Ethyl Diazoacetate
Title | Journal |
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BOROX catalysis: self-assembled amino-BOROX and imino-BOROX chiral Brønsted acids in a five component catalyst assembly/catalytic asymmetric aziridination. | The Journal of organic chemistry 20120921 |
Chromatographic examination of the chemical composition and sequence distribution of copolymers from ethyl and benzyl diazoacetate. | Journal of chromatography. A 20120914 |
Intramolecular cycloaddition of azomethine ylides, from imines of O-acylsalicylic aldehyde and ethyl diazoacetate, to ester carbonyl--experimental and DFT computational study. | Organic & biomolecular chemistry 20120807 |
Development of the enantioselective addition of ethyl diazoacetate to aldehydes: asymmetric synthesis of 1,2-diols. | Journal of the American Chemical Society 20120201 |
Stable N-heterocyclic carbene (NHC)-palladium(0) complexes as active catalysts for olefin cyclopropanation reactions with ethyl diazoacetate. | Chemistry (Weinheim an der Bergstrasse, Germany) 20111223 |
Asymmetric cycloaddition reactions of diazoesters with 2-alkenoic acid derivatives catalyzed by binaphthyldiimine-Ni(II) complexes. | The Journal of organic chemistry 20110916 |
Exploring the synthetic versatility of the Lewis acid induced decomposition reaction of α-diazo-β-hydroxy esters. The case of ethyl diazo(3-hydroxy-2-oxo-2,3-dihydro-1H-indol-3-yl)acetate. | The Journal of organic chemistry 20110916 |
Silver-catalyzed C-C bond formation between methane and ethyl diazoacetate in supercritical CO₂. | Science (New York, N.Y.) 20110513 |
Cobalt-mediated selective B-H activation and formation of a Co-B bond in the reaction of the 16-electron CpCo half-sandwich complex containing an o-carborane-1,2-dithiolate ligand with ethyl diazoacetate. | Inorganic chemistry 20110502 |
Highly cis-selective Rh(I)-catalyzed cyclopropanation reactions. | The Journal of organic chemistry 20110415 |
Cu(I) complexes containing a multidentate and conformationally flexible dibenzylidene acetone ligand (dbathiophos): application in catalytic alkene cyclopropanation. | Dalton transactions (Cambridge, England : 2003) 20110414 |
Bimetallic catalysis involving dipalladium(I) and diruthenium(I) complexes. | Chemistry (Weinheim an der Bergstrasse, Germany) 20101227 |
Synthesis of β-keto esters in-flow and rapid access to substituted pyrimidines. | The Journal of organic chemistry 20101217 |
Iron-catalyzed synthesis of glycine derivatives via carbon-nitrogen bond cleavage using diazoacetate. | Chemical communications (Cambridge, England) 20101214 |
Readily accessible bicyclononynes for bioorthogonal labeling and three-dimensional imaging of living cells. | Angewandte Chemie (International ed. in English) 20101203 |
Tin(II) chloride assisted synthesis of N-protected γ-amino β-keto esters through semipinacol rearrangement. | Organic & biomolecular chemistry 20101107 |
'Carbene radicals' in Co(II)(por)-catalyzed olefin cyclopropanation. | Journal of the American Chemical Society 20100811 |
Iridium compounds with kappa-P,P,Si (biPSi) pincer ligands: favoring reactive structures in unsaturated complexes. | Journal of the American Chemical Society 20100707 |
Computational study of cyclopropanation reactions with halodiazoacetates. | The Journal of organic chemistry 20100402 |
Synthesis of Biginelli dihydropyrimidinone derivatives with various substituents on aluminium-planted mesoporous silica catalyst. | Organic & biomolecular chemistry 20100307 |
An efficient and convenient synthesis of ethyl 1-(4-methoxyphenyl)-5-phenyl-1H-1,2,3-triazole-4-carboxylate. | Chemistry, an Asian journal 20100201 |
Component match in rhodium catalyzed three-component reactions of ethyl diazoacetate, H2O and aryl imines: a highly diastereoselective one-step synthesis of beta-aryl isoserine derivatives. | Organic & biomolecular chemistry 20091207 |
