Home Other Building Blocks Cyclohex-2-enone

Cyclohex-2-enone

CAS No.:
930-68-7
Catalog Number:
AG0033A4
Molecular Formula:
C6H8O
Molecular Weight:
96.1271
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Purity
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Product Description
Catalog Number:
AG0033A4
Chemical Name:
Cyclohex-2-enone
CAS Number:
930-68-7
Molecular Formula:
C6H8O
Molecular Weight:
96.1271
MDL Number:
MFCD00001577
IUPAC Name:
cyclohex-2-en-1-one
InChI:
InChI=1S/C6H8O/c7-6-4-2-1-3-5-6/h2,4H,1,3,5H2
InChI Key:
FWFSEYBSWVRWGL-UHFFFAOYSA-N
SMILES:
O=C1CCCC=C1
EC Number:
213-223-5
UNII:
445160R1U6
NSC Number:
59710
FEMA Number:
4517
Properties
Complexity:
103  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
96.058g/mol
Formal Charge:
0
Heavy Atom Count:
7  
Hydrogen Bond Acceptor Count:
1  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
96.129g/mol
Monoisotopic Mass:
96.058g/mol
Rotatable Bond Count:
0
Topological Polar Surface Area:
17.1A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
0.6  
Literature
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3,3-Ethyl-enedithio-3,3a,4,5,10,10b-hexa-hydro-2H-furo[2,3-a]carbazole. Acta crystallographica. Section E, Structure reports online 20090301
An exceptionally rapid and selective hydrogenation of 2-cyclohexen-1-one in supercritical carbon dioxide. Chemical communications (Cambridge, England) 20090214
Competitive reaction pathways for o-anilide aryl radicals: 1,5- or 1,6-hydrogen transfer versus nucleophilic coupling reactions. A novel rearrangement to afford an amidyl radical. The Journal of organic chemistry 20090206
Regiocontrolled cobalt-catalyzed Diels-Alder reactions of silicon-functionalized, terminal, and internal alkynes. Organic letters 20090205
(1S,4S,5S,6R)-6-(4-Bromo-phen-yl)-5-nitro-bicyclo-[2.2.2]octan-2-one. Acta crystallographica. Section E, Structure reports online 20090201
(E)-(2,4-Dichloro-phen-yl)[2-hydr-oxy-6-(methoxy-imino)cyclo-hex-1-en-yl]methanone. Acta crystallographica. Section E, Structure reports online 20090201
Tunable coordination of a tropos phosphite for fine-tuning of the Rh catalyzed asymmetric addition of phenylboronic acid to cyclohexenone. Chemical communications (Cambridge, England) 20090128
Synthesis and evaluation of guanidinyl pyrrolidines as bifunctional catalysts for enantioselective conjugate additions to cyclic enones. Organic & biomolecular chemistry 20090121
Diphenylprolinol silyl ether catalysis in an asymmetric formal carbo [3 + 3] cycloaddition reaction via a domino Michael/Knoevenagel condensation. Organic letters 20090101
Enantioselective Robinson-type annulation reaction catalyzed by chiral phosphoric acids. Angewandte Chemie (International ed. in English) 20090101
Ethyl 6-r-(2-chlorophenyl)-2-oxo-4-phenyl-cyclohex-3-ene-1-t-carboxylate. Acta crystallographica. Section E, Structure reports online 20090101
Ethyl 4-(4-methoxy-phen-yl)-2-oxo-6-phenyl-cyclo-hex-3-ene-1-carboxyl-ate. Acta crystallographica. Section E, Structure reports online 20081201
RNA interference-mediated repression of MtCCD1 in mycorrhizal roots of Medicago truncatula causes accumulation of C27 apocarotenoids, shedding light on the functional role of CCD1. Plant physiology 20081101
Synthesis of 2-cyclohexenone derivatives via gold(I)-catalyzed hydrative cyclization of 1,6-diynes. The Journal of organic chemistry 20081003
Cloning and characterisation of a maize carotenoid cleavage dioxygenase (ZmCCD1) and its involvement in the biosynthesis of apocarotenoids with various roles in mutualistic and parasitic interactions. Planta 20081001
Toward an efficient synthesis of taxane analogs by dienyne ring-closing metathesis. Organic letters 20080904
5,5-Bis(hydroxy-meth-yl)-3-methyl-cyclo-hex-2-enone. Acta crystallographica. Section E, Structure reports online 20080901
9-(4-Fluoro-phen-yl)-3,3,6,6-tetra-methyl-10-p-tolyl-1,2,3,4,5,6,7,8,9,10-deca-hydroacridine-1,8-dione. Acta crystallographica. Section E, Structure reports online 20080901
