
Photoinduced cleavage by a rhodium complex at G.U mismatches and exposed guanines in large and small RNAs. Biochimie 20020901
Rhodium carboxylate catalyzed decomposition of vinyldiazoacetates in the presence of heterodienes: enantioselective synthesis of the 6-azabicyclo[3.2.2]nonane and 6-azabicyclo[3.2.2]nonanone ring systems. The Journal of organic chemistry 20020809
Rhodium-catalyzed silylcarbocyclization (SiCaC) and carbonylative silylcarbocyclization (CO-SiCaC) reactions of enynes. Journal of the American Chemical Society 20020807
Intermolecular transition metal-catalyzed [4 + 2 + 2] cycloaddition reactions: a new approach to the construction of eight-membered rings. Journal of the American Chemical Society 20020731
Rhodium catalyzed [4 + 2 + 2] cycloaddition and alkyne insertion: a new route to eight-membered rings. Journal of the American Chemical Society 20020731
Asymmetric hydroformylation with highly crosslinked polystyrene-supported (R,S)-BINAPHOS-Rh(I) complexes: the effect of immobilization position. Bioorganic & medicinal chemistry letters 20020722
Electrochemical evaluation of rhodium dimer-DNA interactions. Journal of pharmaceutical and biomedical analysis 20020720
Highly enantioselective syntheses of functionalized alpha-methylene-gamma-butyrolactones via Rh(I)-catalyzed intramolecular Alder ene reaction: application to formal synthesis of (+)-pilocarpine. Journal of the American Chemical Society 20020717
Highly selective hydroformylation of the cinchona alkaloids. The Journal of organic chemistry 20020712
Regio- and enantiospecific rhodium-catalyzed allylic etherification reactions using copper(I) alkoxides: influence of the copper halide salt on selectivity. Journal of the American Chemical Society 20020710
Modification of carbon nanofibres for the immobilization of metal complexes: a case study with rhodium and anthranilic acid. Chemistry (Weinheim an der Bergstrasse, Germany) 20020702
Mechanism of asymmetric hydrogenation by rhodium complexes with unsymmetrical P-chirogenic bisphosphine ligands. Chirality 20020701
Stereochemical aspects of the iodine(III)-mediated aziridination reaction of some cyclic allylic carbamates. Organic letters 20020627
Catalytic asymmetric cyclopropanation using bridged dirhodium tetraprolinates on solid support. Organic letters 20020613
Structure and chemistry of N-substituted corroles and their rhodium(I) and zinc(II) metal-ion complexes. Chemistry (Weinheim an der Bergstrasse, Germany) 20020603
Controlled release of rhodium (II) carboxylates and their association complexes with cyclodextrins from hydroxyapatite matrix. Biomaterials 20020601
Synthesis of a potent antagonist of E-selectin. The Journal of organic chemistry 20020517
Highly chemoselective rhodium-catalyzed methylenation of fluorine-containing ketones. Organic letters 20020516
An ortho-substituted BIPHEP ligand and its applications in Rh-catalyzed hydrogenation of cyclic enamides. Organic letters 20020516
Total synthesis of (S)-(+)-imperanene. Effective use of regio- and enantioselective intramolecular carbon-hydrogen insertion reactions catalyzed by chiral dirhodium(II) carboxamidates. The Journal of organic chemistry 20020503
Preparation of new microgel polymers and their application as supports in organic synthesis. The Journal of organic chemistry 20020503
First example of regiospecific intermolecular C-H insertion reactions of cyclic rhodium carbenoids: novel synthesis of 3-indol-3'-yloxindoles. Chemical communications (Cambridge, England) 20020421
Oxidative charge transport through DNA in nucleosome core particles. Chemistry & biology 20020401
Reaction of singlet oxygen with Ir(I) and Rh(I) thiolato complexes: oxidative addition vs. S-oxidation. Chemical communications (Cambridge, England) 20020321
