Trimethylsilylacetylene
Title | Journal |
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Electron acceptors based on functionalizable cyclopenta[hi]aceanthrylenes and dicyclopenta[de,mn]tetracenes. | Journal of the American Chemical Society 20120926 |
Synthesis of Enantiopure tertiary skipped diynes via one-pot desymmetrizing TMS-cleavage. | Organic letters 20120803 |
A general procedure for the synthesis of alkyl- and arylethynyl-1,2,3-triazole-fused dihydroisoquinolines. | Organic & biomolecular chemistry 20120214 |
A selective intramolecular 5-exo-dig or 6-endo-dig cyclization en route to 2-furanone or 2-pyrone containing tricyclic scaffolds. | The Journal of organic chemistry 20111202 |
Acetylene-expanded dendralene segments with exotopic phosphaalkene units. | Chemistry (Weinheim an der Bergstrasse, Germany) 20111017 |
A terminal nickel(II) anilide complex featuring an unsymmetrically substituted amido pincer ligand: synthesis and reactivity. | Dalton transactions (Cambridge, England : 2003) 20110921 |
Synthesis of a small library of bivalent α-D-mannopyranosides for lectin cross-linking. | Carbohydrate research 20110906 |
Crystallographic coincidence of two bridging species in a dinuclear Co ethynyl-benzene complex. | Acta crystallographica. Section E, Structure reports online 20110701 |
A specific chemodosimeter for fluoride ion based on a pyrene derivative with trimethylsilylethynyl groups. | Organic & biomolecular chemistry 20110621 |
Sequential coupling/desilylation-coupling/cyclization in a single pot under Pd/C-Cu catalysis: synthesis of 2-(hetero)aryl indoles. | Organic & biomolecular chemistry 20110521 |
Highly enantioselective addition of trimethylsilylacetylene to aldehydes catalyzed by a zinc-amino-alcohol complex. | Chemistry (Weinheim an der Bergstrasse, Germany) 20110516 |
Synthesis and stereochemical assignment of (+)-chamuvarinin. | Organic letters 20110204 |
First total synthesis and antileishmanial activity of (Z)-16-methyl-11-heptadecenoic acid, a new marine fatty acid from the sponge Dragmaxia undata. | Chemistry and physics of lipids 20110201 |
Preparation of 4'-benzenesulfonyl-3'-deoxythymidine and its reaction with organoaluminum and organosilicon reagents. | Carbohydrate research 20101210 |
A versatile gold synthon for acetylene C-H bond activation. | Dalton transactions (Cambridge, England : 2003) 20101121 |
The influence of a 1,1-diarylvinyl moiety on the photochromism of naphthopyrans. | Organic & biomolecular chemistry 20101107 |
One-pot three-step synthesis of 1,2,3-triazoles by copper-catalyzed cycloaddition of azides with alkynes formed by a Sonogashira cross-coupling and desilylation. | Organic letters 20101105 |
Synthesis of 1,3-dialkyl-1,2,3-triazolium ionic liquids and their applications to the Baylis-Hillman reaction. | The Journal of organic chemistry 20100618 |
One-pot procedure for the synthesis of unsymmetrical diarylalkynes. | The Journal of organic chemistry 20100521 |
Meldrum's acids and 5-alkylidene Meldrum's acids in catalytic carbon-carbon bond-forming processes. | Accounts of chemical research 20100316 |
Diastereoselective synthesis of syn-1,3-diols by titanium-mediated reductive coupling of propargylic alcohols. | Organic letters 20100115 |
Conjugated polymer nanoparticles for effective siRNA delivery to tobacco BY-2 protoplasts. | BMC plant biology 20100101 |
Isolated monomeric and dimeric mixed diorganocuprates based on the size-controllable bulky 'rind' ligands. | Journal of the American Chemical Society 20091223 |
New synthesis of (11Z,13Z)-11,13-hexadecadienal, the female sex pheromone of the navel orangeworm. | Bioscience, biotechnology, and biochemistry 20091201 |
3,3'-Anisyl-substituted BINOL, H(4)BINOL, and H(8)BINOL ligands: asymmetric synthesis of diverse propargylic alcohols and their ring-closing metathesis to chiral cycloalkenes. | The Journal of organic chemistry 20091120 |
Enantioselective rhodium-catalyzed conjugate alkynylation of 5-benzylidene Meldrum's acids with TMS-acetylene. | Journal of the American Chemical Society 20091021 |
Enantioselective nucleophilic addition of trimethylsilylacetylene to n-phosphinoylimines promoted by C(2)-symmetric proline-derived beta-amino alcohol. | The Journal of organic chemistry 20090918 |
First total synthesis and antiprotozoal activity of (Z)-17-methyl-13-octadecenoic acid, a new marine fatty acid from the sponge Polymastia penicillus. | Chemistry and physics of lipids 20090901 |
Synthesis of vinylcycloheptadienes by the nickel-catalyzed three-component [3 + 2 + 2] cocyclization. Application to the synthesis of polycyclic compounds. | The Journal of organic chemistry 20090501 |