Synthesis of [n,5]-spiroketals by ring enlargement of donor-acceptor-substituted cyclopropane derivatives. | The Journal of organic chemistry 20091120 |
Efficient method for the synthesis of functionalized pyrazoles by catalyst-free one-pot tandem reaction of nitroalkenes with ethyl diazoacetate. | Organic & biomolecular chemistry 20091107 |
Rhodium-catalyzed synthesis of 3-hydroxy-beta-lactams via oxonium ylide generation: three-component reaction between azetidine-2,3-diones, ethyl diazoacetate, and alcohols. | The Journal of organic chemistry 20091106 |
Evidence for a boroxinate based Brønsted acid derivative of VAPOL as the active catalyst in the catalytic asymmetric aziridination reaction. | Journal of the American Chemical Society 20091104 |
Tandem asymmetric Aza-Darzens/ring-opening reactions: dual functionality from the silane lewis acid. | Journal of the American Chemical Society 20091021 |
Organocatalytic aziridine synthesis using F+ salts. | Organic letters 20091015 |
Catalytic enantioselective 1,3-dipolar cycloadditions of alkyl diazoacetates with alpha,beta-disubstituted acroleins. | Chemical communications (Cambridge, England) 20090928 |
Highly active gold-based catalyst for the reaction of benzaldehyde with ethyl diazoacetate. | Chemical communications (Cambridge, England) 20090914 |
Palladium(II) carboxylates and palladium(I) carbonyl carboxylate complexes as catalysts for olefin cyclopropanation with ethyl diazoacetate. | Dalton transactions (Cambridge, England : 2003) 20090907 |
Formal aromatic C-H insertion for stereoselective isoquinolinone synthesis and studies on mechanistic insights into the C-C bond formation. | The Journal of organic chemistry 20090821 |
Enantioselective aza-Darzens reaction catalyzed by a chiral phosphoric acid. | Organic letters 20090604 |
Platinum(II) tetramesityltetraphosphane-1,4-diides. | Dalton transactions (Cambridge, England : 2003) 20090428 |
Synthesis, transformations, and comparative studies of porphyryl acrylic acids and their homologues. | The Journal of organic chemistry 20090220 |
Magnesium-catalyzed asymmetric direct aldol addition of ethyl diazoacetate to aromatic, aliphatic, and alpha,beta-unsaturated aldehydes. | Journal of the American Chemical Society 20090211 |
Highly cis-selective cyclopropanations with ethyl diazoacetate using a novel Rh(I) catalyst with a chelating N-heterocyclic iminocarbene ligand. | Organic letters 20090205 |
Unusually reactive and selective carbonyl ylides for three-component cycloaddition reactions. | Journal of the American Chemical Society 20090128 |
Reactions of diazo compounds with alkenes catalysed by [RuCl(cod)(Cp)]: effect of the substituents in the formation of cyclopropanation or metathesis products. | Chemistry (Weinheim an der Bergstrasse, Germany) 20090101 |
A simple one-pot preparation of diazoacetoacetate derivatives from aldehydes. | The Journal of organic chemistry 20081107 |
Highly efficient formation of halodiazoacetates and their use in stereoselective synthesis of halocyclopropanes. | Organic & biomolecular chemistry 20081021 |
1,3-Dipolar cycloadditions of acetylenic sulfones in solution and on solid supports. | The Journal of organic chemistry 20081017 |
Synthesis of indoles via domino reaction of N-aryl amides and ethyl diazoacetate. | Journal of the American Chemical Society 20081015 |
Synthesis of substituted 6-cyclopropylpurine bases and nucleosides by cross-coupling reactions or cyclopropanations. | Organic & biomolecular chemistry 20080707 |
Synthesis of stable derivatives of cycloprop-2-ene carboxylic acid. | The Journal of organic chemistry 20080606 |