Oxidation of p-chlorotoluene and cyclohexene catalysed by polymer-anchored oxovanadium(IV) and copper(II) complexes of amino acid derived tridentate ligands. Dalton transactions (Cambridge, England : 2003) 20080828
(9S)-9-(2-hydroxy-4,4-dimethyl-6-oxo-1-cyclohexen-1-yl)-3,3-dimethyl-2,3,4,9-tetrahydro-1H-xanthen-1-one, a selective and orally active neuropeptide Y Y5 receptor antagonist. Journal of medicinal chemistry 20080814
Altered expression of DJ-1 in the hippocampal cells following in vivo and in vitro neuronal damage induced by trimethyltin. Neuroscience letters 20080808
Nucleophilic fluoroalkylation of alpha,beta-enones, arynes, and activated alkynes with fluorinated sulfones: probing the hard/soft nature of fluorinated carbanions. The Journal of organic chemistry 20080801
Insight into substrate binding in Shibasaki's Li3(THF)n(BINOLate)3Ln complexes and implications in catalysis. Journal of the American Chemical Society 20080611
Cyclohexene photo-oxidation over vanadia catalyst analyzed by time resolved ATR-FT-IR spectroscopy. Physical chemistry chemical physics : PCCP 20080607
Stereoselective umpolung tandem addition of heteroatoms to phenol. Journal of the American Chemical Society 20080604
3-Methyl-5-(3-phenoxy-phen-yl)cyclo-hex-2-enone. Acta crystallographica. Section E, Structure reports online 20080601
Catalytic asymmetric epoxidation of cyclic enones. Journal of the American Chemical Society 20080514
Identifying the minimal enzymes required for anhydrotetracycline biosynthesis. Journal of the American Chemical Society 20080514
Accumulation of apocarotenoids in mycorrhizal roots of leek (Allium porrum). Phytochemistry 20080501
A theoretical study on the trans-addition intramolecular hydroacylation of 4-alkynals catalyzed by cationic rhodium complexes. The Journal of organic chemistry 20080404
Asymmetric Morita-Baylis-Hillman reaction of arylaldehydes with 2-cyclohexen-1-one catalyzed by chiral bis(thio)urea and DABCO. Organic letters 20080320
Expression of two old yellow enzyme homologues from Gluconobacter oxydans and identification of their citral hydrogenation abilities. Molecular biotechnology 20080301
Mycosporine-like amino acids and marine toxins--the common and the different. Marine drugs 20080301
4'-Methyl-3-(4-nitro-phen-yl)-4-phenyl-4,5,1',2',3',4'-hexa-hydro-spiro-[isoxazole-5,2'-naphthalen]-1'-one. Acta crystallographica. Section E, Structure reports online 20080201
Ultraviolet cavity ringdown spectra and the S1(n,pi) ring-inversion potential energy function for 2-cyclohexen-1-one-d0 and Its 2,6,6-d3 isotopomer. The journal of physical chemistry. A 20080110
Metabolite profiling of mycorrhizal roots of Medicago truncatula. Phytochemistry 20080101
In vivo depletion of endogenous glutathione facilitates trimethyltin-induced neuronal damage in the dentate gyrus of mice by enhancing oxidative stress. Neurochemistry international 20080101
High-throughput kinetic study of hydrogenation over palladium nanoparticles: combination of reaction and analysis. Chemistry (Weinheim an der Bergstrasse, Germany) 20080101
Enantioselective Cu-catalyzed 1,4-addition of Grignard reagents to cyclohexenone using taddol-derived phosphine-phosphite ligands and 2-methyl-THF as a solvent. Angewandte Chemie (International ed. in English) 20080101
Access to well-defined isolated Fe(II) centers on silica and their use in oxidation. Dalton transactions (Cambridge, England : 2003) 20071221
N-heterocyclic carbene catalyzed aza-Morita-Baylis-Hillman reaction of cyclic enones with N-tosylarylimines. The Journal of organic chemistry 20070914
[2+2] cycloaddition reactions with a tungsten-stabilized 2H-phenol. Journal of the American Chemical Society 20070912
Asymmetric alkene reduction by yeast old yellow enzymes and by a novel Zymomonas mobilis reductase. Biotechnology and bioengineering 20070901
Isotope effects and the mechanism of epoxidation of cyclohexenone with tert-butyl hydroperoxide. The Journal of organic chemistry 20070803
