Beyond benzyl grignards: facile generation of benzyl carbanions from styrenes.

Chemistry (Weinheim an der Bergstrasse, Germany) 20120723

Aerobic oxidation reactions catalyzed by vanadium complexes of bis(phenolate) ligands.

Inorganic chemistry 20120702

Synthesis of taxane ABC tricyclic skeleton from lycoctonine.

Natural product communications 20120601

Total syntheses of hopeanol and hopeahainol A empowered by a chiral Brønsted acid induced pinacol rearrangement.

Angewandte Chemie (International ed. in English) 20120423

Regioselective synthesis of 1,2-dihydropyridines by rhodium-catalyzed hydroboration of pyridines.

Journal of the American Chemical Society 20120227

Palladium-catalyzed synthesis of terminal acetals via highly selective anti-Markovnikov nucleophilic attack of pinacol on vinylarenes, allyl ethers, and 1,5-dienes.

Chemical communications (Cambridge, England) 20120128

Catalytic non-conventional trans-hydroboration: a theoretical and experimental perspective.

Chemistry (Weinheim an der Bergstrasse, Germany) 20120127

Ionic crystals [M3O(OOCC6H5)6(H2O)3]4[α-SiW12O40] (M = Cr, Fe) as heterogeneous catalysts for pinacol rearrangement.

Inorganic chemistry 20120116

Highly selective trifluoromethylation of 1,3-disubstituted arenes through iridium-catalyzed arene borylation.

Angewandte Chemie (International ed. in English) 20120109

Transition-metal-catalyzed synthesis of diboranes(4).

Angewandte Chemie (International ed. in English) 20111223

Hydride as a leaving group in the reaction of pinacolborane with halides under ambient Grignard and Barbier conditions. One-pot synthesis of alkyl, aryl, heteroaryl, vinyl, and allyl pinacolboronic esters.

The Journal of organic chemistry 20111202

Completing the puzzle of aurachin biosynthesis in Stigmatella aurantiaca Sg a15.

Molecular bioSystems 20111201

Stereoselective construction of quaternary carbon stereocenters via a semipinacol rearrangement strategy.

Accounts of chemical research 20111115

1,2-Bis(benz-yloxy)-1,2-bis-(4-chloro-phen-yl)-3,8-dimeth-oxy-acenaphthene.

Acta crystallographica. Section E, Structure reports online 20111001

Alkoxide-catalyzed reduction of ketones with pinacolborane.

The Journal of organic chemistry 20110805

An efficient copper(I)-catalyst system for the asymmetric hydroboration of β-substituted vinylarenes with pinacolborane.

Chemistry, an Asian journal 20110801

4,4,5,5-Tetra-methyl-1,3,2λ-dioxa-phospho-lan-2-one.

Acta crystallographica. Section E, Structure reports online 20110801

Structure-based design of novel boronic acid-based inhibitors of autotaxin.

Journal of medicinal chemistry 20110714

Silver-catalyzed 1,3-dipolar cycloaddition of azomethine ylides with β-boryl acrylates.

The Journal of organic chemistry 20110318

New developments in aromatic halogenation, borylation, and cyanation.

Chimia 20110101

Chiral Brønsted acid catalyzed pinacol rearrangement.

Angewandte Chemie (International ed. in English) 20101210

Diols and anions can control the formation of an exciplex between a pyridinium boronic acid with an aryl group connected via a propylene linker.

Chemical communications (Cambridge, England) 20101121

Catalytic activity of phosphine-copper complexes for hydroboration of styrene with pinacolborane: experiment and theory.

The journal of physical chemistry. A 20101118

1-Bromo-3-(1',1'-dimethylalkyl)-1-deoxy-Δ(8)-tetrahydrocannabinols: New selective ligands for the cannabinoid CB(2) receptor.

Bioorganic & medicinal chemistry 20101115

An opportunity for Mg-catalyzed Grignard-type reactions: direct coupling of benzylic halides with pinacolborane with 10 mol % of magnesium.

Journal of the American Chemical Society 20100901

Isolation and reactivity of palladium hydrido complexes: intermediates in the hydrodefluorination of pentafluoropyridine.

