Home Other Building Blocks Bis(diphenylphosphino)methane

Bis(diphenylphosphino)methane

CAS No.:
2071-20-7
Catalog Number:
AG002IUS
Molecular Formula:
C25H22P2
Molecular Weight:
384.3897
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
1g
95%
In Stock USA
United States
$13
- +
5g
95%
In Stock USA
United States
$19
- +
25g
95%
In Stock USA
United States
$50
- +
100g
95%
In Stock USA
United States
$163
- +
500g
95%
In Stock USA
United States
$650
- +
Product Description
Catalog Number:
AG002IUS
Chemical Name:
Bis(diphenylphosphino)methane
CAS Number:
2071-20-7
Molecular Formula:
C25H22P2
Molecular Weight:
384.3897
MDL Number:
MFCD00003537
IUPAC Name:
diphenylphosphanylmethyl(diphenyl)phosphane
InChI:
InChI=1S/C25H22P2/c1-5-13-22(14-6-1)26(23-15-7-2-8-16-23)21-27(24-17-9-3-10-18-24)25-19-11-4-12-20-25/h1-20H,21H2
InChI Key:
XGCDBGRZEKYHNV-UHFFFAOYSA-N
SMILES:
c1ccc(cc1)P(c1ccccc1)CP(c1ccccc1)c1ccccc1
EC Number:
218-194-2
UNII:
I5O2HZR38V
NSC Number:
147767
Properties
Complexity:
325  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
1  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
384.12g/mol
Formal Charge:
0
Heavy Atom Count:
27  
Hydrogen Bond Acceptor Count:
0
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
384.399g/mol
Monoisotopic Mass:
384.12g/mol
Rotatable Bond Count:
6  
Topological Polar Surface Area:
0A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
XLogP3:
6  
Literature
Title Journal
Bis[μ-bis-(diphenyl-phosphan-yl)methane-κ(2)P:P']bis-[(isoquinoline-κN)silver(I)] bis-(trifluoro-methane-sulfonate)-isoquinoline (1/1). Acta crystallographica. Section E, Structure reports online 20120801
Bis[μ(2)-bis-(diphenyl-phosphan-yl)methane-κP:P']bis-(μ(4)-diphenyl-phosphinato-κO:O:O':O')bis-(μ(2)-trifluoro-acetato-κO:O')tetra-silver(I) acetonitrile disolvate. Acta crystallographica. Section E, Structure reports online 20111201
[μ-Bis(diphenyl-phosphan-yl-κP)methane]-deca-carbonyl-tri-μ-hydrido-trirhenium(I)(3 Re-Re) dichloromethane solvate. Acta crystallographica. Section E, Structure reports online 20111201
Synthesis and characterization of diiron dithiolate complexes containing a quinoxaline bridge. Dalton transactions (Cambridge, England : 2003) 20111107
Synthesis, structure and photophysical properties of binuclear methylplatinum complexes containing cyclometalating 2-phenylpyridine or benzo{h}quinoline ligands: a comparison of intramolecular Pt-Pt and π-π interactions. Dalton transactions (Cambridge, England : 2003) 20110928
A new cumulene diiron complex related to the active site of Fe-only hydrogenases and its phosphine substituted derivatives: synthesis, electrochemistry and structural characterization. Journal of inorganic biochemistry 20110901
Bis[μ(2)-bis-(diphenyl-phosphan-yl)methane-κP:P']bis-(μ(4)-diphenyl-phosphinato-κO:O:O':O')bis-[μ(2)-trifluoro-methane-sulfonato-(0.546/0.454)]-κO:O';κO:O-tetra-silver(I) acetonitrile disolvate. Acta crystallographica. Section E, Structure reports online 20110801
[μ(2)-Bis(diphenyl-phosphanyl)methane][μ(3)-bis-(diphenyl-phosphanyl)meth-yl]trichlorido-tetra-gold(I) tetra-hydro-furan disolvate. Acta crystallographica. Section E, Structure reports online 20110201
[μ-Bis(diphenyl-phosphan-yl)methane-1:2κP:P']nona-carbonyl-1κC,2κC,3κC-[tris-(biphenyl-4-yl)arsane-3κAs]-triangulo-triruthenium(0). Acta crystallographica. Section E, Structure reports online 20110201
Bis{[μ-bis-(diphenyl-phosphan-yl)methane-1:2κP:P']nona-carbonyl-1κC,2κC,3κC-[(4-methyl-sulfanylphen-yl)diphenyl-phosphane-3κP]-triangulo-triruthen-ium(0)} dichloro-methane monosolvate. Acta crystallographica. Section E, Structure reports online 20110201