Chemical identification and functional analysis of apocarotenoids involved in the development of arbuscular mycorrhizal symbiosis. Bioscience, biotechnology, and biochemistry 20070601
Bioactive lignans from Peperomia heyneana. Journal of natural products 20070401
Asymmetric synthesis of the epimeric (3S)-3-((E)-hex-1-enyl)-2-methylcyclohexanones. Molecules (Basel, Switzerland) 20070221
Exploration of the enantioselective Birch-Cope sequence for the synthesis of carbocyclic quaternary stereocenters. The Journal of organic chemistry 20070202
Isolation and characterization of N98-1272 A, B and C, selective acetylcholinesterase inhibitors from metabolites of an actinomycete strain. Journal of enzyme inhibition and medicinal chemistry 20070201
Apocarotenoid biosynthesis in arbuscular mycorrhizal roots: contributions from methylerythritol phosphate pathway isogenes and tools for its manipulation. Phytochemistry 20070101
Demonstration of promoted zinc Schlenk equilibria, their equilibrium values and derived reactivity. Chemistry (Weinheim an der Bergstrasse, Germany) 20070101
Spirodionic acid, a novel metabolite from Streptomyces sp., part 2: total synthesis through a twofold michael addition as a selective spiroannelation strategy. Chemistry (Weinheim an der Bergstrasse, Germany) 20070101
The reactivity of calicheamicin gamma(1)(I) in the minor groove of DNA: the decisive role of the environment. Chemistry (Weinheim an der Bergstrasse, Germany) 20070101
Enantioselective direct aza hetero-Diels-Alder reaction catalyzed by chiral Brønsted acids. Organic letters 20061221
A new asymmetric organocatalytic nitrocyclopropanation reaction. Chemical communications (Cambridge, England) 20061214
Optimization of the catalytic asymmetric addition of nitroalkanes to cyclic enones with trans-4,5-methano-L-proline. Organic letters 20061012
3-[5-(4-Bromophenyl)-1H-pyrazol-3-ylamino]-5,5-dimethylcyclohex-2-en-1-one-(Z)-3-(4-bromophenyl)-3-chloroacrylonitrile (2/1): a stoichiometric cocrystal of a reaction product with one of its early precursors. Acta crystallographica. Section C, Crystal structure communications 20061001
Asymmetric Morita-Baylis-Hillman reaction catalyzed by isophoronediamine-derived bis(thio)urea organocatalysts. Organic letters 20060914
Isolation, structure, and absolute stereochemistry of platensimycin, a broad spectrum antibiotic discovered using an antisense differential sensitivity strategy. Journal of the American Chemical Society 20060913
Induced chirality of the light-harvesting carotenoid salinixanthin and its interaction with the retinal of xanthorhodopsin. Biochemistry 20060912
Zr(IV)-monosubstituted Keggin-type dimeric polyoxometalates: synthesis, characterization, catalysis of H2O2-based oxidations, and theoretical study. Inorganic chemistry 20060904
The enantioselective Birch-Cope sequence for the synthesis of carbocyclic quaternary stereocenters. Application to the synthesis of (+)-mesembrine. Organic letters 20060831
Synthetic studies toward highly functionalized 5beta-lanosterol derivatives: a versatile approach utilizing anionic cycloaddition. The Journal of organic chemistry 20060804
Dioxygen affinities and catalytic oxidation activities of cobalt complexes with Schiff bases containing crown ether. Journal of inorganic biochemistry 20060801
Novel gamma-secretase inhibitors discovered by library screening of in-house synthetic natural product intermediates. Bioorganic & medicinal chemistry letters 20060715
Self-assembling bisurea macrocycles used as an organic zeolite for a highly stereoselective photodimerization of 2-cyclohexenone. Journal of the American Chemical Society 20060628
Accumulation of apocarotenoids in mycorrhizal roots of Ornithogalum umbellatum. Phytochemistry 20060601
Studies on the reactive species in fluoride-mediated carbon-carbon bond-forming reactions: carbanion formation by desilylation with fluoride and enolates. The Journal of organic chemistry 20060526