Inhibition of androstenediol-dependent LNCaP tumour growth by 17alpha-ethynyl-5alpha-androstane-3alpha, 17beta-diol (HE3235). | British journal of cancer 20090407 |
Chemicals possessing a neurotrophin-like activity on dopaminergic neurons in primary culture. | PloS one 20090101 |
Synthesis of functional cubes from octavinylsilsesquioxane (OVS). | Organic & biomolecular chemistry 20081221 |
Wiring terpyridine: approaches to alkynylthienyl 2,2':6',2''-terpyridines. | Dalton transactions (Cambridge, England : 2003) 20081221 |
Enantioselective syntheses of carbanucleosides from the Pauson-Khand adduct of trimethylsilylacetylene and norbornadiene. | Organic letters 20081016 |
A spectroscopic study of self-assembled monolayer of porphyrin-functionalized oligo(phenyleneethynylene)s on gold: the influence of the anchor moiety. | Physical chemistry chemical physics : PCCP 20080914 |
Methyl 4-(trimethyl-silylethyn-yl)benzoate. | Acta crystallographica. Section E, Structure reports online 20080601 |
Highly diastereoselective Friedel-Crafts alkylation reactions via chiral alpha-functionalized benzylic carbocations. | Chemistry, an Asian journal 20080201 |
4-(9-Anthryl)-2-methylbutyn-2-ol. | Acta crystallographica. Section E, Structure reports online 20080201 |
Shape-persistent macrocycles with intraannular alkyl groups: some structural limits of discotic liquid crystals with an inverted structure. | Beilstein journal of organic chemistry 20080101 |
Facile synthesis of two diastereomeric indolizidines corresponding to the postulated structure of alkaloid 5,9E-259B from a Bufonid toad (Melanophryniscus). | Beilstein journal of organic chemistry 20080101 |
Bis(1-tosyl-2-pyrrol-yl)ethyne. | Acta crystallographica. Section E, Structure reports online 20080101 |
Dibenzyl 3,3',4,4'-tetra-methyl-5,5'-(ethynedi-yl)bis-(pyrrole-2-carboxyl-ate). | Acta crystallographica. Section E, Structure reports online 20080101 |
Selective bromination of perylene diimides under mild conditions. | The Journal of organic chemistry 20070803 |
5-alkynyl analogs of arabinouridine and 2'-deoxyuridine: cytostatic activity against herpes simplex virus and varicella-zoster thymidine kinase gene-transfected cells. | Journal of medicinal chemistry 20070614 |
Synthesis of 10-nm scale oligothiophene molecular wires bearing anchor units at both terminal positions. | The Journal of organic chemistry 20070330 |
First total syntheses of (Z)-15-methyl-10-hexadecenoic acid and the (Z)-13-methyl-8-tetradecenoic acid. | Chemistry and physics of lipids 20070101 |
Flexible synthetic routes to poison-frog alkaloids of the 5,8-disubstituted indolizidine-class I: synthesis of common lactam chiral building blocks and application to the synthesis of (-)-203A, (-)-205A, and (-)-219F. | Beilstein journal of organic chemistry 20070101 |
Flexible synthesis of poison-frog alkaloids of the 5,8-disubstituted indolizidine-class. II: Synthesis of (-)-209B, (-)-231C, (-)-233D, (-)-235B', (-)-221I, and an epimer of 193E and pharmacological effects at neuronal nicotinic acetylcholine receptors. | Beilstein journal of organic chemistry 20070101 |
Preparation and characterization of a family of Ru2 compounds bearing iodo/ethynyl substituents on the periphery. | Inorganic chemistry 20061002 |
One-shot double elimination process: a practical and concise protocol for diaryl acetylenes. | Chemistry, an Asian journal 20060918 |
Asymmetric synthesis of alpha,alpha-dibranched propargylamines by acetylide additions to N-tert-butanesulfinyl ketimines. | The Journal of organic chemistry 20060901 |
Chromene chromium carbene complexes in the syntheses of naphthopyran and naphthopyrandione units present in photochromic materials and biologically active natural products. | Journal of the American Chemical Society 20060830 |
Synthesis of alpha-amino acids by reaction of aziridine-2-carboxylic acids with carbon nucleophiles. | Organic & biomolecular chemistry 20060807 |
Total syntheses of (+)-1893B and its three diastereomers and evaluation of their biological activities. | The Journal of antibiotics 20060801 |
A stable silaborene: synthesis and characterization. | Journal of the American Chemical Society 20060118 |
Convergent synthesis of 10 nm aryleneethynylene molecular wires by an iterative regioselective deprotection/Sonogashira coupling protocol. | The Journal of organic chemistry 20060106 |
Homoleptic trimethylsilylacetylide complexes of chromium(III), iron(II), and cobalt(III): syntheses, structures, and ligand field parameters. | Inorganic chemistry 20051114 |
