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(Triisopropylsilyl)acetylene

CAS No.:
89343-06-6
Catalog Number:
AG0034XD
Molecular Formula:
C11H22Si
Molecular Weight:
182.3779
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
1g
97%
In Stock USA
United States
$13
- +
5g
97%
In Stock USA
United States
$30
- +
25g
97%
In Stock USA
United States
$112
- +
100g
97%
In Stock USA
United States
$344
- +
500g
97%
In Stock USA
United States
$1369
- +
Product Description
Catalog Number:
AG0034XD
Chemical Name:
(Triisopropylsilyl)acetylene
CAS Number:
89343-06-6
Molecular Formula:
C11H22Si
Molecular Weight:
182.3779
MDL Number:
MFCD00075452
IUPAC Name:
ethynyl-tri(propan-2-yl)silane
InChI:
InChI=1S/C11H22Si/c1-8-12(9(2)3,10(4)5)11(6)7/h1,9-11H,2-7H3
InChI Key:
KZGWPHUWNWRTEP-UHFFFAOYSA-N
SMILES:
CC([Si](C(C)C)(C(C)C)C#C)C
Properties
Complexity:
159  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
182.149g/mol
Formal Charge:
0
Heavy Atom Count:
12  
Hydrogen Bond Acceptor Count:
0
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
182.382g/mol
Monoisotopic Mass:
182.149g/mol
Rotatable Bond Count:
4  
Topological Polar Surface Area:
0A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
Literature
Title Journal
Substituent effects on the electronic characteristics of pentacene derivatives for organic electronic devices: dioxolane-substituted pentacene derivatives with triisopropylsilylethynyl functional groups. Journal of the American Chemical Society 20120829
Unexpected formation of a cyclic vinylene sulfate in the synthesis of ethynyl-substituted acenes. Chemical communications (Cambridge, England) 20120707
Highly chemoselective nickel-catalyzed three-component cross-trimerization between two distinct terminal alkynes and an internal alkyne. Organic letters 20110107
Rhodium-catalyzed asymmetric conjugate alkynylation of nitroalkenes. Chemical communications (Cambridge, England) 20100928
A stable heptacene derivative substituted with electron-deficient trifluoromethylphenyl and triisopropylsilylethynyl groups. Organic letters 20100806
(Butane-1,3-diyne-1,4-diyl)bis-(tri-isopropyl-silane). Acta crystallographica. Section E, Structure reports online 20100801
Efficient preparation of photoswitchable dithienylethene-linker-conjugates by palladium-catalyzed coupling reactions of terminal alkynes with thienyl chlorides and other aryl halides. Chemistry, an Asian journal 20100503
Electronic properties of pentacene versus triisopropylsilylethynyl-substituted pentacene: environment-dependent effects of the silyl substituent. Journal of the American Chemical Society 20100120
Nickel-catalyzed, regio- and stereoselective hydroalkynylation of methylenecyclopropanes with retention of the cyclopropane ring, leading to the synthesis of 1-methyl-1-alkynylcyclopropanes. Journal of the American Chemical Society 20090415
Nickel-catalyzed highly regio- and stereoselective cross-trimerization between triisopropylsilylacetylene and internal alkynes leading to 1,3-diene-5-ynes. Journal of the American Chemical Society 20090311
Nickel-catalyzed regioselective hydroalkynylation of styrenes: improved catalyst system, reaction scope, and mechanism. Organic letters 20090205
Wiring terpyridine: approaches to alkynylthienyl 2,2':6',2''-terpyridines. Dalton transactions (Cambridge, England : 2003) 20081221
Rhodium-catalyzed asymmetric ring-opening alkynylation of azabenzonorbornadienes. Organic letters 20080918
Rhodium-catalyzed (E)-selective cross-dimerization of terminal alkynes. Chemical communications (Cambridge, England) 20080807
Nickel-catalyzed addition of C-H bonds of terminal alkynes to 1,3-dienes and styrenes. Journal of the American Chemical Society 20080423
Synthesis of highly soluble and oxidatively stable tetraceno[2,3-b]thiophenes and pentacenes. The Journal of organic chemistry 20070817
Palladium-catalyzed selective cross-addition of triisopropylsilylacetylene to internal and terminal unactivated alkynes. Organic letters 20070719
Synthetic chlorins bearing auxochromes at the 3- and 13-positions. The Journal of organic chemistry 20060526
Structurally characterized hetero-oligopolyphenylenes: synthetic advances toward next-generation heterosuperbenzenes. Chemistry (Weinheim an der Bergstrasse, Germany) 20060403
Properties