Nucleophilic addition to (3-methylpentadienyl)iron(1+) cations: counterion control of regioselectivity; application to the enantioselective synthesis of 4,5-disubstituted cyclohexenones. Journal of the American Chemical Society 20060510
Microsphere-based protease assays and screening application for lethal factor and factor Xa. Cytometry. Part A : the journal of the International Society for Analytical Cytology 20060501
Synthesis of (+)-sch 642305 by a biomimetic transannular Michael reaction. Organic letters 20060330
A superior P-H phosphonite: asymmetric allylic substitutions with fenchol-based palladium catalysts. Beilstein journal of organic chemistry 20060101
Isoprenoid metabolism and plastid reorganization in arbuscular mycorrhizal roots. The New phytologist 20060101
2-Amino-4-(2-methoxyphenyl)-7,7-dimethyl-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile and 2-amino-4-(2-methoxyphenyl)-7,7-dimethyl-3-nitro-4,6,7,8-tetrahydro-5H-chromen-5-one hemihydrate. Acta crystallographica. Section C, Crystal structure communications 20051201
Facile preparation of a new BINAP-based building block, 5,5'-diiodoBINAP, and its synthetic application. The Journal of organic chemistry 20051125
Tetrahydropyran rings from a Mukaiyama-Michael cascade reaction. Journal of the American Chemical Society 20051123
Probing the 'additive effect' in the proline and proline hydroxamic acid catalyzed asymmetric addition of nitroalkanes to cyclic enones. Chirality 20051101
Chiral binaphthyl-derived amine-thiourea organocatalyst-promoted asymmetric Morita-Baylis-Hillman reaction. Organic letters 20050915
New silicon-mediated, sequential ring expansions of n-sized 2-cycloalkenones into hydroxyolefinic n + m + p medium-sized lactones: short synthesis of (-)-phoracantholide-J. Organic letters 20050915
Proton transfer in the oxidative half-reaction of pentaerythritol tetranitrate reductase. Structure of the reduced enzyme-progesterone complex and the roles of residues Tyr186, His181, His184. The FEBS journal 20050901
Sequential aminodiene Diels-Alder approach to the ergoline skeleton. The Journal of organic chemistry 20050819
Role of active site residues and solvent in proton transfer and the modulation of flavin reduction potential in bacterial morphinone reductase. The Journal of biological chemistry 20050722
Tandem Sakurai-aldol addition reactions as a route to structurally complex carbocycles. The Journal of organic chemistry 20050527
Preparation of 2- and 4-arylmethyl N-substituted and N,N-disubstituted anilines via a 'green', multicomponent reaction. Organic letters 20050414
Reaction of morphinone reductase with 2-cyclohexen-1-one and 1-nitrocyclohexene: proton donation, ligand binding, and the role of residues Histidine 186 and Asparagine 189. The Journal of biological chemistry 20050318
C-H...O hydrogen bonds in cyclohexenone reveal the spectroscopic behavior of Csp3-H and Csp2-H donors. Chemphyschem : a European journal of chemical physics and physical chemistry 20050301
Opening the 'black box': oscillations in organocuprate conjugate addition reactions. Chemical communications (Cambridge, England) 20050221
Synthesis of an analogue of the marine polypropionate tridachiahydropyrone. Organic letters 20050203
Parallel mechanistic studies on the counterion effect of manganese salen and porphyrin complexes on olefin epoxidation by iodosylarenes. Journal of inorganic biochemistry 20050201
Three oxygenated cyclohexenone derivatives produced by an endophytic fungus. Bioscience, biotechnology, and biochemistry 20050201
Structural assignment of Diels-Alder adducts: an experimental and theoretical approach. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20050101
An exceptional P-H phosphonite: biphenyl-2,2'-bisfenchylchlorophosphite and derived ligands (BIFOPs) in enantioselective copper-catalyzed 1,4-additions. Beilstein journal of organic chemistry 20050101
High stereoselectivity on low temperature Diels-Alder reactions. Beilstein journal of organic chemistry 20050101
On the role of PIII ligands in the conjugate addition of diorganozinc derivatives to enones. Chemistry (Weinheim an der Bergstrasse, Germany) 20041119
