Home Sulfos Bismuth(iii) trifluoromethanesulfonate

Bismuth(iii) trifluoromethanesulfonate

CAS No.:
88189-03-1
Catalog Number:
AG0034JD
Molecular Formula:
C3BiF9O9S3
Molecular Weight:
656.1877
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
1g
95%
In Stock USA
United States
$10
- +
5g
95%
In Stock USA
United States
$32
- +
25g
95%
In Stock USA
United States
$93
- +
100g
95%
In Stock USA
United States
$275
- +
Product Description
Catalog Number:
AG0034JD
Chemical Name:
Bismuth(iii) trifluoromethanesulfonate
CAS Number:
88189-03-1
Molecular Formula:
C3BiF9O9S3
Molecular Weight:
656.1877
MDL Number:
MFCD08272314
IUPAC Name:
bismuth;trifluoromethanesulfonate
InChI:
InChI=1S/3CHF3O3S.Bi/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3
InChI Key:
NYENCOMLZDQKNH-UHFFFAOYSA-K
SMILES:
FC(S(=O)(=O)[O-])(F)F.FC(S(=O)(=O)[O-])(F)F.FC(S(=O)(=O)[O-])(F)F.[Bi+3]
UNII:
51KD8E1741
Properties
Complexity:
145  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
4  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
655.836g/mol
Formal Charge:
0
Heavy Atom Count:
25  
Hydrogen Bond Acceptor Count:
18  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
656.17g/mol
Monoisotopic Mass:
655.836g/mol
Rotatable Bond Count:
0
Topological Polar Surface Area:
197A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
Literature
Title Journal
Bi(OTf)3-, TfOH-, and TMSOTf-mediated, one-pot epoxide rearrangement, addition, and intramolecular silyl-modified Sakurai (ISMS) cascade toward dihydropyrans: comparison of catalysts and role of Bi(OTf)3. The Journal of organic chemistry 20111118
Bi(OTf)3-catalysed prenylation of electron-rich aryl ethers and phenols with isoprene: a direct route to prenylated derivatives. Organic & biomolecular chemistry 20110721
Biomimetic cationic polyannulation reaction catalyzed by Bi(OTf)3: cyclization of 1,6-dienes, 1,6,10-trienes, and aryl polyenes. Organic letters 20110701
Synthesis of chiral 1-substituted tetrahydroisoquinolines by the intramolecular 1,3-chirality transfer reaction catalyzed by Bi(OTf)3. The Journal of organic chemistry 20110401
Efficient conversion of triacylglycerols and fatty acids to biodiesel in a microwave reactor using metal triflate catalysts. Organic & biomolecular chemistry 20101021
Bismuth(III) triflate-catalyzed direct conversion of corticosteroids into highly functionalized 17-ketosteroids by cleavage of the C17-dihydroxyacetone side chain. The Journal of organic chemistry 20091106
Multicatalytic synthesis of complex tetrahydrofurans involving bismuth(III) triflate catalyzed intramolecular hydroalkoxylation of unactivated olefins. Organic letters 20090319
Bismuth triflate-catalyzed Wagner-Meerwein rearrangement in terpenes. Application to the synthesis of the 18alpha-oleanane core and A-neo-18alpha-oleanene compounds from lupanes. Organic & biomolecular chemistry 20090207
An efficient and mild bismuth triflate-catalysed three-component Mannich-type reaction. Organic & biomolecular chemistry 20071007
New entries to water-compatible Lewis acids. Chemistry (Weinheim an der Bergstrasse, Germany) 20060807
Bismuth triflate-chiral bipyridine complexes as water-compatible chiral Lewis acids. Organic letters 20051013
Bismuth compounds in organic synthesis. A one-pot synthesis of homoallyl ethers and homoallyl acetates from aldehydes catalyzed by bismuth triflate. The Journal of organic chemistry 20050318
Glycosylation of sialyl acetates with a novel catalyst combination: bismuth triflate and BF3.OEt2 system. Bioorganic & medicinal chemistry 20030717
Highly powerful and practical acylation of alcohols with acid anhydride catalyzed by Bi(OTf)(3). The Journal of organic chemistry 20011228
Properties