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Potassium Tert-Butoxide

CAS No.:
865-47-4
Catalog Number:
AG0035IS
Molecular Formula:
C4H9KO
Molecular Weight:
112.2120
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
25g
98%
In Stock USA
United States
$40
- +
100g
98%
In Stock USA
United States
$48
- +
500g
98%
In Stock USA
United States
$104
- +
Product Description
Catalog Number:
AG0035IS
Chemical Name:
Potassium Tert-Butoxide
CAS Number:
865-47-4
Molecular Formula:
C4H9KO
Molecular Weight:
112.2120
MDL Number:
MFCD00012162
IUPAC Name:
potassium;2-methylpropan-2-olate
InChI:
InChI=1S/C4H9O.K/c1-4(2,3)5;/h1-3H3;/q-1;+1
InChI Key:
LPNYRYFBWFDTMA-UHFFFAOYSA-N
SMILES:
[O-]C(C)(C)C.[K+]
EC Number:
212-740-3
UNII:
VR838VHE0V
Properties
Complexity:
29  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
2  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
112.029g/mol
Formal Charge:
0
Heavy Atom Count:
6  
Hydrogen Bond Acceptor Count:
1  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
112.213g/mol
Monoisotopic Mass:
112.029g/mol
Rotatable Bond Count:
0
Topological Polar Surface Area:
23.1A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
Literature
Title Journal
High yielding synthesis of N-ethyl dehydroamino acids. Amino acids 20121001
Intramolecular direct dehydrohalide coupling promoted by KO(t)Bu: total synthesis of Amaryllidaceae alkaloids anhydrolycorinone and oxoassoanine. Organic letters 20120907
Potassium tert-butoxide-mediated regioselective silaboration of aromatic alkenes. Chemical communications (Cambridge, England) 20120818
Lipase-mediated synthesis of water-soluble plant stanol derivatives in tert-butanol. Bioresource technology 20120601
Neocuproine-KOtBu promoted intramolecular cross coupling to approach fused rings. Chemical communications (Cambridge, England) 20110921
Mizoroki-heck-type reaction mediated by potassium tert-butoxide. Angewandte Chemie (International ed. in English) 20110509
Cross coupling: When is free really free? Nature chemistry 20101201
An efficient organocatalytic method for constructing biaryls through aromatic C-H activation. Nature chemistry 20101201
Pd-catalyzed arylation of silyl enol ethers of substituted alpha-fluoroketones. Organic & biomolecular chemistry 20090421
3-Aryltetronic acids: efficient preparation and use as precursors for vulpinic acids. The Journal of organic chemistry 20090206
Determination of carbamate, phenylurea and phenoxy acid herbicide residues by gas chromatography after potassium tert-butoxide/dimethyl sulphoxide/ethyl iodide derivatization reaction. Journal of chromatography. A 20081031
New synthetic routes to optically active alpha-quaternary alpha-aryl amino acid derivatives via the diastereoselective Stevens and Sommelet-Hauser rearrangements. Organic & biomolecular chemistry 20081021
Transition metal-free addition of ketones or nitriles to 1,3-dienes. Chemical communications (Cambridge, England) 20080207
Palladium-catalyzed cross-coupling reactions of silanolates: a paradigm shift in silicon-based cross-coupling reactions. Chemistry (Weinheim an der Bergstrasse, Germany) 20060623
Bioassay monitoring of waste PCB samples during chemical destruction treatments. Water science and technology : a journal of the International Association on Water Pollution Research 20060101
Chemiluminescence in molecular recognition: base-induced decomposition of optically active dioxetanes bearing a bisnaphthol moiety with a complex of optically active crown ether-potassium tert-butoxide. Chemical communications (Cambridge, England) 20050214
Formation of 4-aminopyrimidines via the trimerization of nitriles using focused microwave heating. Journal of combinatorial chemistry 20050101
Synthesis of carbazoles via an intramolecular cyclization of 2-(6-substituted 3(Z)-hexen-1,5-diynyl)anilines and their related molecules. The Journal of organic chemistry 20040319
Utilizing capillary gas chromatography mass spectrometry to determine 4-benzotrifluoride t-butyl ether as a reaction by-product in fluoxetine synthesized using potassium t-butoxide as base. Journal of pharmaceutical and biomedical analysis 20030205
Synthesis and characterization of injectable, water-soluble copolymers of tertiary amine methacrylates and poly(ethylene glycol) containing methacrylates. Biomaterials 20021101
Properties