Trimethylsilyl cyanide
Title | Journal |
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Enantioselective synthesis of tertiary α-hydroxy phosphonates catalyzed by carbohydrate/cinchona alkaloid thiourea organocatalysts. | Angewandte Chemie (International ed. in English) 20120827 |
Difluoro(trimethylsilyl)acetonitrile: synthesis and fluoroalkylation reactions. | The Journal of organic chemistry 20120706 |
Strategic design and refinement of Lewis acid-base catalysis by rare-earth-metal-containing polyoxometalates. | Inorganic chemistry 20120618 |
Kinetics and mechanism of the racemic addition of trimethylsilyl cyanide to aldehydes catalysed by Lewis bases. | Organic & biomolecular chemistry 20120607 |
Photoswitchable nanoparticles for triggered tissue penetration and drug delivery. | Journal of the American Chemical Society 20120530 |
Direct crystallographic observation of catalytic reactions inside the pores of a flexible coordination polymer. | Chemistry (Weinheim an der Bergstrasse, Germany) 20120529 |
o-Benzenedisulfonimide and its chiral derivative as Brønsted acids catalysts for one-pot three-component Strecker reaction. Synthetic and mechanistic aspects. | Organic & biomolecular chemistry 20120528 |
Cyanosilylation of carbonyl compounds with trimethylsilyl cyanide catalyzed by an yttrium-pillared silicotungstate dimer. | Angewandte Chemie (International ed. in English) 20120410 |
Trimeth-yl(triphenyl-meth-oxy)silane. | Acta crystallographica. Section E, Structure reports online 20120201 |
Cooperative thiourea-Brønsted acid organocatalysis: enantioselective cyanosilylation of aldehydes with TMSCN. | The Journal of organic chemistry 20111202 |
Unsymmetric salen ligands bearing a Lewis base: intramolecularly cooperative catalysis for cyanosilylation of aldehydes. | Organic & biomolecular chemistry 20110921 |
Chiral N,N'-dioxides: new ligands and organocatalysts for catalytic asymmetric reactions. | Accounts of chemical research 20110816 |
Addition of TMSCN to chiral ketimines derived from isatin. Synthesis of an oxindole-based peptidomimetic and a bioactive spirohydantoin. | Organic & biomolecular chemistry 20110807 |
Gold-complexes catalyzed oxidative α-cyanation of tertiary amines. | Chemical communications (Cambridge, England) 20110227 |
Synthesis of chiral cyclic nitrones by asymmetric addition of β-ketosulfones to nitroalkenes followed by reductive cyclization. | Chemistry (Weinheim an der Bergstrasse, Germany) 20110117 |
Detection of warfare agents in liquid foods using the brine shrimp lethality assay. | Journal of food science 20110101 |
Investigation of Lewis acid versus Lewis base catalysis in asymmetric cyanohydrin synthesis. | Chemistry (Weinheim an der Bergstrasse, Germany) 20101004 |
Acetone cyanohydrin as a source of HCN in the Cu-catalyzed hydrocyanation of alpha-aryl diazoacetates. | The Journal of organic chemistry 20100416 |
Brønsted acid-catalyzed efficient Strecker reaction of ketones, amines and trimethylsilyl cyanide. | Organic & biomolecular chemistry 20100321 |
trans-1-Phenyl-pyrrolidine-2,5-dicarbo-nitrile. | Acta crystallographica. Section E, Structure reports online 20100201 |
Lanthanide versus actinide reactivity in the formation of sterically crowded [(C(5)Me(5))(3)ML(n)] nitrile and isocyanide complexes. | Chemistry (Weinheim an der Bergstrasse, Germany) 20100118 |
Kinetics and mechanism of vanadium catalysed asymmetric cyanohydrin synthesis in propylene carbonate. | Beilstein journal of organic chemistry 20100101 |
Brønsted acid-promoted hydrocyanation of arylalkenes. | Organic letters 20091119 |
