Home Aminos 1,8-Bis(dimethylamino)naphthalene

1,8-Bis(dimethylamino)naphthalene

CAS No.:
20734-58-1
Catalog Number:
AG002IZU
Molecular Formula:
C14H18N2
Molecular Weight:
214.3061
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
1g
95%
In Stock USA
United States
$36
- +
5g
95%
In Stock USA
United States
$47
- +
25g
98%
In Stock USA
United States
$50
- +
100g
98%
In Stock USA
United States
$188
- +
500g
98%
In Stock USA
United States
$850
- +
Product Description
Catalog Number:
AG002IZU
Chemical Name:
1,8-Bis(dimethylamino)naphthalene
CAS Number:
20734-58-1
Molecular Formula:
C14H18N2
Molecular Weight:
214.3061
MDL Number:
MFCD00003920
IUPAC Name:
1-N,1-N,8-N,8-N-tetramethylnaphthalene-1,8-diamine
InChI:
InChI=1S/C14H18N2/c1-15(2)12-9-5-7-11-8-6-10-13(14(11)12)16(3)4/h5-10H,1-4H3
InChI Key:
GJFNRSDCSTVPCJ-UHFFFAOYSA-N
SMILES:
CN(c1cccc2c1c(ccc2)N(C)C)C
EC Number:
244-001-6
UNII:
6S79D2P9H8
Properties
Complexity:
203  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
214.147g/mol
Formal Charge:
0
Heavy Atom Count:
16  
Hydrogen Bond Acceptor Count:
2  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
214.312g/mol
Monoisotopic Mass:
214.147g/mol
Rotatable Bond Count:
2  
Topological Polar Surface Area:
6.5A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
3.4  
Literature
Title Journal
Time-dependent intensity changes of free fatty acids detected by matrix-assisted laser desorption and ionization time-of-flight mass spectrometry in the presence of 1,8-bis-(dimethylamino)naphthalene--a cautionary note. Rapid communications in mass spectrometry : RCM 20120715
Proton sponge-functionalized silica as high performance adsorbents for solid-phase extraction of trace perfluoroalkyl sulfonates in the environmental water samples and their direct analysis by MALDI-TOF-MS. The Analyst 20120507
The synthesis of 2'-methylseleno adenosine and guanosine 5'-triphosphates. Bioorganic & medicinal chemistry 20120401
Sublimation of new matrix candidates for high spatial resolution imaging mass spectrometry of lipids: enhanced information in both positive and negative polarities after 1,5-diaminonapthalene deposition. Analytical chemistry 20120221
Improved detection of phosphopeptides by negative ion matrix-assisted laser desorption/ionization mass spectrometry using a proton sponge co-matrix. Analytica chimica acta 20120120
H-bond-assisted intramolecular nucleophilic displacement of the 1-NMe2 group in 1,8-bis(dimethylamino)naphthalenes as a route to multinuclear heterocyclic compounds and strained naphthalene derivatives. The Journal of organic chemistry 20110902
Quantitative detection of trace perfluorinated compounds in environmental water samples by Matrix-assisted Laser Desorption/Ionization-Time of Flight Mass Spectrometry with 1,8-bis(tetramethylguanidino)-naphthalene as matrix. Talanta 20110715
Lipid fingerprinting of gram-positive lactobacilli by intact--matrix-assisted laser desorption/ionization mass spectrometry using a proton sponge based matrix. Rapid communications in mass spectrometry : RCM 20110630
Hybrid organic-inorganic catalytic mesoporous materials with proton sponges as building blocks. Physical chemistry chemical physics : PCCP 20110628
A simple one-dimensional method of chemical shift anisotropy determination under MAS conditions. Journal of magnetic resonance (San Diego, Calif. : 1997) 20101201
A colorimetric proton sponge. The Journal of organic chemistry 20101015
Synthesis of C-substituted t-BuNH-8,9-R,R'-nido-7,8,9-C3B8H9 (R,R' = H,H; MeH; Me,Me; Ph,H and Ph,Ph) tricarbollide compounds and their tautomeric conversions. Effect of substituents on tautomeric equilibria between neutral and zwitterionic forms. Dalton transactions (Cambridge, England : 2003) 20100507
An experimental solution to the 'missing hydrogens' question surrounding the macropolyhedral 19-vertex boron hydride monoanion [B19H22]-, a simplification of its synthesis, and its use as an intermediate in the first example of syn-B18H22 to anti-B18H22 isomer conversion. Inorganic chemistry 20100503