Dalton transactions (Cambridge, England : 2003) 20100828

C-H bond activation/borylation of furans and thiophenes catalyzed by a half-sandwich iron N-heterocyclic carbene complex.

Chemistry, an Asian journal 20100705

The synthesis and NMR investigation on novel boron derivatives of stavudine.

Bioorganic chemistry 20100601

Synthesis of notoamide J: a potentially pivotal intermediate in the biosynthesis of several prenylated indole alkaloids.

The Journal of organic chemistry 20100507

Borinium cations as sigma-B-H ligands in osmium complexes.

Journal of the American Chemical Society 20100428

Catalytic asymmetric conjugate addition of alpha-cyanoketones for the construction of a quaternary stereogenic center.

Organic letters 20100402

Regio- and stereoselective Ni-catalyzed 1,4-hydroboration of 1,3-dienes: access to stereodefined (Z)-allylboron reagents and derived allylic alcohols.

Journal of the American Chemical Society 20100303

Dramatic effect of Lewis acids on the rhodium-catalyzed hydroboration of olefins.

Journal of the American Chemical Society 20100113

Highly regio- and stereoselective synthesis of (Z)-trisubstituted alkenes via propyne bromoboration and tandem Pd-catalyzed cross-coupling.

Organic letters 20090917

Rationally improved chiral Brønsted acid for catalytic enantioselective allylboration of aldehydes with an expanded reagent scope.

The Journal of organic chemistry 20090605

Synthesis of 1-borylisoindoles via palladium-catalyzed dehydrogenation/C-H borylation of isoindolines.

Journal of the American Chemical Society 20090506

Unexpected Ti(III)/Mn-promoted pinacol coupling of ketones.

The Journal of organic chemistry 20090501

Reduction of benzophenones with SmI2. Post electron transfer processes.

The Journal of organic chemistry 20090306

Demonstration that CobG, the monooxygenase associated with the ring contraction process of the aerobic cobalamin (vitamin B12) biosynthetic pathway, contains an Fe-S center and a mononuclear non-heme iron center.

The Journal of biological chemistry 20090220

Diastereoselective intramolecular pinacol couplings of sulfinyl iron(0) diene complexes.

The Journal of organic chemistry 20090220

Aerobic oxidation of pinacol by vanadium(V) dipicolinate complexes: evidence for reduction to vanadium(III).

Journal of the American Chemical Society 20090121

Selectivity control in Lewis acid catalyzed regiodivergent tandem cationic cyclization/ring expansion terminated by pinacol rearrangement.

Angewandte Chemie (International ed. in English) 20090101

Activation of B-H bonds by an oxo-rhenium complex.

Dalton transactions (Cambridge, England : 2003) 20081221

Asymmetric reductive Mannich reaction to ketimines catalyzed by a Cu(I) complex.

Journal of the American Chemical Society 20081203

Diastereoselective addition of zincated hydrazones to alkenylboronates and stereospecific trapping of boron/zinc bimetallic intermediates by carbon electrophiles.

Journal of the American Chemical Society 20081119

Diastereoselective synthesis of cyclopentanediols by InCl 3/Al mediated intramolecular pinacol coupling reaction in aqueous media.

Molecules (Basel, Switzerland) 20081027

Ionic-liquid-promoted decaborane olefin-hydroboration: a new efficient route to 6-R-B10H13 derivatives.

Inorganic chemistry 20081020

Total syntheses of (+)- and (-)-peribysin E.

Journal of the American Chemical Society 20081015

Synthesis, characterization, and reactivity of rhodium(I) acetylacetonato complexes containing pyridinecarboxaldimine ligands.

Inorganic chemistry 20081006

Analysis of recognition of fructose by imprinted polymers.

Talanta 20080915

Pinacol macrocyclization-based route to the polyfused medium-sized CDE ring system of lancifodilactone G.

Organic letters 20080904

Sigma-borane complexes of iridium: synthesis and structural characterization.

Journal of the American Chemical Society 20080813

9,9-Dioctyl-2,7-bis-(4,4,5,5-tetra-methyl-1,3,2-dioxaborolan-2-yl)-9H-fluorene.

Acta crystallographica. Section E, Structure reports online 20080801

An expeditious one-step entry to the tetracyclic core of integrastatins.