Synthesis of monodisperse oligo-p-phenylenes via rhodium-catalyzed alkyne cyclotrimerization. Organic letters 20020307
Amidoglycosylation via metal-catalyzed internal nitrogen atom delivery. Organic letters 20020307
Amplification of a cyclic mixed-metalloporphyrin tetramer from a dynamic combinatorial library through orthogonal metal coordination. Chemical communications (Cambridge, England) 20020307
One-pot preparation of chiral beta-amino esters by rhodium-catalyzed three-components coupling reaction. Chemical & pharmaceutical bulletin 20020201
Reactivity studies of anticancer active dirhodium complexes with 2-aminothiophenol. Inorganic chemistry 20020128
Synthesis of furo[2,3b]furans and furo[2,3b]pyrans via rhodium-catalyzed tandem hydroformylation/acetalization. Organic letters 20020124
DNA hydrolysis and oxidative cleavage by metal-binding peptides tethered to rhodium intercalators. Biochemistry 20020108
Detection of DNA base mismatches using DNA intercalators. Methods in enzymology 20020101
Highly enantioselective Rh-catalyzed hydrogenation based on phosphine-phosphite ligands derived from carbohydrates. The Journal of organic chemistry 20011214
A dirhodium(II)-carbenoid route to (-)- and (+)-Geissman-Waiss lactone: synthesis of (1R,7R,8R)-(-)-turneforcidine. The Journal of organic chemistry 20011214
High selectivity from configurational match/mismatch in carbon-hydrogen insertion reactions of steroidal diazoacetates catalyzed by chiral dirhodium(II) carboxamidates. The Journal of organic chemistry 20011130
Innovative synthesis of 4-carbaldehydepyrrolin-2-ones by zwitterionic rhodium catalyzed chemo- and regioselective tandem cyclohydrocarbonylation/CO insertion of alpha-imino alkynes. Journal of the American Chemical Society 20011024
Rhodium-catalyzed asymmetric 1,4-addition of organoboron reagents to 5,6-dihydro-2(1H)-pyridinones. Asymmetric synthesis of 4-aryl-2-piperidinones. The Journal of organic chemistry 20011019
Regioselective and enantiospecific rhodium-catalyzed allylic amination with N-(arylsulfonyl)anilines. Organic letters 20011018
Regioselective aromatic borylation in an inert solvent. Organic letters 20010906
Synthesis of paramagnetic tetranuclear rhodium and iridium complexes with the 2,6-pyridinedithiolate ligand. Redox-induced degradation to diamagnetic triiridium compounds. Inorganic chemistry 20010827
Long-range oxidative damage in DNA/RNA duplexes. Biochemistry 20010731
Synthesis of a new class of 5'-functionalized adenosines using a rh(ii)-catalyzed 1,3-dipolar cycloaddition. Organic letters 20010726
Dosimetry of beta-ray ophthalmic applicators: comparison of different measurement methods. Medical physics 20010701
Regio- and diastereoselective tandem rhodium-catalyzed allylic alkylation/Pauson-Khand annulation reactions. Journal of the American Chemical Society 20010516
Probing nucleic acid structure with shape-selective rhodium and ruthenium complexes. Current protocols in nucleic acid chemistry 20010501
A ring expansion-annulation strategy for the synthesis of substituted azulenes. Preparation and Suzuki coupling reactions of 1-azulenyl triflates. Organic letters 20010405
Enantioselective rhodium(I)-catalyzed hydrogenation of trifluoromethyl ketones. Organic letters 20010208
Antifungal activity of rhodium, iridium, and ruthenium tripodal phosphine complexes. The new microbiologica 20000101
Platinum group metal sensitivity: reactivity to platinum group metal salts in platinum halide salt-sensitive workers. Annals of allergy 19871201
IgE antibody responses to platinum group metals: a large scale refinery survey. British journal of industrial medicine 19860101
Properties