Home Halogens Diethylaminosulfur trifluoride

Diethylaminosulfur trifluoride

CAS No.:
38078-09-0
Catalog Number:
AG0034QI
Molecular Formula:
C4H10F3NS
Molecular Weight:
161.1891
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
Product Description
Catalog Number:
AG0034QI
Chemical Name:
Diethylaminosulfur trifluoride
CAS Number:
38078-09-0
Molecular Formula:
C4H10F3NS
Molecular Weight:
161.1891
IUPAC Name:
N-ethyl-N-(trifluoro-λ4-sulfanyl)ethanamine
InChI:
InChI=1S/C4H10F3NS/c1-3-8(4-2)9(5,6)7/h3-4H2,1-2H3
InChI Key:
CSJLBAMHHLJAAS-UHFFFAOYSA-N
SMILES:
CCN(S(F)(F)F)CC
EC Number:
253-771-2
UNII:
78622BV6IJ
Properties
Complexity:
78.4  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
161.049g/mol
Formal Charge:
0
Heavy Atom Count:
9  
Hydrogen Bond Acceptor Count:
5  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
161.186g/mol
Monoisotopic Mass:
161.049g/mol
Rotatable Bond Count:
2  
Topological Polar Surface Area:
4.2A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
3.5  
Literature
Title Journal
Solid-phase chemical synthesis and in vitro biological evaluation of novel 2β-piperazino-(20R)-5α-pregnane-3α,20-diol N-derivatives as anti-leukemic agents. Steroids 20121101
An improved method for the synthesis of protected glycosyl fluorides from thioglycosides using N,N-diethylaminosulfur trifluoride (DAST). Carbohydrate research 20121001
Ring expansion of cyclic β-amino alcohols induced by diethylaminosulfur trifluoride: synthesis of cyclic amines with a tertiary fluorine at C3. The Journal of organic chemistry 20120720
Skeletal rearrangements resulting from reactions of 1,6:2,3- and 1,6:3,4-dianhydro-β-D-hexopyranoses with diethylaminosulphur trifluoride. Organic & biomolecular chemistry 20120114
(1S*,3S*,8S*,10S*)-10-Fluoro-15-oxa-tetra-cyclo-[6.6.1.0.0]penta-deca-5,12-dien-3-ol. Acta crystallographica. Section E, Structure reports online 20110801
Synthesis and anti-HIV-1 activity of new fluoro-HEPT analogues: an investigation on fluoro versus hydroxy substituents. Archiv der Pharmazie 20110601
m-Carborane-based chiral NBN pincer-metal complexes: synthesis, structure, and application in asymmetric catalysis. Inorganic chemistry 20110502
DAST-mediated cyclization of α,α-disubstituted-α-acylaminoketones: efficient and divergent synthesis of unprecedented heterocycles. Organic letters 20110121
Enantioselective synthesis of β-fluoroamines from β-amino alcohols: application to the synthesis of LY503430. Organic letters 20101015
Aminodifluorosulfinium salts: selective fluorination reagents with enhanced thermal stability and ease of handling. The Journal of organic chemistry 20100521
First principles insight into the alpha-glucan structures of starch: their synthesis, conformation, and hydration. Chemical reviews 20100414
Synthesis and anti-HIV-1 activity of 1-substiuted 6-(3-cyanobenzoyl) and [(3-cyanophenyl)fluoromethyl]-5-ethyl-uracils. Archiv der Pharmazie 20090901
DAST-mediated regioselective anomeric group migration in saccharides. The Journal of organic chemistry 20090605
Synthesis of 1,1-Dioxobenzo[b]thiophene-2-ylmethyloxycarbonyl (Bsmoc) protected N-methyl amino acids by reduction of Bsmoc-5-oxazoli-dinones and their use in peptide synthesis. Protein and peptide letters 20090101
Fluorination reactions in microreactors. Chemical communications (Cambridge, England) 20080714
Brassinosteroids: synthesis and activity of some fluoro analogues. Journal of medicinal chemistry 20080710
1H,13C, 19F NMR, and ESI mass spectral characterization of two geminal difluorosteroids. Magnetic resonance in chemistry : MRC 20080401
Fluorination of triptolide and its analogues and their cytotoxicity. Bioorganic & medicinal chemistry letters 20080401
Synthesis and antimicrobial activity of 7-fluoro-3-aminosteroids. Bioorganic & medicinal chemistry letters 20070915
Application of solid-phase chemistry for the synthesis of 3'-fluoro-3'-deoxythymidine. Nucleosides, nucleotides & nucleic acids 20070101
4'-Fluorinated carbocyclic nucleosides: synthesis and inhibitory activity against S-adenosyl-L-homocysteine hydrolase. Bioorganic & medicinal chemistry 20060815
Rearrangement of homoallylic alcohols induced by DAST. Organic letters 20060511
Synthesis of fluorinated analogs of myristic acid as potential inhibitors of Egyptian armyworm (Spodoptera littoralis) delta11 desaturase. Lipids 20030801
Electrophilic fluorinating reagent mediated synthesis of fluorinated alpha-keto Ethers, benzil, and 6,6'-dialkoxy-2,2'-bipyridines. The Journal of organic chemistry 20020906
Synthesis of 2'-deoxy-2'-fluoroguanyl-(3',5')-guanosine. Nucleosides, nucleotides & nucleic acids 20020101
Synthesis of 9-(2,3-dideoxy-2-fluoro-beta-D-threo-pentofuranosyl)adenine (FddA) via a purine 3'-deoxynucleoside. The Journal of organic chemistry 20011102
Synthetic explorations towards 3-deoxy-3-fluoro derivatives of D-perosamine. Carbohydrate research 20010830
Properties