Chemical communications (Cambridge, England) 20080721

An improved system for the palladium-catalyzed borylation of aryl halides with pinacol borane.

The Journal of organic chemistry 20080718

Catalytic enantioselective allyl- and crotylboration of aldehydes using chiral diol x SnCl4 complexes. optimization, substrate scope and mechanistic investigations.

Journal of the American Chemical Society 20080702

rac-(2R,3S)-2-Phenyl-3-(3-phenyl-1,2,3,4-tetra-hydro-quinoxalin-2-yl)quinoxaline.

Acta crystallographica. Section E, Structure reports online 20080701

Gold(I)-catalyzed divergence in the reactivity of 3-silyloxy 1,6-enynes: pinacol-terminated vs claisen-terminated cyclization cascades.

Organic letters 20080619

Sequential Ni-catalyzed borylation and cross-coupling of aryl halides via in situ prepared neopentylglycolborane.

Organic letters 20080619

Stereochemical nonrigidity of a chiral rhodium boryl hydride complex: a sigma-borane complex as transition state for isomerization.

Journal of the American Chemical Society 20080402

Efficient amide-directed catalytic asymmetric hydroboration.

Journal of the American Chemical Society 20080326

On the role of samarium/HMPA in the post electron-transfer steps in SmI2 reductions.

Organic letters 20080306

Thermometric MIP sensor for fructosyl valine.

Biosensors & bioelectronics 20080227

Stepwise oxygenation of pinacolborane by a rhodiumperoxo complex: detection of an intermediate metal borate and perborate.

Angewandte Chemie (International ed. in English) 20080101

Enantioselective pinacol coupling of aryl aldehydes catalyzed by chiral Salan-Mo(IV) complexes.

The Journal of organic chemistry 20071221

The skeletal rearrangement of gold- and platinum-catalyzed cycloisomerization of cis-4,6-dien-1-yn-3-ols: pinacol rearrangement and formation of bicyclo[4.1.0]heptenone and reorganized styrene derivatives.

Journal of the American Chemical Society 20071219

Samarium(ii) iodide-mediated intramolecular pinacol coupling reactions with cyclopropyl ketones.

Chemical communications (Cambridge, England) 20071207

Room temperature-stable electride as a synthetic organic reagent: application to pinacol coupling reaction in aqueous media.

Organic letters 20071011

Theoretical study of the role of solvent H2O in neopentyl and pinacol rearrangements.

Journal of computational chemistry 20070715

Palladium-catalyzed cyclization of 1,omega-dienols: multiple ways to intramolecularly trap a carbocation.

The Journal of organic chemistry 20070622

Development of fructosyl valine binding polymers by covalent imprinting.

Biosensors & bioelectronics 20070615

One-pot synthesis of arylboronic acids and aryl trifluoroborates by Ir-catalyzed borylation of arenes.

Organic letters 20070301

Catalyzed tandem reaction of 3-silyloxy-1,5-enynes consisting of cyclization and pinacol rearrangement.

Angewandte Chemie (International ed. in English) 20070101

Synthetic studies toward (-)-FR901483 using a conjugate allylation to install the C-1 quaternary carbon.

The Journal of organic chemistry 20061208

Luminescence tuning of organoboron quinolates through substituent variation at the 5-position of the quinolato moiety.

Organic letters 20061109

TADDOL-derived phosphites and phosphoramidites for efficient rhodium-catalyzed asymmetric hydroboration.

Organic letters 20060706

Mechanisms of glycerol dehydration.

The journal of physical chemistry. A 20060511

Novel calixarene hemisphere synthesized via pinacol rearrangement of [2.1.2.1]metacyclophane.

Organic letters 20060511

The uptake of methyl vinyl ketone, methacrolein, and 2-methyl-3-butene-2-ol onto sulfuric acid solutions.

The journal of physical chemistry. A 20060223

Studies of low-coordinate iron dinitrogen complexes.

Journal of the American Chemical Society 20060125

Formation of arylboronates by a CuI-catalyzed coupling reaction of pinacolborane with aryl iodides at room temperature.

Organic letters 20060119

New enantioselective entry to cycloheptane amino acid polyols.