Gold(I) ethylene and copper(I) ethylene complexes supported by a polyhalogenated triazapentadienyl ligand. | Inorganic chemistry 20080602 |
Modularly designed transition metal PNP and PCP pincer complexes based on aminophosphines: synthesis and catalytic applications. | Accounts of chemical research 20080201 |
Catalytic asymmetric aziridination with borate catalysts derived from VANOL and VAPOL ligands: scope and mechanistic studies. | Chemistry (Weinheim an der Bergstrasse, Germany) 20080101 |
Selective C-C coupling of Ir-ethene and Ir-carbenoid radicals. | Chemistry (Weinheim an der Bergstrasse, Germany) 20080101 |
A simple and efficient approach to the synthesis of endo and exo bicyclo[6.1.0]nona-3,5-diene-9-carboxaldehyde. | Molecules (Basel, Switzerland) 20071030 |
Ph3As-catalyzed wittig-type olefination of aldehydes with diazoacetate in the presence of Na2S2O4. | The Journal of organic chemistry 20070817 |
Palladium-catalyzed cross-coupling of aryl or vinyl iodides with ethyl diazoacetate. | Journal of the American Chemical Society 20070718 |
Mo and W dihalide complexes with uncommon trigonal-prismatic geometry imposed by the linear tetraphosphine ancillary ligand and their reactivities toward diazoalkanes. | Inorganic chemistry 20070611 |
Direct access to N-H-aziridines from asymmetric catalytic aziridination with borate catalysts derived from vaulted binaphthol and vaulted biphenanthrol ligands. | Journal of the American Chemical Society 20070606 |
BH3-catalyzed oligomerization of ethyl diazoacetate: the role of C-boron enolates. | Journal of the American Chemical Society 20070425 |
Structure and reaction mechanism of basil eugenol synthase. | PloS one 20070101 |
Alkene cyclopropanation catalyzed by Halterman iron porphyrin: participation of organic bases as axial ligands. | Dalton transactions (Cambridge, England : 2003) 20061028 |
9-{[3-fluoro-2-(hydroxymethyl)cyclopropylidene]methyl}adenines and -guanines. Synthesis and antiviral activity of all stereoisomers1. | Journal of medicinal chemistry 20061005 |
Rhodium-mediated stereoselective polymerization of 'carbenes'. | Journal of the American Chemical Society 20060802 |
Trace level detection and quantitation of ethyl diazoacetate by reversed-phase high performance liquid chromatography and UV detection. | Journal of pharmaceutical and biomedical analysis 20060607 |
A non-fluorous copper catalyst for the styrene cyclopropanation reaction in a fluorous medium. | Chemical communications (Cambridge, England) 20060307 |
Very efficient, reusable copper catalyst for carbene transfer reactions under biphasic conditions using ionic liquids. | Organic letters 20060216 |
Unprecedented stereoselective synthesis of catalytically active chiral Mo3CuS4 clusters. | Chemistry (Weinheim an der Bergstrasse, Germany) 20060201 |
Chiral organometallic triangles with Rh-Rh bonds. 2. Compounds prepared from enantiopure cis-Rh2(C6H4PPh2)2(OAc)2(HOAc)2 and their catalytic potentials. | Inorganic chemistry 20051114 |
Catalysis of enantioselective [2+1]-cycloaddition reactions of ethyl diazoacetate and terminal acetylenes using mixed-ligand complexes of the series Rh2(RCO2)n(L*4-n). Stereochemical heuristics for ligand exchange and catalyst synthesis. | Journal of the American Chemical Society 20051019 |
Steric and electronic tuning of chiral bis(oxazoline) ligands with 3,3'-bithiophene backbone. | The Journal of organic chemistry 20050916 |
A gold catalyst for carbene-transfer reactions from ethyl diazoacetate. | Angewandte Chemie (International ed. in English) 20050819 |
Copper-catalyzed addition of ethyl diazoacetate to furans: an alternative to dirhodium(II) tetraacetate. | The Journal of organic chemistry 20050722 |
A flexible and versatile strategy for the covalent immobilization of chiral catalysts based on pyridinebis(oxazoline) ligands. | The Journal of organic chemistry 20050708 |