Highly enantioselective conjugate additions of potassium organotrifluoroborates to enones by use of monodentate phosphoramidite ligands. The Journal of organic chemistry 20041112
Protein thiol modification by 15-deoxy-Delta12,14-prostaglandin J2 addition in mesangial cells: role in the inhibition of pro-inflammatory genes. Molecular pharmacology 20041101
Synthesis and antinematodal activity of 3-n-alkylphenols. Bioscience, biotechnology, and biochemistry 20041101
Oxygen-promoted palladium(II) catalysis: facile C(sp2)-C(sp2) bond formation via cross-coupling of alkenylboronic compounds and olefins. Organic letters 20041028
A short route to enantiomerically pure benzophenanthridinone skeleton: synthesis of lactone analogues of narciclasine and lycoricidine. The Journal of organic chemistry 20041001
Catalytic enantioselective conjugate addition of trimethylsilylacetylene to 2-cyclohexen-1-one. Organic letters 20040916
Brønsted acid-promoted cyclizations of siloxyalkynes with arenes and alkenes. Journal of the American Chemical Society 20040825
Highly enantioselective Cu-catalysed asymmetric 1,4-addition of diphenylzinc to cyclohexenone. Chemical communications (Cambridge, England) 20040821
2-Amino-4-(1-naphthyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile and 2-amino-7,7-dimethyl-4-(1-naphthyl)-5-oxo-5,6,7,8-tetrahydro-4H-chromene-3-carbonitrile. Acta crystallographica. Section C, Crystal structure communications 20040501
NaOH-catalyzed thiolysis of alpha,beta-epoxyketones in water. A key step in the synthesis of target molecules starting from alpha,beta-unsaturated ketones. The Journal of organic chemistry 20040402
Two compounds from allelopathic rice accession and their inhibitory activity on weeds and fungal pathogens. Phytochemistry 20040401
Different reaction modes for the oxidative dimerization of epoxyquinols and epoxyquinones. Importance of intermolecular hydrogen-bonding. The Journal of organic chemistry 20040305
Novel enhancement of diastereoselectivity of [2 + 2] photocycloaddition of chiral cyclohexenones to ethylene by adding naphthalenes. The Journal of organic chemistry 20040206
Structure and expression of 12-oxophytodienoate reductase (subgroup I) genes in pea, and characterization of the oxidoreductase activities of their recombinant products. Molecular genetics and genomics : MGG 20040201
An aza-steroidal [17,16-c]pyrazole derivative: 2'-(p-fluorophenyl)-17a-aza-2'H-pyrazolo[4',3':16,17]-D-homoandrost-4-en-3-one. Acta crystallographica. Section C, Crystal structure communications 20040201
Catalytic asymmetric Michael reaction of beta-keto esters: effects of the linker heteroatom in linked-BINOL. Journal of the American Chemical Society 20031224
H-tunneling in the multiple H-transfers of the catalytic cycle of morphinone reductase and in the reductive half-reaction of the homologous pentaerythritol tetranitrate reductase. The Journal of biological chemistry 20031107
Urease inhibitory activity of simple alpha,beta-unsaturated ketones. Life sciences 20031024
2-azabicyclo[2.2.2]octa-3,5-dione via a nitrile Diels-Alder reaction. The Journal of organic chemistry 20031017
Asymmetric Morita-Baylis-Hillman reactions catalyzed by chiral Brønsted acids. Journal of the American Chemical Society 20031008
Synthesis of (-)-tetrodotoxin: preparation of an advanced cyclohexenone intermediate. The Journal of organic chemistry 20031003
Alpha,beta-unsaturated carbonyl compounds: induction of oxidative DNA damage in mammalian cells. Mutagenesis 20030901
Particle growth by acid-catalyzed heterogeneous reactions of organic carbonyls on preexisting aerosols. Environmental science & technology 20030901
Investigation of the asymmetric ionic Diels-Alder reaction for the synthesis of cis-decalins. Organic & biomolecular chemistry 20030821
High-pressure selectivity studies--a simple route to a homochiral wistarin precursor. Chemistry (Weinheim an der Bergstrasse, Germany) 20030818