The Journal of organic chemistry 20060106

Stereoselective pinacol coupling of chiral formylferrocene using divalent samarium triflate: preparation of a new chiral bisferrocenyl oxazoline ligand and its application to asymmetric Diels-Alder reactions.

Organic letters 20051222

The unusual phases of anhydrous and hydrated pinacol.

Acta crystallographica. Section B, Structural science 20051201

A density functional study of propylene glycol conversion to propanal and propanone of various acid-catalyzed reaction models: a water-addition effect.

Journal of computational chemistry 20051130

Samarium diiodide-induced intramolecular pinacol coupling of dinitrones: synthesis of cyclic cis-vicinal diamines.

Chemical communications (Cambridge, England) 20051121

Novel multichiral diols and diamines by highly stereoselective pinacol coupling of planar chiral [2.2]paracyclophane derivatives.

Chemistry (Weinheim an der Bergstrasse, Germany) 20051118

Nickel-catalyzed trans-alkynylboration of alkynes via activation of a boron-chlorine bond.

Journal of the American Chemical Society 20051116

Vanadium-catalyzed pinacol coupling reaction in water.

The Journal of organic chemistry 20051014

Preparation and Suzuki-Miyaura coupling reactions of tetrahydropyridine-2-boronic acid pinacol esters.

The Journal of organic chemistry 20050902

Tetracyanoanthraquinodimethanes with a chiral amide group: preparation, properties, and charge-transfer photochirogenetic reaction with 1,2-dianisylacenaphthene-1,2-diol.

The Journal of organic chemistry 20050708

Syntheses and reactions of the bis-boryloxide O(Bpin)2(pin = O2C2Me4).

Dalton transactions (Cambridge, England : 2003) 20050621

Steric effects in metathesis and reduction reactions of phosphinimines with catechol- and pinacolboranes.

Inorganic chemistry 20050613

Synthesis of planar-chiral paracyclophanes via samarium(II)-catalyzed intramolecular pinacol coupling.

Organic letters 20050609

Highly functionalised cyclobutanols via samarium(II) iodide-induced pinacol cyclisations of carbohydrate-derived 1,4-diketones.

Carbohydrate research 20050523

Ketone-imide versus ketone-oxime reductive cross-coupling promoted by samarium diiodide: new mechanistic insight gained from a failed aminocyclopentitol synthesis.

The Journal of organic chemistry 20050513

Samarium diiodide-catalyzed diastereoselective pinacol couplings.

Organic letters 20050512

A chelation effect on the pathway between intramolecular hydrodimerization and pinacol coupling.

Organic letters 20050414

Pinacol coupling of aromatic aldehydes and ketones using TiCl3-Mg under ultrasound irradiation.

Ultrasonics sonochemistry 20050401

Rhodium boryl complexes in the catalytic, terminal functionalization of alkanes.

Journal of the American Chemical Society 20050302

Six- and eightfold palladium-catalyzed cross-coupling reactions of hexa- and octabromoarenes.

Chemistry (Weinheim an der Bergstrasse, Germany) 20041217

Ring expansion-annulation strategy for the synthesis of substituted azulenes and oligoazulenes. 2. Synthesis of azulenyl halides, sulfonates, and azulenylmetal compounds and their application in transition-metal-mediated coupling reactions.

The Journal of organic chemistry 20041210

In quest of factors that control the enantioselective catalytic Markovnikov hydroboration/oxidation of vinylarenes.

Chemistry (Weinheim an der Bergstrasse, Germany) 20041203

Efficient analyte oxidation in an electrospray ion source using a porous flow-through electrode emitter.

Journal of the American Society for Mass Spectrometry 20041201

Palladium-catalyzed borylation of phenyl bromides and application in one-pot Suzuki-Miyaura biphenyl synthesis.

Organic letters 20041125

Catalytic, highly enantio- and diastereoselective pinacol coupling reaction with a new tethered bis(8-quinolinolato) ligand.

Journal of the American Chemical Society 20041020

The potential of photochemical transition metal reactions in prebiotic organic synthesis. I. Observed conversion of methanol into ethylene glycol as possible prototype for sugar alcohol formation.