Computational insight into the Rh-mediated activation of white phosphorus. Inorganic chemistry 20110103
A tetra-silver(I)ditungsten(VI) cluster with sulfide and bis-(diphenyl-phosphino)methane ligands. Acta crystallographica. Section E, Structure reports online 20101001
catena-Poly[silver(I)-bis-[μ-bis-(diphenyl-phosphino)methane-κP:P']-μ-thio-cyanato-κS:S-silver(I)-μ-thio-cyanato-κS:N]. Acta crystallographica. Section E, Structure reports online 20101001
Associative and dissociative mechanisms in the formation of phthalazine bridged organodiplatinum(II) complexes. Inorganic chemistry 20100920
An iridium-mediated C-H activation/CO2-carboxylation reaction of 1,1-bisdiphenylphosphinomethane. Dalton transactions (Cambridge, England : 2003) 20100907
Bis([μ-bis-(diphenyl-phosphino)methane-1:2κP:P']nona-carbonyl-1κC,2κC,3κC-{tris-[4-(methyl-sulfan-yl)phen-yl]arsine-3κAs}-triangulo-triruthenium(0)) dichloro-methane monosolvate. Acta crystallographica. Section E, Structure reports online 20100901
Nucleophilic aromatic addition reactions of the metallabenzenes and metallapyridinium: attacking aromatic metallacycles with bis(diphenylphosphino)methane to form metallacyclohexadienes and cyclic eta(2)-allene-coordinated complexes. Chemistry (Weinheim an der Bergstrasse, Germany) 20100618
Cytotoxicity of half sandwich ruthenium(II) complexes with strong hydrogen bond acceptor ligands and their mechanism of action. Journal of inorganic biochemistry 20100201
Bis{[μ-bis-(diphenyl-phosphino)methane-1:2κP:P']nona-carbonyl-1κC,2κC,3κC-[tris-(4-methoxy-phen-yl)arsine-3κAs]-triangulo-triruthenium(0)} dichloro-methane solvate. Acta crystallographica. Section E, Structure reports online 20100101
catena-Poly[[(6,7,9,10,17,18,20,21-octa-hydro-5,8,11,16,19,22-hexa-oxadibenzo[a,j]cyclo-octa-decene)barium]-di-μ-thio-cyanato-[thio-cyanato-diaurate(I)(Au-Au)]-μ-thio-cyanato]. Acta crystallographica. Section E, Structure reports online 20091201
Bis[μ(2)-bis-(diphenyl-phosphino)methane]bis-(μ(2)-ethane-1,2-dithiol-ato)-μ(4)-sulfido-μ(2)-sulfido-disulfidodimolybdenum(V)disilver(I) dimethyl-formamide tris-olvate. Acta crystallographica. Section E, Structure reports online 20091201
[μ-Bis-(diphenyl-phosphino)methane-1:2κP:P']nonacarbonyl-1κC,2κC,3κC-[tris-(4-methyl-phen-yl)arsine-3κAs]-triangulo-triruthenium(0). Acta crystallographica. Section E, Structure reports online 20091201
catena-Poly[[[acetonitrile-copper(I)]-bis-[μ-bis-(diphenyl-phosphino)methane-κP:P']-copper(I)-μ-1,2-di-4-pyridy-l-ethene] bis-(tetra-fluoridoborate)]. Acta crystallographica. Section E, Structure reports online 20091101
Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(2,2'-bipyridine-κN,N')copper(I)] bis-(tetra-fluoro-borate). Acta crystallographica. Section E, Structure reports online 20091001
Synthesis and structure of an 'iron-doped' copper selenide cluster molecule: [Cu30Fe2Se6(SePh)24(dppm)4]. Inorganic chemistry 20090921
Heteroleptic arene ruthenium complexes based on meso-substituted dipyrrins: synthesis, structure, reactivity, and electrochemical studies. Inorganic chemistry 20090817
The controlled formation and cleavage of an intramolecular d8-d8 Pt-Pt interaction in a dinuclear cycloplatinated molecular 'pivot-hinge'. Chemistry (Weinheim an der Bergstrasse, Germany) 20090803
Gold complexes with the selenolate ligand [2-(Me2NCH2)C6H4Se]-. Inorganic chemistry 20090504