Asymmetric cyanation of aldehydes, ketones, aldimines, and ketimines catalyzed by a versatile catalyst generated from cinchona alkaloid, achiral substituted 2,2'-biphenol and tetraisopropyl titanate. | Chemistry (Weinheim an der Bergstrasse, Germany) 20091102 |
TTMPP: An efficient organocatalyst in the ring-opening of aziridines with silylated nucleophiles. | Organic & biomolecular chemistry 20090921 |
Iron catalyzed oxidative cyanation of tertiary amines. | Chemical communications (Cambridge, England) 20090907 |
(RS)-(2-Bromo-4-fluoro-anilino)[2-(4,6-dimethoxy-pyrimidin-2-yl-oxy)phen-yl]acetonitrile. | Acta crystallographica. Section E, Structure reports online 20090901 |
Nucleophilic cyclopropanation reaction with bis(iodozincio)methane by 1,4-addition to alpha,beta-unsaturated carbonyl compounds. | Chemistry, an Asian journal 20090803 |
Facile and efficient enantioselective Strecker reaction of ketimines by chiral sodium phosphate. | Chemistry (Weinheim an der Bergstrasse, Germany) 20090608 |
Cyanoesterification of 1,2-dienes catalyzed by nickel. | Journal of the American Chemical Society 20090513 |
Dimethyl 6,6'-dicyano-2,2'-bipyridine-3,3'-dicarboxyl-ate. | Acta crystallographica. Section E, Structure reports online 20090501 |
Efficient three-component Strecker reaction of aldehydes/ketones via NHC-amidate palladium(II) complex catalysis. | The Journal of organic chemistry 20090403 |
Enantioselective cyanosilylation of ketones catalyzed by recyclable polymeric and dimeric Mn(III) salen complexes at room temperature. | Chirality 20090201 |
Mechanism-guided development of VO(salen)X complexes as catalysts for the asymmetric synthesis of cyanohydrin trimethylsilyl ethers. | Chemistry (Weinheim an der Bergstrasse, Germany) 20090101 |
A tin-tungsten mixed oxide as an efficient heterogeneous catalyst for C-C bond-forming reactions. | Chemistry (Weinheim an der Bergstrasse, Germany) 20090101 |
2-(Trimethyl-siloxy)adamantane-2-carbonitrile. | Acta crystallographica. Section E, Structure reports online 20090101 |
Reactivity of the disilyne RSi[triple bond]SiR (R = Si(i)Pr[CH(SiMe3)2]2) toward silylcyanide: two pathways to form the bis-adduct [RSiSiR(CNSiMe3)2] with some silaketenimine character and a 1,4-diaza-2,3-disilabenzene analogue. | Journal of the American Chemical Society 20081217 |
First total synthesis of (5Z,9Z)-(+/-)-2-methoxy-5,9-octadecadienoic acid, a marine derived methoxylated analog of taxoleic acid. | Chemistry and physics of lipids 20081101 |
Facile preparation of alpha-aryl nitriles by direct cyanation of alcohols with TMSCN under the catalysis of InX3. | Organic letters 20081016 |
Synthesis of N-allylideneamines and their use for the double nucleophilic addition of ketene silyl (thio)acetals and trimethylsilyl cyanide. | Organic letters 20080918 |
Unexpected formation of complex bridged tetrazoles via intramolecular 1,3-dipolar cycloaddition of 1,2-O-cyanoalkylidene derivatives of 3-azido-3-deoxy-D-allose. | Carbohydrate research 20080811 |
[Development of C-C bond formation and asymmetric reactions catalyzed by N-heterocyclic carbenes]. | Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan 20080801 |
Stereoselective synthesis of novel uracil polyoxin C conjugates as substrate analogues of chitin synthase. | The Journal of organic chemistry 20080516 |
Size-selective Lewis acid catalysis in a microporous metal-organic framework with exposed Mn2+ coordination sites. | Journal of the American Chemical Society 20080507 |
A new strategy for designing non-C2-symmetric monometallic bifunctional catalysts and their application in enantioselective cyanation of aldehydes. | Chemistry (Weinheim an der Bergstrasse, Germany) 20080101 |