Comparison of the gastroprotective effect of a diterpene lactone isolated from Croton cajucara with its synthetic derivatives. Journal of ethnopharmacology 20030801
Steric factors direct Baylis-Hillman and aldol reactions in titanium tetrachloride mediated coupling between alpha-keto esters and cyclohex-2-enone derivatives. The Journal of organic chemistry 20030725
Polymer-supported bisBINOL ligands for the immobilization of multicomponent asymmetric catalysts. Organic letters 20030724
Uniquely modified imidazole alkaloids from a calcareous Leucetta sponge. Journal of natural products 20030701
A proton-shuttle mechanism mediated by the porphyrin in benzene hydroxylation by cytochrome p450 enzymes. Journal of the American Chemical Society 20030618
An experimental and theoretical study of the type C enone rearrangement: mechanistic and exploratory organic photochemistry. Journal of the American Chemical Society 20030507
Mild, fast, and stereoselective epoxide opening by ketone enolate anions. Application to synthesis of the norlignan curculigine. The Journal of organic chemistry 20030418
The fungal metabolite austdiol. Acta crystallographica. Section C, Crystal structure communications 20030401
Generation of chiral boron enolates by rhodium-catalyzed asymmetric 1,4-addition of 9-aryl-9-borabicyclo[3.3.1]nonanes (B-Ar-9BBN) to alpha,beta-unsaturated ketones. The Journal of organic chemistry 20030307
Catalysis of the Michael addition reaction by late transition metal complexes of BINOL-derived salens. The Journal of organic chemistry 20030307
Acute irritation followed by primary sensitization to 2-cyclohexen-1-one in a chemistry student. Contact dermatitis 20030301
Synthesis of new chiral bis(isoxazoline) ligands containing spiro[5.5]undecane skeleton. Chirality 20030101
Alicycliphilus denitrificans gen. nov., sp. nov., a cyclohexanol-degrading, nitrate-reducing beta-proteobacterium. International journal of systematic and evolutionary microbiology 20030101
Photodimerisation of enones in a clay microenvironment. Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology 20021201
Rapid-injection NMR study of iodo- and cyano-Gilman reagents with 2-cyclohexenone: observation of pi-complexes and their rates of formation. Journal of the American Chemical Society 20021120
Stimulation of carotenoid metabolism in arbuscular mycorrhizal roots. Planta 20021101
Solid-phase development of chiral phosphoramidite ligands for enantioselective conjugate addition reactions. Chemistry (Weinheim an der Bergstrasse, Germany) 20021018
Aroma active components in aqueous kiwi fruit essence and kiwi fruit puree by GC-MS and multidimensional GC/GC-O. Journal of agricultural and food chemistry 20020911
Crystal structure of bacterial morphinone reductase and properties of the C191A mutant enzyme. The Journal of biological chemistry 20020823
Theoretical study of the photochemical [2 + 2]-cycloadditions of cyclic and acyclic alpha,beta-unsaturated carbonyl compounds to ethylene. The Journal of organic chemistry 20020823
A convergent synthesis of the cardenolide skeleton: intramolecular aldol condensation via reduction of alpha-bromoketones. The Journal of organic chemistry 20020809
TiCl(4)-promoted Baylis-Hillman reactions of substituted 5-isoxazolecarboxaldehydes with cycloalkenones). The Journal of organic chemistry 20020809
Competition and selectivity of organic reactions on semiconductor surfaces: reaction of unsaturated ketones on Si(100)-2 x 1 and Ge(100)-2 x 1. Journal of the American Chemical Society 20020731
Formation of vinyl halides via a ruthenium-catalyzed three-component coupling. Journal of the American Chemical Society 20020626
Kinetic and structural basis of reactivity of pentaerythritol tetranitrate reductase with NADPH, 2-cyclohexenone, nitroesters, and nitroaromatic explosives. The Journal of biological chemistry 20020614
Sequential one-pot InBr(3)-catalyzed 1,4- then 1,2-nucleophilic addition to enones. The Journal of organic chemistry 20020531