Reaction kinetics and critical phenomena: rates of some first order gas evolution reactions in binary solvents with a consolute point. | The journal of physical chemistry. A 20050602 |
Novel ozone-mediated cleavage of the benzhydryl protecting group from aziridinyl esters. | Organic letters 20050526 |
Mechanism and origin of enantioselectivity in the Rh2(OAc)(DPTI)3-catalyzed cyclopropenation of alkynes. | Journal of the American Chemical Society 20050504 |
Surface-catalyzed growth of polymethylene-rich copolymer films on gold. | Journal of the American Chemical Society 20050309 |
Enantio- and diastereocontrol in intermolecular cyclopropanation reaction of styrene catalyzed by dirhodium(II) complexes with bulky ortho-metalated aryl phosphines. | Chemical communications (Cambridge, England) 20041107 |
Acid-catalyzed reactions of aromatic aldehydes with ethyl diazoacetate: an investigation on the synthesis of 3-hydroxy-2-arylacrylic acid ethyl esters. | The Journal of organic chemistry 20041029 |
Ruthenium porphyrin catalyzed tandem sulfonium/ammonium ylide formation and [2,3]-sigmatropic rearrangement. A concise synthesis of (+/-)-platynecine. | The Journal of organic chemistry 20041015 |
Complete control of the chemoselectivity in catalytic carbene transfer reactions from ethyl diazoacetate: an N-heterocyclic carbene-Cu system that suppresses diazo coupling. | Journal of the American Chemical Society 20040908 |
Group 11 metal complexes of SPS-based pincer ligands: syntheses, X-ray structures and reactivity. | Dalton transactions (Cambridge, England : 2003) 20040821 |
A new chiral Rh(II) catalyst for enantioselective [2 + 1]-cycloaddition. mechanistic implications and applications. | Journal of the American Chemical Society 20040728 |
Automated structure elucidation of two unexpected products in a reaction of an alpha,beta-unsaturated pyruvate. | Magnetic resonance in chemistry : MRC 20040701 |
The role of binding constants in the efficiency of chiral catalysts immobilized by electrostatic interactions: the case of azabis(oxazoline)-copper complexes. | Chemistry (Weinheim an der Bergstrasse, Germany) 20040621 |
Vitamin B12 derivatives as natural asymmetric catalysts: enantioselective cyclopropanation of alkenes. | The Journal of organic chemistry 20040402 |
Nitrosation of glycine ethyl ester and ethyl diazoacetate to give the alkylating agent and mutagen ethyl chloro(hydroximino)acetate. | Chemical research in toxicology 20040301 |
Synthesis and antiviral activity of monofluorinated cyclopropanoid nucleosides. | Organic & biomolecular chemistry 20040121 |
Isotope effects and the nature of selectivity in rhodium-catalyzed cyclopropanations. | Journal of the American Chemical Society 20031224 |
Monomeric rhodium(II) catalysts for the preparation of aziridines and enantioselective formation of cyclopropanes from ethyl diazoacetate at room temperature. | The Journal of organic chemistry 20031212 |
Diastereoselective and enantioselective cyclopropanation of alkenes catalyzed by cobalt porphyrins. | The Journal of organic chemistry 20031017 |
Electronically tuned chiral ruthenium porphyrins: extremely stable and selective catalysts for asymmetric epoxidation and cyclopropanation. | Chemistry (Weinheim an der Bergstrasse, Germany) 20031006 |
Activation of alkyl halides via a silver-catalyzed carbene insertion process. | Journal of the American Chemical Society 20030806 |
Acid-promoted olefination of ketones by an iron(III) porphyrin complex. | Organic letters 20030710 |
Synthesis, molecular structure, and C-C coupling reactions of carbeneruthenium(II) complexes with C5H5Ru(=CRR') and C5Me5Ru(=CRR') as molecular units. | Chemistry (Weinheim an der Bergstrasse, Germany) 20030606 |