Dinuclear {(salen)Al} complexes display expanded scope in the conjugate cyanation of alpha,beta-unsaturated imides. | Angewandte Chemie (International ed. in English) 20080101 |
Characterisation of the substrate specificity of the nitrile hydrolyzing system of the acidotolerant black yeast Exophiala oligosperma R1. | Studies in mycology 20080101 |
2,2'-Bis(4-methoxy-phen-yl)-2,2'-bis-(tri-methyl-silan-yloxy)-2,2'-(ferrocene-1,1'-diyl)diacetonitrile. | Acta crystallographica. Section E, Structure reports online 20080101 |
Cyclosophorohexadecaose and succinoglycan monomers as catalytic carbohydrates for the Strecker reaction. | Carbohydrate research 20071210 |
Efficient nickel mediated carbon-carbon bond cleavage of organonitriles. | Dalton transactions (Cambridge, England : 2003) 20070528 |
Synthesis of a cyanoethylidene derivative of 3,6-anhydro-d-galactose and its application as glycosyl donor. | Carbohydrate research 20070226 |
Direct cyanation of heteroaromatic compounds mediated by hypervalent iodine(III) reagents: In situ generation of PhI(III)-CN species and their cyano transfer. | The Journal of organic chemistry 20070105 |
Gold-catalyzed cyanosilylation reaction: homogeneous and heterogeneous pathways. | Chemistry (Weinheim an der Bergstrasse, Germany) 20070101 |
Asymmetric activation of tropos 2,2'-biphenol with cinchonine generates an effective catalyst for the asymmetric strecker reaction of N-tosyl-protected aldimines and ketoimines. | Angewandte Chemie (International ed. in English) 20070101 |
Facile synthesis of monomeric alumatranes. | Journal of the American Chemical Society 20061025 |
Efficient pyrrole synthesis using double nucleophilic addition to alpha,beta-unsaturated imines with plural nucleophiles. | Organic letters 20060803 |
Synthesis of a galacto-configured C-ketoside-based gamma-sugar-amino acid and its use in peptide coupling reactions. | Carbohydrate research 20060724 |
Nucleophilic additions of trimethylsilyl cyanide to cyclic oxocarbenium ions: evidence for the loss of stereoselectivity at the limits of diffusion control. | Journal of the American Chemical Society 20060705 |
Lewis base catalyzed addition of trimethylsilyl cyanide to aldehydes. | The Journal of organic chemistry 20060512 |
4,6-O-[1-cyano-2-(2-iodophenyl)ethylidene] acetals. improved second-generation acetals for the stereoselective formation of beta-D-mannopyranosides and regioselective reductive radical fragmentation to beta-D-rhamnopyranosides. scope and limitations. | The Journal of organic chemistry 20060428 |
Supramolecular catalysis of Strecker reaction in water under neutral conditions in the presence of beta-cyclodextrin. | The Journal of organic chemistry 20060317 |
Activation of TMSCN by N-heterocyclic carbenes for facile cyanosilylation of carbonyl compounds. | The Journal of organic chemistry 20060203 |
In situ generation of HCN for mass spectrometric studies. | Journal of the American Society for Mass Spectrometry 20060101 |
Synthesis of (-)-quinocarcin by directed condensation of alpha-amino aldehydes. | Journal of the American Chemical Society 20051207 |
Highly diastereoselective cyanation of methyl ketimines obtained from (R)-glyceraldehyde. | The Journal of organic chemistry 20051125 |
Catalytic enantioselective desymmetrization of meso-N-acylaziridines with TMSCN. | Journal of the American Chemical Society 20050817 |
Multicomponent cascade reactions: sequential [1 + 4] and [2 + 3] cycloadditions for the generation of heterocyclic ring systems. | Organic letters 20050721 |
Thiourea-catalyzed enantioselective cyanosilylation of ketones. | Journal of the American Chemical Society 20050629 |
On-step synthesis of a bifunctional BINOL ligand for the highly enantioselective cyanation of aliphatic aldehydes. | Organic letters 20050609 |