Enantioselective conjugate addition of diethylzinc to cyclic enones catalyzed by copper complexes of methylene-bridged P-chirogenic diphosphines. Chirality 20020515
Unusual regioselective intramolecular Diels-Alder reaction forming tricyclo[4.3.1.0(3,7)]decane system. The Journal of organic chemistry 20020503
Derivatives of dehydrocrotonin, a diterpene lactone isolated from Croton cajucara: cytotoxicity in rat cultured hepatocytes and in V79 cells. Human & experimental toxicology 20020501
Rate acceleration of the Baylis-Hillman reaction in polar solvents (water and formamide). Dominant role of hydrogen bonding, not hydrophobic effects, is implicated. The Journal of organic chemistry 20020125
The role of glutamine 114 in old yellow enzyme. The Journal of biological chemistry 20020118
The T(1) (3)(pi-pi*)/S(0) intersections and triplet lifetimes of cyclic alpha,beta-enones. The Journal of organic chemistry 20011228
Catalyzed Diels-Alder reaction of alkylidene- or arylideneacetoacetates and Danishefsky's dienes with lanthanide salts aimed at selective synthesis of cis-4,5-dimethyl-2-cyclohexenone derivatives. The Journal of organic chemistry 20011130
A pyridone analogue of traditional cannabinoids. A new class of selective ligands for the CB(2) receptor. Bioorganic & medicinal chemistry 20011101
Is benzene oxide homoaromatic? A microcalorimetric study. Journal of the American Chemical Society 20011024
DNA-damaging potential and glutathione depletion of 2-cyclohexene-1-one in mammalian cells, compared to food relevant 2-alkenals. Mutation research 20011018
Lewis base effects in the Baylis-Hillman reaction of imines with cyclohex-2-en-1-one and cyclopent-2-en-1-one. Chemical communications (Cambridge, England) 20010921
Inhalation toxicity studies of the alpha,beta-unsaturated ketones: ethyl vinyl ketone. Inhalation toxicology 20010801
Stereoselective trans- and cis-dihydroxylations of 2H-pyranyl and dihydropyridinyl heterocycles synthesized from formal [3 + 3]-cycloaddition reactions of alpha,beta-unsaturated iminium ions with 1,3-dicarbonyl equivalents. Organic letters 20010712
3-(p-chlorophenyl)-4-phenyl-4,5-dihydroisoxazole-5-spiro-2'-1',2',3',4'-tetrahydronaphthalen-1'-one. Acta crystallographica. Section C, Crystal structure communications 20010701
Antioxidant principles from Bauhinia tarapotensis. Journal of natural products 20010701
Discovery of a new efficient chiral ligand for copper-catalyzed enantioselective Michael additions by high-throughput screening of a parallel library. Chemistry (Weinheim an der Bergstrasse, Germany) 20010618
Mechanism of the antigen formation of carvone and related alpha, beta-unsaturated ketones. Contact dermatitis 20010601
BINOL-salen metal catalysts incorporating a bifunctional design. Organic letters 20010531
Studies toward the total synthesis of scyphostatin: first entry to the highly functionalized cyclohexenone segment. Organic letters 20010531
Use of a methoxy substituent in controlling the stereochemistry of intramolecular iron-mediated diene/olefin cyclocoupling. The Journal of organic chemistry 20010504
Cloning, sequencing, and heterologous expression of the elmGHIJ genes involved in the biosynthesis of the polyketide antibiotic elloramycin from Streptomyces olivaceus Tü2353. Journal of natural products 20010401
Effects of glutathione depletion by 2-cyclohexen-1-one on excitatory amino acids-induced enhancement of activator protein-1 DNA binding in murine hippocampus. Journal of neurochemistry 20010301
Cytotoxicity of derivatives from dehydrocrotonin on V79 cells and Escherichia coli. Toxicology 20010227
Total synthesis of natural dysidiolide. The Journal of organic chemistry 20010223
Inhalation toxicity studies of the alpha,beta-unsaturated ketones: 2-cyclohexene-1-one. Inhalation toxicology 20010101
Cloning and sequence analysis of two Pseudomonas flavoprotein xenobiotic reductases. Journal of bacteriology 19991001
Sequence and properties of pentaerythritol tetranitrate reductase from Enterobacter cloacae PB2. Journal of bacteriology 19961101
Properties