Generation of phosphoranes derived from phosphites. A new class of phosphorus ylides leading to high E selectivity with semi-stabilizing groups in Wittig olefinations. | Journal of the American Chemical Society 20030521 |
Copper(II)-catalyzed [2,3]-sigmatropic rearrangement of N-methyltetrahydropyridinium ylids. | The Journal of organic chemistry 20030516 |
Iron(III) and ruthenium(II) porphyrin complex-catalyzed selective olefination of aldehydes with ethyl diazoacetate. | The Journal of organic chemistry 20030502 |
Direct catalytic asymmetric aldol-type reaction of aldehydes with ethyl diazoacetate. | Organic letters 20030501 |
Highly regioselective functionalization of aliphatic carbon-hydrogen bonds with a perbromohomoscorpionate copper(I) catalyst. | Journal of the American Chemical Society 20030212 |
Transition metal-catalyzed cyclopropanation of alkenes in water: catalyst efficiency and in situ generation of the diazo reagent. | Organic letters 20021212 |
Remarkably stable iron porphyrins bearing nonheteroatom-stabilized carbene or (alkoxycarbonyl)carbenes: isolation, X-ray crystal structures, and carbon atom transfer reactions with hydrocarbons. | Journal of the American Chemical Society 20021106 |
The first immobilization of pyridine-bis(oxazoline) chiral ligands. | Organic letters 20021031 |
Improvement of ligand economy controlled by polymer morphology: the case of polymer-supported bis(oxazoline) catalysts. | Bioorganic & medicinal chemistry letters 20020722 |
The [2 + 1] and [4 + 3] cyclization reactions of fulvenes with Fischer carbene complexes: new access to annulated cyclopentanones. | Journal of the American Chemical Society 20020529 |
Dendritic ruthenium porphyrins: a new class of highly selective catalysts for alkene epoxidation and cyclopropanation. | Chemistry (Weinheim an der Bergstrasse, Germany) 20020402 |
The first enantiomerically pure [n]triangulanes and analogues: sigma-[n]helicenes with remarkable features. | Chemistry (Weinheim an der Bergstrasse, Germany) 20020215 |
Copper(I)-homoscorpionate catalysts for the preferential, kinetically controlled cis cyclopropanation of alpha-olefins with ethyl diazoacetate. | Journal of the American Chemical Society 20020213 |
A new and efficient method for the selective olefination of aldehydes with ethyl diazoacetate catalyzed by an iron(II) porphyrin complex. | Journal of the American Chemical Society 20020116 |
Asymmetric cyclopropanation catalyzed by a series of copper-(Schiff-base) complexes with two chiral centers. | Enantiomer 20020101 |
Bis(oxazoline)copper complexes covalently bonded to insoluble support as catalysts in cyclopropanation reactions. | The Journal of organic chemistry 20011228 |
Reactivity of 2-methylene-1,3-dicarbonyl compounds. 1,3-dipolar cycloaddition reaction with ethyl diazoacetate. | Chemical & pharmaceutical bulletin 20011201 |
Catalytic asymmetric cyclopropanation of heteroaryldiazoacetates. | The Journal of organic chemistry 20011005 |
A family of highly active copper(I)-homoscorpionate catalysts for the alkyne cyclopropenation reaction. | Chemical communications (Cambridge, England) 20010921 |
1,2-aryl and 1,2-hydride migration in transition metal complex catalyzed diazo decomposition: a novel approach to alpha-aryl-beta-enamino esters. | Organic letters 20010920 |
Bidentate carbenoid ester coordination in ruthenium(II) Schiff-base complexes leading to excellent levels of diastereo- and enantioselectivity in catalytic alkene cyclopropanation. | Chemical communications (Cambridge, England) 20010907 |
Asymmetric inter- and intramolecular cyclopropanation of alkenes catalyzed by chiral ruthenium porphyrins. Synthesis and crystal structure of a chiral metalloporphyrin carbene complex. | Journal of the American Chemical Society 20010509 |