Probing the intermediates of halogen addition to alkynes: bridged halonium versus open halovinyl cation; a theoretical study. | The Journal of organic chemistry 20051111 |
Concise and practical synthesis of C-glycosyl ketones from sugar benzothiazoles and their transformation into chiral tertiary alcohols. | The Journal of organic chemistry 20051111 |
On the utility of the azido transfer protocol: synthesis of 2- and 5-azido N-methylimidazoles, 1,3-thiazoles and N-methylpyrazole and their conversion to triazole-azole bisheteroaryls. | Organic & biomolecular chemistry 20050421 |
Intramolecular Pauson-Khand reactions of methylenecyclopropane and bicyclopropylidene derivatives as an approach to spiro(cyclopropanebicyclo[n.3.0]alkenones). | Chemistry (Weinheim an der Bergstrasse, Germany) 20050408 |
Synthesis of 5-ethynyl-2'-deoxyuridine-5'-boranomono phosphate as a potential thymidylate synthase inhibitor. | Nucleosides, nucleotides & nucleic acids 20050101 |
Trapping evidence for the thermal cyclization of di-(o-acetylphenyl)acetylene to 3,3'-dimethyl-1,1'-biisobenzofuran. | Beilstein journal of organic chemistry 20050101 |
Practical highly enantioselective synthesis of terminal propargylamines. An expeditious synthesis of (S)-(+)-coniine. | Chemical communications (Cambridge, England) 20041021 |
Stereoselective synthesis of sugar-modified enyne analogues of adenosine and uridine. Interaction with S-adenosyl-L-homocysteine hydrolase and antiviral and cytotoxic effects. | Journal of medicinal chemistry 20041007 |
Catalytic enantioselective conjugate addition of trimethylsilylacetylene to 2-cyclohexen-1-one. | Organic letters 20040916 |
Synthesis of porphyrins bearing hydrocarbon tethers and facile covalent attachment to si(100). | The Journal of organic chemistry 20040820 |
A copper- and amine-free sonogashira reaction employing aminophosphines as ligands. | The Journal of organic chemistry 20040806 |
Iridium-catalyzed coupling of simple primary or secondary amines, aldehydes and trimethylsilylacetylene: preparation of propargylic amines. | Chemical communications (Cambridge, England) 20040721 |
Triplet diphenylcarbenes protected by (trimethylsilyl)ethynyl groups. | The Journal of organic chemistry 20040611 |
Elaboration of diaryl ketones into naphthalenes fused on two or four sides: a naphthoannulation procedure. | Journal of the American Chemical Society 20040317 |
NMR chemical shifts. Substituted acetylenes. | The Journal of organic chemistry 20040220 |
Synthesis and characterization of bis(S-acetylthio)-derivatized europium triple-decker monomers and oligomers. | Inorganic chemistry 20031117 |
Enantiospecific synthesis of the phospholipase A2 inhibitors (-)-cinatrin C1 and (+)-cinatrin C3. | Organic & biomolecular chemistry 20031021 |
New entry to a three-component pyrimidine synthesis by TMS-Ynones via Sonogashira coupling. | Organic letters 20030918 |
Synthesis and structural characterization of porphyrinic enediynes: geometric and electronic effects on thermal and photochemical reactivity. | Inorganic chemistry 20030825 |
A molecular approach to self-assembly of trimethylsilylacetylene derivatives on gold. | Chemistry (Weinheim an der Bergstrasse, Germany) 20030606 |
Synthesis of poly(aryleneethynylene)s bearing glucose units as substituents. | Chemical communications (Cambridge, England) 20030107 |
Linchpin construction of unsymmetrical 1,4-alkynediols. | The Journal of organic chemistry 20021115 |
Enantiospecific synthesis of the phospholipase A2 inhibitor (-)-cinatrin B. | The Journal of organic chemistry 20020628 |
Cyclic tetraselenadiynes: rigid cycles with long-range van der Waals forces between chalcogen centers. | The Journal of organic chemistry 20020614 |
Trimethylsilylethynyl ketones as surrogates for ethynyl ketones in the double Michael reaction. | The Journal of organic chemistry 20020503 |
Direct addition of TMS-acetylene to aldimines catalyzed by a simple, commercially available Ir(I) complex. | Organic letters 20011227 |
Synthesis of meso-substituted chlorins via tetrahydrobilene-a intermediates. | The Journal of organic chemistry 20011102 |
Rapid homogeneous-phase Sonogashira coupling reactions using controlled microwave heating. | The Journal of organic chemistry 20010615 |
GaCl3-promoted ethenylation of silylated beta-dicarbonyl compound with silylethyne. Synthesis of ethenylmalonate. | Organic letters 20010308 |
Highly regioselective cyclotrimerization of 1-perfluoroalkylenynes catalyzed by nickel. | The Journal of organic chemistry 20010209 |