Symmetrization of cationic hydrogen bridges of protonated sponges induced by solvent and counteranion interactions as revealed by NMR spectroscopy. Chemistry (Weinheim an der Bergstrasse, Germany) 20100201
Proton sponge: a novel and versatile MALDI matrix for the analysis of metabolites using mass spectrometry. Analytical chemistry 20091001
1,8-Bis(dimethylamino)naphthalene: a novel superbasic matrix for matrix-assisted laser desorption/ionization time-of-flight mass spectrometric analysis of fatty acids. Rapid communications in mass spectrometry : RCM 20090801
Degenerate intermolecular and intramolecular proton-transfer reactions: electronic structure of the transition states. The journal of physical chemistry. A 20090723
Probing molecular recognition in the solid-state by use of an enolizable chromophoric barbituric acid. The Journal of organic chemistry 20080704
Application of the PM6 method to modeling the solid state. Journal of molecular modeling 20080601
Carbon-13 NMR relaxation study of 1,8-bis(dimethylamino)naphthalene in isotropic solution. The journal of physical chemistry. A 20080529
Diimine supported group 10 hydroxo, oxo, amido, and imido complexes. Dalton transactions (Cambridge, England : 2003) 20080507
Influence of N-substituent and solvent on internal conversion in 1-aminonaphthalenes. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20071001
Solid-phase synthesis of oligodeoxyribonucleoside boranophosphates by the boranophosphotriester method. The Journal of organic chemistry 20060526
1,8-Bis(hexamethyltriaminophosphazenyl)naphthalene, HMPN: a superbasic bisphosphazene 'proton sponge'. Journal of the American Chemical Society 20051116
(Fluoren-9-ylidene)methanedithiolato complexes of platinum: synthesis, reactivity, and luminescence. Inorganic chemistry 20051003
Study of photoinduced electron transfer between [60]fullerene and proton-sponge by laser flash photolysis: addition effects of organic acid. The journal of physical chemistry. A 20050721
Oxygen-bridged borate anions from tris(pentafluorophenyl)borane: synthesis, NMR characterization, and reactivity. Inorganic chemistry 20050711
Sonic spray as a dual polarity ion source for ion/ion reactions. Analytical chemistry 20050601
Femtosecond excited state studies of the two-center three-electron bond driven twisted internal charge transfer dynamics in 1,8-bis(dimethylamino)naphthalene. The journal of physical chemistry. A 20050428
Macropolyhedral boron-containing cluster chemistry. The reaction of B16H20 and B14H18 with [PtMe2(PMe2Ph)2] to give [(PMe2Ph)2PtB16H17Me] and [(PMe2Ph)2PtB14H16]. Dalton transactions (Cambridge, England : 2003) 20050421
NMR relaxation study of the protonated form of 1,8-Bis(dimethylamino)naphthalene in isotropic solution: anisotropic motion outside of extreme narrowing and ultrafast proton transfer. The journal of physical chemistry. A 20050113
Synthesis and characterization of novel monocarbollide exo-closo-(pi-arene)biruthenacarboranes [(PPh3)mClRu(eta6-C6H5R)Ru'CB10H11-n(OMe)n] (where R = H, m = 2, n = 1; R = mu-PPh2, m = 1, n = 0, 1). Inorganic chemistry 20041004
Unusually Large Primary (2)H/(1)H Kinetic Isotope Effects Accompanying a syn-beta-H Elimination Reaction in a sigma-Alkyl-Palladium Complex. Journal of the American Chemical Society 20040310
Electron-transfer-induced substitution of alkylated C60 chlorides with proton sponge. The Journal of organic chemistry 20040123
From weak interactions to covalent bonds: a continuum in the complexes of 1,8-bis(dimethylamino)naphthalene. Journal of the American Chemical Society 20030409
1,8-bis(tetramethylguanidino)naphthalene (TMGN): a new, superbasic and kinetically active 'proton sponge'. Chemistry (Weinheim an der Bergstrasse, Germany) 20020402
Symmetry of N-H-N hydrogen bonds in 1,8-bis(dimethylamino)naphthalene.H+ and 2,7-dimethoxy-1,8-bis(dimethylamino)naphthalene.H+. Journal of the American Chemical Society 20010711
Ten-vertex rhodadithiaborane chemistry: Acta crystallographica. Section C, Crystal structure communications 20010501
Properties