Home Sulfos Scandium(iii) trifluoromethanesulfonate

Scandium(iii) trifluoromethanesulfonate

CAS No.:
144026-79-9
Catalog Number:
AG001IU0
Molecular Formula:
C3F9O9S3Sc
Molecular Weight:
492.1632
Pack Size
Purity
Availability
Location
Price(USD)
Quantity
  
1g
97%
In Stock USA
United States
$19
- +
5g
97%
In Stock USA
United States
$50
- +
10g
97%
In Stock USA
United States
$94
- +
25g
97%
In Stock USA
United States
$188
- +
100g
97%
In Stock USA
United States
$494
- +
Product Description
Catalog Number:
AG001IU0
Chemical Name:
Scandium(iii) trifluoromethanesulfonate
CAS Number:
144026-79-9
Molecular Formula:
C3F9O9S3Sc
Molecular Weight:
492.1632
MDL Number:
MFCD00798539
IUPAC Name:
scandium(3+);trifluoromethanesulfonate
InChI:
InChI=1S/3CHF3O3S.Sc/c3*2-1(3,4)8(5,6)7;/h3*(H,5,6,7);/q;;;+3/p-3
InChI Key:
HZXJVDYQRYYYOR-UHFFFAOYSA-K
SMILES:
FC(S(=O)(=O)[O-])(F)F.FC(S(=O)(=O)[O-])(F)F.FC(S(=O)(=O)[O-])(F)F.[Sc+3]
Properties
Complexity:
145  
Compound Is Canonicalized:
Yes
Covalently-Bonded Unit Count:
4  
Defined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Exact Mass:
491.812g/mol
Formal Charge:
0
Heavy Atom Count:
25  
Hydrogen Bond Acceptor Count:
18  
Hydrogen Bond Donor Count:
0
Isotope Atom Count:
0
Molecular Weight:
492.146g/mol
Monoisotopic Mass:
491.812g/mol
Rotatable Bond Count:
0
Topological Polar Surface Area:
197A^2
Undefined Atom Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
Literature
Title Journal
Lewis acid trapping of an elusive copper-tosylnitrene intermediate using scandium triflate. Journal of the American Chemical Society 20120912
Catalytic asymmetric sulfenylation of unprotected 3-substituted oxindoles. Organic letters 20120601
Sc(OTf)3-catalyzed synthesis of indoles and SnCl4-mediated regioselective hydrochlorination of 5-(arylamino)pent-3-yn-2-ones. The Journal of organic chemistry 20111021
Chiral Sc-catalyzed asymmetric Michael reactions of thiols with enones in water. Organic & biomolecular chemistry 20110521
Efficient conversion of triacylglycerols and fatty acids to biodiesel in a microwave reactor using metal triflate catalysts. Organic & biomolecular chemistry 20101021
Highly enantioselective synthesis of alpha-stereogenic esters through catalytic asymmetric michael addition of 4-oxo-4-arylbutenoates. Chemistry (Weinheim an der Bergstrasse, Germany) 20100903
Scandium triflate-catalyzed one-pot domino approach towards general and efficient syntheses of unsymmetrical 9-substituted xanthene derivatives. Organic & biomolecular chemistry 20100307
Selective heteronuclear Hartmann-Hahn: a multiple-pulse sequence for selective magnetization transfer in the structural elucidation of 'isotagged' oligosaccharides. Journal of magnetic resonance (San Diego, Calif. : 1997) 20100301
Biomimetic synthesis of a new class of bacterial signaling molecules. Organic letters 20090716
Sc(OTf)(3)-catalyzed condensation of 2-alkyl-N-tosylaziridine with aldehydes or ketones: an efficient synthesis of 5-alkyl-1,3-oxazolidines. Chemical communications (Cambridge, England) 20090714
Alpha-sulfanyl and alpha-selanyl propadienyl cations: regioselective generations and cycloadditions with thioamides and selemides controlled by MeNO2-H2O system. Organic letters 20090702
Sc(OTf)3-catalyzed or t-BuOK promoted tandem reaction of 2-(2-(alkynyl)benzylidene)malonate with indole. Organic letters 20080605
Sc(OTf)3-mediated silylation of hydroxy functional groups on a solid surface: a catalytic grafting method operating at room temperature. Angewandte Chemie (International ed. in English) 20080101
Asymmetric Friedel-Crafts alkylation of indoles with methyl (E)-2-oxo-4-aryl-3-butenoates catalyzed by Sc(OTf)3/pybox. Chemistry (Weinheim an der Bergstrasse, Germany) 20080101
Enantioselective Friedel-Crafts alkylations catalyzed by bis(oxazolinyl)pyridine-scandium(III) triflate complexes. Journal of the American Chemical Society 20070815
Highly diastereoselective synthesis of beta-carboxy-gamma-lactams and their ethyl esters via Sc(OTf)(3)-catalyzed imino Mukaiyama-aldol type reaction of 2,5-bis(trimethylsilyloxy)furan with imines. The Journal of organic chemistry 20070622
First catalytic and green synthesis of aryl-(Z)-vinyl chlorides and its plausible addition-elimination mechanism. Organic letters 20070315
Mild reductive opening of aryl pyranosides promoted by scandium(III) triflate. Journal of the American Chemical Society 20070110
Direct C-glycosylation of indole with unprotected mono-, di-, and trisaccharides: a one-pot synthesis of 1-deoxy-1,1-bis(3-indolyl)alditols. Carbohydrate research 20061127
Catalytic enantioselective and diastereoselective addition of aldehyde-derived enecarbamates to alpha-oxo aldehydes. Angewandte Chemie (International ed. in English) 20060602
Scandium triflate catalyzed cycloaddition of imines with 1,1-cyclopropanediesters: efficient and diastereoselective synthesis of multi-substituted pyrrolidines. Organic & biomolecular chemistry 20060121
Catalytic asymmetric ring opening of meso-epoxides with aromatic amines in water. Organic letters 20051013
Enantioselective indole Friedel--Crafts alkylations catalyzed by bis(oxazolinyl)pyridine-scandium(III) triflate complexes. Journal of the American Chemical Society 20030910
Highly enantioselective 1,3-dipolar cycloaddition reactions of 2-benzopyrylium-4-olate catalyzed by chiral Lewis acids. Journal of the American Chemical Society 20021218
Scandium(III) trifluoromethanesulfonate catalyzed aromatic nitration with inorganic nitrates and acetic anhydride. Chemical & pharmaceutical bulletin 20020801
Direct formation of N-acylated amino acid derivatives via nucleophilic addition to N-acylimino esters using a polymer-supported amine and scandium triflate. Journal of combinatorial chemistry 20010101
Properties