Enantioselective cyanosilylation of ketones catalyzed by a chiral oxazaborolidinium ion. | Journal of the American Chemical Society 20050420 |
Synthesis of homo-N-nucleoside with 1,2,4-triazole-3-carboxamide. | Nucleosides, nucleotides & nucleic acids 20050101 |
Cobalt(II) chloride catalyzed one-pot synthesis of alpha-aminonitriles. | Beilstein journal of organic chemistry 20050101 |
Synthesis of 13,14-secotestosterone derivatives. | Steroids 20040701 |
Epimerization of diastereomeric alpha-amino nitriles to single stereoisomers in the solid state. | Organic letters 20040624 |
Endo-selective quenching of hexahydropyrrolo[2,3-b]indole-based N-acyliminium ions. | The Journal of organic chemistry 20040528 |
Functionalization of OEP-based benzochlorins to develop carbohydrate-conjugated photosensitizers. Attempt to target beta-galactoside-recognized proteins. | The Journal of organic chemistry 20040109 |
Synthesis and anti-HIV activity of 4'-cyano-2',3'-didehydro-3'-deoxythymidine. | Nucleosides, nucleotides & nucleic acids 20040101 |
The first total synthesis of the marine fatty acid (+/-)-2-methoxy-13-methyltetradecanoic acid: a cytotoxic fatty acid to leukemia cells. | Chemistry and physics of lipids 20031201 |
Polymer-supported pyridine-bis(oxazoline). Application to ytterbium-catalyzed silylcyanation of benzaldehyde. | Organic letters 20031002 |
Catalytic asymmetric cyanosilylation of ketones with chiral Lewis base. | Journal of the American Chemical Society 20030820 |
Expedient one-pot synthesis of novel chiral 2-substituted 5-phenyl-1,4-benzodiazepine scaffolds from amino acid-derived amino nitriles. | The Journal of organic chemistry 20030530 |
The first example of enantioselective isocyanosilylation of meso epoxides with TMSCN catalyzed by novel chiral organogallium and indium complexes. | Chemical communications (Cambridge, England) 20030321 |
Stereoselective C-glycosidation of unprotected D-glycals with trimethylsilyl cyanide. | Chirality 20030101 |
Octopaminergic agonists for the cockroach neuronal octopamine receptor. | Journal of insect science (Online) 20030101 |
Glucofuranosylation with penta-O-propanoyl-beta-D-glucofuranose. | Carbohydrate research 20021119 |
Novel sigma receptor ligands. Part 2. SAR of spiro[[2]benzopyran-1,4'-piperidines] and spiro[[2]benzofuran-1,4'-piperidines] with carbon substituents in position 3. | Journal of medicinal chemistry 20021024 |
Aluminum-catalyzed asymmetric addition of TMSCN to aromatic and aliphatic ketones promoted by an easily accessible and recyclable peptide ligand. | Angewandte Chemie (International ed. in English) 20020315 |
Lewis acid-catalyzed ring-opening reactions of semicyclic N,O-acetals possessing an exocyclic nitrogen atom: mechanistic aspect and application to piperidine alkaloid synthesis. | Journal of the American Chemical Society 20011219 |
[Development and application of enantioselective Lewis acid-Lewis base bifunctional catalyst]. | Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan 20011201 |
Switching enantiofacial selectivities using one chiral source: catalytic enantioselective synthesis of the key intermediate for (20S)-camptothecin family by (S)-selective cyanosilylation of ketones. | Journal of the American Chemical Society 20011010 |
Total asymmetric synthesis of the putative structure of the cytotoxic diterpenoid (-)-sclerophytin a and of the authentic natural sclerophytins A and B. | Journal of the American Chemical Society 20010919 |
Stereocontrolled asymmetric synthesis of alpha-hydroxy-beta-amino acids. A stereodivergent approach. | Journal of the American Chemical Society 20010418 |