Synthesis and crystal structures of bis(diphenylphosphanyl)methanides of lithium and calcium as well as of their borane adducts. Dalton transactions (Cambridge, England : 2003) 20090428
Laser spectroscopy for atmospheric and environmental sensing. Sensors (Basel, Switzerland) 20090101
Formation of [PtPd(2)(mu(3)-X)(2)(P-P)(dppmX)(2)](2+) (X = S, Se; P-P = dppe, 2 x PPh(3)) aggregates through activation of the chalcogen-rich [PtX(4)] ring by a Pd(I)-Pd(I) bond. Dalton transactions (Cambridge, England : 2003) 20081114
A C-H activation-CO(2)-carboxylation reaction sequence mediated by an 'Iridium(dppm)' species. Formation of the anionic ligand (Ph(2)P)(2)C-COOH. Chemical communications (Cambridge, England) 20081021
Synthesis and photophysical studies of calix[4]arene-based binuclear platinum(II) complexes: probing metal-metal and ligand-ligand interactions. Inorganic chemistry 20080616
Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(chloro-difluoro-acetato-κO)silver(I)](Ag-Ag). Acta crystallographica. Section E, Structure reports online 20080501
Reactivity of a heterocyclic As-Se compound with metal salts: syntheses and structures of the first copper complexes and of new alkali metal salts containing As-Se anions. Dalton transactions (Cambridge, England : 2003) 20080221
Strong intra- and intermolecular aurophilic interactions in a new series of brilliantly luminescent dinuclear cationic and neutral au(I) benzimidazolethiolate complexes. Inorganic chemistry 20080204
Bis[μ-methyl-enebis(diphenyl-phosphine)]bis-[(5-nitro-1,10-phenanthroline)silver(I)] bis-(hexa-fluoridoanti-monate). Acta crystallographica. Section E, Structure reports online 20080101
The nature of the chemical bond in linear three-body systems: from i3- to mixed chalcogen/halogen and trichalcogen moieties. Bioinorganic chemistry and applications 20070101
Rhodium dimers with 2,2-dimethyl-1,3-diisocyano and bis(diphenylphosphino)methane bridging ligands. Inorganic chemistry 20061030
Syntheses, structures, and nonlinear optical properties of heteroselenometallic W-Se-Ag cluster compounds containing phosphine ligands. Inorganic chemistry 20061016
Structures, photoluminescence, and reversible vapoluminescence properties of neutral platinum(II) complexes containing extended pi-conjugated cyclometalated ligands. Journal of the American Chemical Society 20060628
Solution and solid-state properties of luminescent M-M bond-containing coordination/organometallic polymers using the RNC-M2(dppm)2-CNR building blocks (M = Pd, Pt; R = Aryl, Alkyl). Inorganic chemistry 20060403
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Synthesis of heterobimetallic Ru-Mn complexes and the coupling reactions of epoxides with carbon dioxide catalyzed by these complexes. Chemistry (Weinheim an der Bergstrasse, Germany) 20060123
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Arsinophosphonium cations from arsenium-phosphine and -bisphosphine coordination chemistry. Inorganic chemistry 20051212
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The synthesis, structural, and spectroscopic characterization of uranium(IV) perrhenate complexes. Inorganic chemistry 20051017
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Complexes of lanthanide nitrates with bis(diphenylphosphino)methane dioxide. Inorganic chemistry 20030728
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[Bis(diphenylphosphino)methane][1,3-bis(diphenylphosphino)propane]platinum(II) dibromide. Acta crystallographica. Section C, Crystal structure communications 20011101
Properties