Origins of life and evolution of the biosphere : the journal of the International Society for the Study of the Origin of Life 20041001

Regio- and enantiocontrol in the room-temperature hydroboration of vinyl arenes with pinacol borane.

Journal of the American Chemical Society 20040804

Theoretical study of reaction pathways for the rhodium phosphine-catalysed borylation of C-H bonds with pinacolborane.

Dalton transactions (Cambridge, England : 2003) 20040521

Reaction of tin porphyrins with vicinal diols.

Inorganic chemistry 20040405

Photochemical pinacol rearrangements of unsymmetrical diols.

The Journal of organic chemistry 20040319

Palladium-catalyzed cross-coupling of stereospecific potassium cyclopropyl trifluoroborates with aryl bromides.

Organic letters 20040205

Metal-catalyzed reactions of diborons for synthesis of organoboron compounds.

Chemical record (New York, N.Y.) 20040101

Room temperature borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane catalyzed by iridium complexes in an inert solvent.

Chemical communications (Cambridge, England) 20031207

Synthesis of 2,3-substituted thienylboronic acids and esters.

The Journal of organic chemistry 20031128

Synthesis of arylboronates by the palladium catalysed cross-coupling reaction in ionic liquids.

Organic & biomolecular chemistry 20031007

Waste-free and facile solid-state protection of diamines, anthranilic acid, diols, and polyols with phenylboronic acid.

Chemistry (Weinheim an der Bergstrasse, Germany) 20030905

Truly catalytic and enantioselective pinacol coupling of aryl aldehydes mediated by chiral Ti(III) complexes.

The Journal of organic chemistry 20030711

New mixed phosphonate esters by transesterification of pinacol phosphonates and their use in aldehyde and ketone coupling reactions with nonstabilized phosphonates.

The Journal of organic chemistry 20030221

A novel, solventless reductive coupling of carbonyl compounds by alkali metals, catalysed by bromobenzene.

Chemical communications (Cambridge, England) 20030221

Pinacol coupling reaction of beta-halo-alpha,beta-unsaturated aldehydes promoted by TiI4.

Organic letters 20021114

Mechanistic insight into fragmentation reactions of titanapinacolate complexes.

Journal of the American Chemical Society 20021016

A sigma 4, lambda 5-phosphinine palladium complex: a new type of phosphorus ligand and catalyst. Application to the Pd-catalyzed formation of arylboronic esters.

Chemical communications (Cambridge, England) 20020807

Novel Brønsted acidic ionic liquids and their use as dual solvent-catalysts.

Journal of the American Chemical Society 20020529

sigma-Borane and dihydroborate complexes of ruthenium.

Journal of the American Chemical Society 20020522

Efficient synthesis and hydrolysis of cyclic oxalate esters of glycols.

Chemical & pharmaceutical bulletin 20020301

Microwave-assisted synthesis of pinacol boronates from aryl chlorides catalyzed by a palladium/imidazolium salt system.

Organic letters 20020221

Rhodium-catalyzed, regiospecific functionalization of polyolefins in the melt.

Journal of the American Chemical Society 20020220

Enantioselective pinacol coupling of aldehydes mediated and catalyzed by chiral titanium complexes.

Organic letters 20011129

Synthesis of novel, potent, diol-based HIV-1 protease inhibitors via intermolecular pinacol homocoupling of (2S)-2-benzyloxymethyl-4-phenylbutanal.

Journal of medicinal chemistry 20011011

Photochemical reactions and on-line UV detection in microfabricated reactors.

Lab on a chip 20010901

Reactions of aliphatic ketones R2CO (R=Me, Et, iPr and tBu) with the MCI4/Li(Hg) system (M=U or Ti): mechanistic analogies between the McMurry, Wittig, and Clemmensen reactions.

Chemistry (Weinheim an der Bergstrasse, Germany) 20010716

Diastereoselective inter- and intramolecular pinacol coupling of aldehydes promoted by monomeric titanocene(II) complex Cp(2)TiPh.

The Journal of organic chemistry 20010601

Hydroboration of unsaturated phosphonic esters: synthesis of boronophosphonates and trisubstituted vinylphosphonates.

Organic letters 20010125